Pastillation of ammonium sulfate nitrate
View Patent ↗Processes are presented for the production of ammonium sulfate nitrate. The processes provide for producing a highly uniform product and having a substantially uniform size. The processes include reacting ammonium sulfate and ammonium nitrate to form an FASN slurry melt. The slurry melt is continuously stirred and heated to keep the slurry melt under a shear thinned condition and at a uniform temperature until the slurry melt is extruded, cooled and solidified.
1. A process for the production of ammonium sulfate nitrate, comprising:
forming a slurry melt comprising ammonium sulfate nitrate and ammonium sulfate in a reactor;
passing the slurry melt to a heated stator;
continuously agitating the slurry melt in the heated stator to maintain the slurry melt under a shear-thinned condition;
recycling a recycle portion of the slurry melt from the heated stator to the reactor;
passing a portion of the slurry melt through a channel in the heated stator;
and
forming droplets by extruding the portion of the slurry melt through a moving grid that slides over the channel,
wherein the moving grid comprises grid holes sized to form the droplets;
wherein the process includes temperature control to maintain the slurry melt at a temperature from about 178° C. to about 210° C.
2. The process of claim 1 , wherein the reactor is operated at atmospheric pressure.
3. The process of claim 1 , wherein the process includes pressure control that maintains the pressure below about 0.8 MPa.
4. The process of claim 1 , wherein the process includes pressure control that maintains the pressure below about 0.2 MPa.
5. The process of claim 1 , further comprising the steps of:
dropping the droplets onto a moving belt; and
cooling the droplets to form uniform solid particles in the 1 to 3 mm diameter range.
6. The process of claim 5 , further comprising the step of:
passing a hot fluid through the moving grid holes after the step of dropping the droplets onto a moving belt.
7. The process of claim 6 , further comprising the step of:
collecting residual slurry melt blown out of the grid holes by the hot fluid.
8. The process of 1 , further comprising the step of:
mechanically scraping residual slurry melt around the edges of the grid holes with a scraper.
9. The process of 1 , further comprising the step of:
collecting and removing residual slurry melt using a second moving belt.
10. A process for the production of ammonium sulfate nitrate, comprising:
forming a slurry melt comprising ammonium sulfate nitrate and ammonium sulfate in a reactor having a temperature from about 178° C. to about 210° C.;
passing the slurry melt to a heated stator having a temperature from about 178° C. to about 210° C. and a pressure of less than about 0.8 MPa;
continuously agitating the slurry melt in the heated stator to maintain the slurry melt under a shear-thinned condition;
recycling a recycle portion of the slurry melt from the heated stator to the reactor;
passing a portion of the slurry melt through a channel in the heated stator;
forming droplets by extruding the portion of the slurry melt through a moving grid that slides over the channel, wherein the moving grid comprises grid holes sized to form the droplets.
11. The process of claim 10 , wherein the reactor is operated at atmospheric pressure.
12. The process of claim 10 , wherein the process includes pressure control that maintains the pressure below about 0.2 MPa.
13. The process of claim 10 , further comprising the steps of:
dropping the droplets onto a moving belt; and
cooling the droplets to form uniform solid particles in the 1 to 3 mm diameter range.
14. The process of claim 13 , further comprising the step of:
passing a hot fluid through the moving grid holes after the step of dropping the droplets onto a moving belt.
15. The process of claim 14 , further comprising the step of:
collecting residual slurry melt blown out of the grid holes by the hot fluid.
16. The process of 10 , further comprising the step of:
mechanically scraping residual slurry melt around the edges of the grid holes with a scraper.
17. The process of 10 , further comprising the step of:
collecting and removing residual slurry melt using a second moving belt.