Area bonded nonwoven fabric from single polymer system
View Patent ↗A nonwoven fabric is provided having a plurality of semi-crystalline filaments that are thermally bonded to each other and are formed of the same polymer and exhibit substantially the same melting temperature. The fabric is produced by melt spinning an amorphous crystallizable polymer to form two components having different levels of crystallinity. During spinning, a first component of the polymer is exposed to conditions that result in stress-induced crystallization such that the first polymer component is in a semi-crystalline state and serves as the matrix or strength component of the fabric. The second polymer component is not subjected to stress induced crystallization and thus remains in a substantially amorphous state which bonds well at relatively low temperatures. In a bonding step, the fabric is heated to soften and fuse the binder component. Under these conditions, the binder component undergoes thermal crystallization so that in the final product, both polymer components are semi-crystalline.
1. A method of making an area-bonded nonwoven fabric comprising the steps of:
melt extruding a crystallizable amorphous polymer of a single polymer system to produce a plurality of fibers;
subjecting the polymer to processing conditions that produce a first polymer component that is at least partially crystalline and a second polymer component that is substantially amorphous;
depositing the plurality of fibers on a collection surface to form a web containing both said first polymer component and said second polymer component;
bonding at least some of the plurality of fibers to one another at adjacent points of contact to form an area bonded nonwoven web in which the second polymer component softens and fuses to form bonds with the first polymer component; and
effecting crystallization of the second polymer component so that in the resulting nonwoven fabric both said polymer components are at least partially crystalline;
wherein the second polymer component is present in an amount ranging from 2% to 35% by weight, and
wherein the processing conditions are selected from the group consisting of
(a) subjecting fibers of the first polymer component to stress that induces crystallization, and subjecting fibers of the second polymer component to stress insufficient to induce crystallization, wherein the steps of subjecting the first and second polymer components to stress to induce or not induce crystallization comprises extruding the fibers at differing extrusion rates; and
(b) subjecting fibers of the first polymer component to stress that induces crystallization, and subjecting fibers of the second polymer component to stress insufficient to induce crystallization, wherein the steps of subjecting the first and second polymer components to stress to induce or not induce crystallization comprises providing a reduction in the intrinsic viscosity of the polymer in the second polymer component relative to the intrinsic viscosity of the polymer in the first polymer component.
2. The method of claim 1 , wherein the crystallizable polymer is selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, and polylactic acid, and copolymers and combinations thereof.
3. The method of claim 1 , wherein the second polymer component prior to bonding has a softening temperature that is at least 5° C. less than a softening temperature of the first polymer component.
4. The method of claim 1 , wherein the step of bonding the fibers comprises heating the fibers to a temperature at which the second polymer component softens and becomes tacky while the first polymer component remains solid, maintaining the fibers in the form of a web while the softened second polymer component adheres to portions of other fibers at fiber crossover points, and cooling the fibers to solidify the second polymer component and form a bonded nonwoven web.
5. The method of claim 1 , wherein the fibers of the nonwoven fabric exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace.
6. The method of claim 1 , wherein the step of melt extruding comprises melt extruding the polymer through one or more spinnerets that form first and second groups of continuous filaments, and said step of subjecting the polymer to processing conditions that produce first and second polymer components comprises subjecting the first group of continuous filaments to stress that induces crystallization, and subjecting the second group of continuous filaments to stress insufficient to induce crystallization.
7. The method of claim 6 , wherein the steps of subjecting the first and second groups of filaments to stress to induce or not induce crystallization comprises drawing the filaments under differing draw rates.
8. The method of claim 6 , wherein the steps of subjecting the first and second groups of filaments to stress to induce or not induce crystallization comprises extruding the filaments at differing extrusion rates.
9. The method of claim 6 , wherein the step of extruding a crystallizable polymer comprising extruding said polymer from first and second extruders, and wherein said step of subjecting the polymer to processing conditions that produce first and second polymer components comprises providing a reduction in the intrinsic viscosity of the polymer in the second extruder relative to the intrinsic viscosity of the polymer in the first extruder.
10. The method of claim 9 , wherein the intrinsic viscosity of the polymer in the second extruder is lowered by adding a viscosity lowering compound to the polymer in the second extruder.
11. The method of claim 9 , wherein the intrinsic viscosity of the polymer in the second extruder is lowered by adding recycled polymer to the second extruder.
12. The method of claim 9 , wherein the step of melt extruding a crystallizable amorphous polymer to produce a plurality of fibers comprises melt extruding the polymer through one or more spinnerets configured to form bicomponent filaments with the first and second polymer components present in distinct portions of the cross section of the filament, wherein the second polymer component is present in an amount ranging from 2% to 25% by weight of the bicomponent filaments.
13. The method of claim 12 , wherein the spinnerets are configured to form continuous multilobal filaments with the second polymer component present in at least some of the lobes of the filaments.
14. A method of making an area bonded nonwoven fabric comprising the steps of:
melt extruding a crystallizable amorphous polymer of a single polymer system through one or more spinnerets that form first and second groups of continuous filaments;
subjecting the first and second groups of continuous filaments to processing conditions that impart stress to the first group of filaments producing stress-induced crystallization such that the filaments are at least partially crystallized, and impart stress to the second group of continuous filaments insufficient to produce stress-induced crystallization such that the filaments remain substantially amorphous;
depositing the first and second groups of continuous filaments on a collection surface to form a web containing both said partially crystalline first filaments as matrix filaments and said amorphous second filaments as binder filaments;
heating the web so that the binder filaments soften and fuse to form bonds with one another and with the matrix filaments while maintaining their continuous filamentary form; and
effecting crystallization of the binder filament during the heating step so that in the resulting nonwoven fabric both said matrix filaments and said binder filaments are at least partially crystalline;
wherein the binder filaments are present in an amount ranging from 5% to 35% by weight, and
wherein the processing conditions are selected from the group consisting of
a) subjecting continuous filaments of the first group to stress that induces crystallization, and subjecting continuous filaments of the second group to stress insufficient to induce crystallization, wherein the steps of subjecting the continuous filaments of the first group and continuous filaments of the second group to stress to induce or not induce crystallization comprises extruding the continuous filaments at differing extrusion rates; and
b) subjecting continuous filaments of the first group to stress that induces crystallization, and subjecting continuous filaments of the second group to stress insufficient to induce crystallization, wherein the steps of subjecting the continuous filaments of the first group and continuous filaments of the second group to stress to induce or not induce crystallization comprises providing a reduction in the intrinsic viscosity of the continuous filaments of the first group relative to the intrinsic viscosity of the continuous filaments of the second group.
15. The method of claim 14 , wherein the crystallizable amorphous polymer comprises polyethylene terephthalate.
16. The method of claim 14 , wherein the filaments of the nonwoven fabric exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace.
17. A method of making a nonwoven fabric comprising the steps of:
melt extruding a crystallizable amorphous polymer of a single polymer system through one or more spinnerets configured to form bicomponent filaments having first and second polymer components present in distinct portions of the cross section of the filament, wherein the intrinsic viscosity of the polymer in the second component is reduced relative to the intrinsic viscosity of the polymer in the first component;
attenuating the filaments to cause stress-induced crystallization in the first polymer component of the filaments but without producing stress-induced crystallization in the second polymer component such that the second polymer component remains substantially amorphous;
depositing the bicomponent filaments on a collection surface to form a web in which the first polymer component of the filaments is partially crystalline and serves as the matrix component of the filaments and the second polymer component of the filament is amorphous and serves as the binder component of the filaments;
heating the web so that the binder component of the filaments softens and fuses to form bonds with contacting filaments while the filaments maintain their continuous filamentary form; and
effecting crystallization of the binder component of the filaments during the heating step so that in the resulting nonwoven fabric both the matrix component and the binder component of the bicomponent filaments are at least partially crystalline;
wherein the binder component is present in an amount ranging from 2% to 25% by weight.
18. The method of claim 17 , including providing the first and second polymer components of differing intrinsic viscosity from two separate sources.
19. The method of claim 17 , including providing the first and second polymer components of from the same source and lowering the intrinsic viscosity of the second polymer component by introducing a viscosity lowering additive.