Liquid crystal composition and liquid crystal display device
View Patent ↗Provided is a liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, high stability to ultraviolet light and high stability to heat, or having a suitable balance regarding at least two of the characteristics. Provided is an AM device having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life, etc. The liquid crystal composition having a nematic phase includes a specific three-ring or four-ring compound having a high maximum temperature and a large dielectric anisotropy as a first component, and a specific compound having a small viscosity or a high maximum temperature of the nematic phase as a second component, and a liquid crystal display device contains the composition.
1. A liquid crystal composition has a nematic phase comprising a mixture of a least one compound selected from the group of compounds represented by formula (1-1-1), at least one compound selected from the group of compounds represented by and formula (1-1-2), at least one compound selected from the group of compounds represented by formula (1-2), and at least one compound selected from the group of compounds represented by formula (1-3-1) and formula (1-3-2) as a first component, and at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 2 and R 3 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring A, ring B and ring C are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 5 and Z 6 are independently a single bond, ethylene or carbonyloxy; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 and X 8 are independently hydrogen or fluorine; and Y 1 is fluorine, chlorine or trifluoromethoxy; and m is 0, 1 or 2.
2. The liquid crystal composition according to claim 1 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-10):
wherein R 2 and R 3 are alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
3. The liquid crystal composition according to claim 2 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1).
4. The liquid crystal composition according to claim 2 , wherein the second component is a mixture of at least one compound selected from the group of compounds represented by formula (2-6) and at least one compound selected from the group of compounds represented by formula (2-10).
5. The liquid crystal composition according to claim 1 , wherein a ratio of the first component is in the range of 5% by weight to 65% by weight, and a ratio of the second component is in the range of 35% by weight to 85% by weight, based on the total weight of the liquid crystal composition.
6. The liquid crystal composition according to claim 1 , further containing at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 4 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons; ring D is independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 2,6-difluoro-1,4-phenylene or 2,5-pyrimidine; Z 7 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and n is 1 or 2, wherein when n is 2 and both of Z 7 are a single bond, at least one of ring D is 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 2,6-difluoro-1,4-phenylene or 2,5-pyrimidine, and when n is 2 and at least one of Z 7 is not a single bond, at least one of ring D is 1,4-phenylene, 2-fluoro-1,4-phenylene or 2,6-difluoro-1,4-phenylene.
7. The liquid crystal composition according to claim 6 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to formula (3-12):
wherein R 4 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons.
8. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-9).
9. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-10).
10. The liquid crystal composition according to claim 6 , wherein a ratio of the third component is in the range of 5% by weight to 40% by weight, based on the total weight of the liquid crystal composition.
11. The liquid crystal composition according to claim 1 , wherein a maximum temperature of the nematic phase is 70° C. or higher, an optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.08 or more and a dielectric anisotropy (25° C.) at a frequency of 1 kHz is 2 or more.
12. A liquid crystal display device, containing the liquid crystal composition according to claim 1 .
13. The liquid crystal display device according to claim 12 , wherein an operating mode of the liquid crystal display device is a TN mode, an OCB mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display device is an active matrix mode.