Electrophotographic photoreceptor and image-forming apparatus
View Patent ↗It is to provide a sheet-shaped electrophotographic photoreceptor which has an uncoated area, is good in mechanical adhesiveness between the photosensitive layer and the sheet-shaped conductive substrate but excellent ease of peeling with a solvent, and is further good in electrical properties. The electrophotographic photoreceptor comprises a sheet-shaped conductive substrate and a photosensitive layer provided thereon, wherein the electrophotographic photoreceptor contains a photosensitive layer-uncoated area within the sheet surface, and the photosensitive layer contains a copolycarbonate resin having an extremely restricted specific structure.
1. An electrophotographic photoreceptor comprising a sheet-shaped conductive substrate and a photosensitive layer provided thereon, wherein the electrophotographic photoreceptor contains both a photosensitive layer-uncoated area and an insulated part within the sheet surface, and the photosensitive layer contains a copolycarbonate resin having a repeating structure represented by the following general formula (1):
wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrogen atom or an alkyl group having 4 or less carbon atoms, Z forms a saturated cyclic aliphatic alkyl group having 5 to 8 carbon atoms including the carbon atom to be bonded, and the saturated cyclic aliphatic alkyl group has one to three methyl groups as substituent(s), wherein the photosensitive layer is the outermost layer of the electrophotographic photoreceptor.
2. The electrophotographic photoreceptor according to claim 1 , wherein the copolycarbonate resin is a copolymer of the repeating structure represented by the general formula (1) above and a repeating structure represented by the following structural formula (2):
3. The electrophotographic photoreceptor according to claim 2 , wherein, in the copolycarbonate resin, the molar ratio of the repeating structure represented by the structural formula (2) is larger than the molar ratio of the repeating structure represented by the general formula (1).
4. The electrophotographic photoreceptor according to claim 2 , wherein, in the copolycarbonate resin, the molar ratio of the repeating structure represented by the structural formula (2) is twice or more the molar ratio of the repeating structure represented by the general formula (1).
5. The electrophotographic photoreceptor according to claim 1 , wherein the general formula (1) is represented by the following structural formula (3):
6. The electrophotographic photoreceptor according to claim 1 , wherein the thickness of the photosensitive layer is 17 μm or larger.
7. An image-forming apparatus comprising the electrophotographic photoreceptor according to claim 1 .
8. The electrophotographic photoreceptor according to claim 1 , wherein an undercoat layer is disposed between the conductive substrate and the photosensitive layer.
9. The electrophotographic photoreceptor according to claim 8 , wherein the undercoat layer has a thickness of from 0.1 μm to 25 μm.
10. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer is a single layer comprising a charge-generating material dispersed in a charge-transporting medium.
11. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer comprises a charge-generating layer and a charge-transporting layer.