Fuel cell system with interconnect
View Patent ↗The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.
1. A fuel cell system, comprising:
a plurality of electrochemical cells, each electrochemical cell formed of an anode, a cathode spaced apart from said anode, and an electrolyte disposed between said anode and said cathode;
an interconnect electrically coupling a pair of electrically adjacent electrochemical cells, said interconnect electrically coupling said anode of one electrochemical cell to said cathode of the other electrochemical cell; and
a cathode conductive layer electrically coupled to said interconnect and in contact with said cathode,
wherein said interconnect is in contact with said cathode conductive layer and in contact with said electrolyte; and wherein said interconnect is formed of a cermet compound in which a reactant phase forms at least one non-ionic conducting ceramic phase in situ during firing of the fuel cell system.
2. The fuel cell system of claim 1 , wherein the cermet compound includes yttria stabilized zirconia (YSZ).
3. The fuel cell system of claim 2 , wherein the reactant phase is SrO.
4. The fuel cell system of claim 3 , wherein the reactant phase forms a SrZrO 3 non-ionic conducting phase during the firing.
5. The fuel cell system of claim 2 , wherein the reactant phase is a rare earth oxide.
6. The fuel cell system of claim 5 , wherein the rare earth oxide is an oxide of at least one of La, Pr, Nd, Gd, Sm, Ho, Er and Yb.
7. The fuel cell system of claim 6 , wherein the reactant phase forms a pyrochlore non-ionic conducting phase during the firing.
8. The fuel cell system of claim 2 , wherein an amount of the reactant phase is less than the stoichiometric ratio with the YSZ to form the at least one non-ionic conducting phase.
9. The fuel cell system of claim 2 , wherein an amount of the reactant phase is at the stoichiometric ratio with the YSZ to form the at least one non-ionic conducting phase.
10. The fuel cell system of claim 2 , wherein an amount of the reactant phase is greater than the stoichiometric ratio with the YSZ to form the at least one non-ionic conducting phase.
11. A fuel cell system comprising:
a plurality of electrochemical cells, each electrochemical cell formed of an anode, a cathode spaced apart from said anode, and an electrolyte disposed between said anode and said cathode;
an interconnect electrically coupling a pair of electrically adjacent electrochemical cells, said interconnect electrically coupling said anode of one electrochemical cell to said cathode of the other electrochemical cell; and
a cathode conductive layer electrically coupled to said interconnect,
wherein said interconnect is in contact with said cathode conductive layer and in contact with said electrolyte; and wherein said interconnect is formed of a cermet compound in which a reactant phase forms at least one non-ionic conducting ceramic phase in situ during firing of the fuel cell system; and
wherein said cathode conductive layer is in contact with said electrolyte.
12. The fuel cell system of claim 1 , wherein said interconnect includes a portion embedded within said electrolyte.
13. A fuel cell system, comprising:
a cathode of a first electrochemical cell;
an electrolyte; and
an anode of a second electrochemical cell spaced apart from said cathode by said electrolyte;
a cathode conductive layer adjoining said cathode;
an interconnect configured to conduct free electrons between said anode and said cathode, wherein said interconnect adjoins both said cathode conductive layer and said electrolyte; and wherein said interconnect is formed of a cermet compound in which a reactant phase forms at least one non-ionic conducting ceramic phase in situ during firing of the fuel cell system.
14. The fuel cell system of claim 13 , wherein the cermet compound includes yttria stabilized zirconia (YSZ).
15. The fuel cell system of claim 14 , wherein the reactant phase is SrO.
16. The fuel cell system of claim 15 , wherein the reactant phase forms a SrZrO 3 non-ionic conducting phase during the firing.
17. The fuel cell system of claim 14 , wherein the reactant phase is a rare earth oxide.
18. The fuel cell system of claim 17 , wherein the rare earth oxide is an oxide of at least one of La, Pr, Nd, Gd, Sm, Ho, Er and Yb.
19. The fuel cell system of claim 18 , wherein the reactant phase forms a pyrochlore non-ionic conducting phase during the firing.
20. The fuel cell system of claim 14 , wherein an amount of the reactant phase is less than the stoichiometric ratio with the YSZ to form the at least one non-ionic conducting phase.
21. The fuel cell system of claim 14 , wherein an amount of the reactant phase is at the stoichiometric ratio with the YSZ to form the at least one non-ionic conducting phase.
22. The fuel cell system of claim 14 , wherein an amount of the reactant phase is greater than the stoichiometric ratio with the YSZ to form the at least one non-ionic conducting phase.