Method for purification of exhaust gas from a diesel engine

1. A method for purification of exhaust gas from a diesel engine in a system, the method comprising the steps of:

providing:

a catalyst for selective catalytic reduction;

a diesel particulate filter at least partially covered by a catalytic layer installed downstream

of the catalyst for selective catalytic reduction; and

a first catalyst for catalytic oxidation installed upstream of the catalyst for selective catalytic

reduction and/or a second catalyst for catalytic oxidation installed between the catalyst for

selective catalytic reduction and the diesel particulate filter;

injecting a controlled amount of reductant at an inlet of the catalyst for selective catalytic reduction; and

injecting a controlled amount of hydrocarbon at an inlet of the catalyst for catalytic oxidation;

wherein the diesel particulate filter is passively regenerated by closing the injection of the reductant;

wherein the diesel particulate filter is actively regenerated by opening the injection of the hydrocarbon at inlet of at least one of the first and second catalysts for catalytic oxidation.

2. The method according to claim 1 , wherein the filter is passively regenerated by NO 2 at a temperature up to 500° C.

3. The method according to claim 1 , wherein the filter is actively regenerated at a temperature from 500° C. to 700° C.

4. The method according to claim 1 , wherein the reductant is ammonia, aqueous solution of ammonia, urea, an aqueous solution of urea, cyanuric acid, ammelide, ammelinge, ammonium cyanate, biuret, ammonium carbamate, ammomium carbonate, ammonium formate, melamine, or tricyanourea.

5. The method according to claim 4 , wherein the reductant is ammonia, aqueous solution of ammonia, urea, an aqueous solution of urea or cyanuric acid.

6. The method according to claim 1 , wherein the hydrocarbon is same fuel as to the diesel engine.

7. The method according to claim 1 , wherein the catalyst for selective catalytic reduction is a vanadium based catalyst or a zeolite based catalyst or a functionalized acidic base metal mixed oxide catalyst.

8. The method according to claim 7 , wherein the vanadium based catalyst is vanadium oxide on titanium oxide with addition of tungsten- or molybdenum oxides, the zeolite based catalyst is copper and/or iron modified beta zeolite, ZSM-5 or chabasite, and the functionalized acidic base metal mixed oxide catalyst comprises acidic cerium- zirconium oxide mixtures and zirconium-titanium oxide mixtures.

9. The method according to claim 7 , wherein the vanadium based catalyst is used at temperatures from 150° C. to 550° C. and the zeolite based catalyst is used at temperatures from 150° C. to 800° C.

10. The method according to claim 1 , wherein the catalytic layer on the diesel particulate filter comprises a mixture of base metal oxides in combination with precious metals preferably palladium and platinum.

11. The method according to claim 1 , wherein a first oxidation catalyst is installed upstream of the catalyst for selective catalytic reduction and a second oxidation catalyst is installed between the catalyst for selective catalytic reduction and the diesel particulate filter and ammonia is injected inlet the first oxidation catalyst.

12. The method according to claim 1 , wherein the catalyst for catalytic oxidation installed upstream of the catalyst for selective catalytic reduction comprises platinum and palladium on lanthanum oxide promoted aluminium oxide, or platinum and palladium on silicon oxide promoted titanium oxide, or platinum and palladium on zirconium oxide promoted cerium oxide; and

the catalyst for catalytic oxidation installed downstream of the catalyst for selective catalytic reduction palladium on lanthanum oxide promoted aluminium oxide, or palladium on silicon oxide promoted titanium oxide, or palladium on zirconium oxide promoted cerium oxide, or mixture of copper and manganese oxides or palladium on a mixture of copper and manganese oxides.

13. The method according to claim 1 , wherein pressure drop across the filter is measured and a created signal is used for controlling addition of reducing agent and addition of hydrocarbon.

14. The method according to claim 1 , wherein the diesel particulate filter is actively regenerated by additionally closing the injection of the reductant.