In-situ method and system for controlling the flow of an organic liquid
View Patent ↗Disclosed is a method and system for controlling the flow of an organic liquid by flowing an organic liquid through a pipe having an upstream end with an unconstricted portion and a downstream end with a constricted portion, the constricted portion having an inner diameter that is at least 10% smaller than the inner diameter of the unconstricted portion, and a porous plug formed of sol-gel derived particles in the pipe, the plug having a length at least two times the diameter of the pipe. Also disclosed is a method and system, the system including a housing having a liquid inlet and a liquid outlet and containing a sol-gel derived composition and a liquid pressure sensitive control means operatively connected to the liquid inlet for controlling the flow of the organic liquid, contacting the sol-gel derived composition to actuate the liquid pressure sensitive control means and controlling the flow of the organic liquid in response to the actuation.
1. A method for controlling the flow of an organic liquid comprising:
flowing an organic liquid through a pipe having an upstream end with an unconstructed portion and a downstream end with a constricted portion, the constricted portion having an inner diameter that is at least 10% smaller than the inner diameter of the unconstricted portion, and a porous plug in the pipe, the plug having a length at least two times the diameter of the pipe, the plug comprising a sol-gel derived composition swellable to at least 1.5 times its volume to cause the plug to swell and control the flow of liquid through the downstream end.
2. The method of claim 1 where the organic solvent is an alkyl hydrocarbon, an aromatic hydrocarbon, a chlorinated hydrocarbon, an alcohol, an aldehyde, an epoxide, a ketone or an organic acid.
3. The method of claim 2 where the organic solvent is hexane, cyclohexane, octane, decane, octadecane, mineral oil, benzene, toluene, xylene, naphthalene, nitrobenzene, dichloromethane, trichloroethylene, perchloroethylene, dichloroethylene, methanol, ethanol, phenol, m-nitrophenol, methyl-t-butyl ether, acetone, gasoline, crude oil, aviation fuel or motor oil.
4. The method of claim 1 wherein the organic liquid is the only liquid.
5. The method of claim 1 wherein is organic liquid forms part of a bi-phasic mixture with water.
6. The method of claim 1 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape.
7. The method of claim 1 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape and having a particle size less than or equal to about 1 nm in at least one direction.
8. The method of claim 1 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape and further comprising an embedded organic polymer.
9. The method of claim 8 wherein the embedded polymer is polyamine, polystyrene or polyvinylphenol having a molecular weight >1,000 g/mol.
10. The method of claim 1 wherein the porous plug is contained in a fracturable housing.
11. A method for controlling the flow of an organic liquid comprising:
flowing an organic liquid through a pipe having an upstream end with an unconstricted portion and a downstream end with a constricted portion, the constricted portion having an inner diameter that is at least 10% smaller than the inner diameter of the unconstricted portion, and a porous plug in the pipe, the plug having a length at least two times the diameter of the pipe, the plug comprising particles of an aromatically-bridged, organosiloxane sol-gel derived composition containing a plurality of alkylsiloxy substituents to cause the plug to swell and control the flow of liquid through the downstream end.
12. The method of claim 11 where the organic solvent is an alkyl hydrocarbon, an aromatic hydrocarbon, a chlorinated hydrocarbon, an alcohol, an aldehyde, an epoxide, a ketone or an organic acid.
13. The method of claim 11 where the organic solvent is hexane, cyclohexane, octane, decane, octadecane, mineral oil, benzene, toluene, xylene, naphthalene, nitrobenzene, dichloromethane, trichloroethylene, perchloroethylene, dichloroethylene methanol, ethanol, phenol, m-nitrophenol, methyl-t-butyl ether, acetone, gasoline, crude oil, aviation fuel or motor oil.
14. The method of claim 11 wherein the organic liquid is the only liquid.
15. The method of claim 11 wherein is organic liquid forms part of a bi-phasic mixture with water.
16. The method of claim 11 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape.
17. The method of claim 11 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape and having a particle size less than or equal to about 1 nm in at least one direction.
18. The method of claim 11 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape and further comprising an embedded organic polymer.
19. The method of claim 18 wherein the embedded polymer is polyamine, polystyrene or polyvinylphenol having a molecular weight >1,000 g/mol.
20. The method of claim 11 wherein the porous plug is contained in a fracturable housing.
21. A system for controlling the flow of an organic liquid comprising:
a pipe having an upstream end with an unconstricted portion and a downstream end with a constricted portion, the constricted portion having an inner diameter that is at least 10% smaller than the inner diameter of the unconstricted portion, and
a porous plug in the pipe, the plug having a length at least two times the diameter of the pipe, the plug comprising a swellable, sol-gel derived particles.
22. The system of claim 21 wherein the sol-gel derived particles have an irregular shape.
23. The system of claim 21 wherein the sol-gel derived particles have a particle size less than or equal to about 1 nm in at least one direction.
24. The system of claim 21 wherein the sol-gel derived particles further comprise an embedded organic polymer.
25. The system of claim 24 wherein the embedded polymer is polyamine, polystyrene or polyvinylphenol having a molecular weight >1,000 g/mol.
26. The system of claim 21 wherein the porous plug is contained in a fracturable housing.
27. A system for controlling the flow of an organic liquid comprising:
a pipe having an upstream end with an unconstricted portion and a downstream end with a constricted portion, the constricted portion having an inner diameter that is at least 10% smaller than the inner diameter of the unconstricted portion; and
a porous plug in the pipe, the plug having a length at least two times the diameter of the pipe, the plug comprising particles of an aromatically-bridged, organosiloxane sol-gel derived composition containing a plurality of alkylsiloxy substituents.
28. The system of claim 27 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape.
29. The system of claim 27 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape and having a particle size less than or equal to about 1 nm in at least one direction.
30. The system of claim 27 wherein the sol-gel derived composition comprises sol-gel derived particles having an irregular shape and further comprising an embedded organic polymer.
31. The system of claim 28 wherein the embedded polymer is polyamine, polystyrene or polyvinylphenol having a molecular weight >1,000 g/mol.
32. The system of claim 27 wherein the porous plug is contained in a fracturable housing.