Nonaqueous electrolyte and lithium secondary battery employing the same
View Patent ↗A nonaqueous electrolyte which contains a nonaqueous organic solvent and a lithium salt dissolved therein is provided. Also provided is a lithium secondary battery employing the nonaqueous electrolyte.
1. A nonaqueous electrolyte which comprises a nonaqueous organic solvent and a lithium salt dissolved therein, wherein the nonaqueous organic solvent comprises at least one cyclic carbonic ester having an unsaturated bond, and at least one sulfonic compound represented by formula (3) or formula (4):
wherein each of R 3 to R 7 independently represents a hydrogen atom or a hydrocarbon group having 1 to 8 carbon atoms, R 8 represents a hydrocarbon group having 1 to 8 carbon atoms, and n 3 represents an integer of 0 to 4;
wherein each of R 9 to R 12 independently represents a hydrogen atom or a hydrocarbon group having 1 to 8 carbon atoms, or R 9 and R 10 , R 11 and R 12 each may be combined with each other to form a ring and R 10 and R 11 may be also combined with each other,
wherein said cyclic carbonic ester having an unsaturated bond is present in an amount ranging from 0.01 to 10% by weight.
2. The nonaqueous electrolyte according to claim 1 , wherein the total content of said at least one sulfonic compound is 0.01 to 15% by weight based on the nonaqueous electrolyte.
3. The nonaqueous electrolyte according to claim 1 , wherein said at least one sulfonic compound is a sulfonic compound represented by formula (3).
4. The nonaqueous electrolyte according to claim 1 , wherein said at least one sulfonic compound is a sulfonic compound represented by formula (4).
5. The nonaqueous electrolyte according to claim 1 , wherein said cyclic carbonic ester having an unsaturated bond is at least one carbonate selected from the group consisting of a vinylene carbonate and a vinylethylene carbonate.
6. The nonaqueous electrolyte according to claim 1 , wherein the nonaqueous organic solvent further comprises at least one acid anhydride.
7. The nonaqueous electrolyte according to claim 6 , wherein the acid anhydride is at least one selected from the group consisting of succinic anhydride, glutaric anhydride, maleic anhydride, citraconic anhydride, glutaconic anhydride, itaconic anhydride, diglycolic anhydride, cyclohexanedicarboxylic anhydride, cyclopentanetetracarboxylic dianhydride, and phenylsuccinic anhydride.
8. A lithium secondary battery employing the nonaqueous electrolyte according to claim 1 .