High discharge capacity lithium battery
View Patent ↗A lithium/iron disulfide electrochemical battery cell with a high discharge capacity. The cell has a lithium negative electrode, an iron disulfide positive electrode and a nonaqueous electrolyte. The positive electrode mixture containing the iron disulfide contains highly packed solid materials, with little space around the solid particles, to provide a high concentration of iron disulfide within the mixture. The separator is thin, to allow more space within the cell for active materials, yet strong enough to prevent short circuits between the positive and negative electrodes under abusive conditions, even when swelling of the cathode during cell discharge places additional stressed on the separator. As a result, the ratio of the interfacial capacity of the positive electrode to the electrode interfacial volume is high, as is the actual capacity on low rate/low power and high rate/high power discharge.
1. An FR6 electrochemical battery cell comprising:
a cylindrical housing;
a negative electrode strip consisting essentially of metallic lithium or lithium alloyed with a metal;
a positive electrode strip comprising iron disulfide coated onto one or both sides of a thin metal strip, said positive electrode strip having a cathode interfacial capacity determined by a theoretical discharge capacity of only portions of the iron disulfide in the coating that are adjacent to the lithium or lithium alloy;
an electrolyte comprising at least one salt dissolved in a nonaqueous electrolyte disposed within the housing;
a separator consisting essentially of a microporous membrane including polyethylene, said microporous membrane having a total a thickness of less than 25 μm and disposed between the negative and positive electrodes;
wherein the positive electrode strip, the negative electrode strip and the separator are spirally wound to form an electrode assembly having an electrode assembly interfacial volume with a radius bounded by an inner surface of the cylindrical housing and a height bounded a longitudinal axis of the cell in which active materials in the positive electrode strip and the negative electrode strip are adjacent to one another; and
wherein the cell has: i) a ratio of the cathode interfacial capacity to the electrode assembly interfacial volume of at least 710 mAh/cm 3 , and ii) a discharge capacity of at least 2950 mAh when discharged at 200 mA continuously to a 1.0 volt cutoff.
2. The cell according to claim 1 , wherein the thickness of the separator is 22 μm or less.
3. The cell according to claim 1 , wherein the thickness of the separator is 20 μm or less.
4. The cell according to claim 1 , wherein the thickness of the separator is 16 μm or less.
5. The cell according to claim 1 , wherein the electrolyte includes at least one solvent selected from: sulfolane, 1,2-dimethoxyethane, 1,2-diehtoxyethane, di(methoxyethyl)ether, tri(glyme), tetragylme, diethyl ether, 1,3-dioxolane, tetrahydrofuran and 2-methyl tetrahydrofuran.
6. The cell according to claim 5 , wherein the salt is at least one selected from: lithium iodide, lithium perchlorate, lithium bromide and lithium trifluoromethanesulfonate.
7. The cell according to claim 1 , wherein the separator has a tensile stress of at least 1.0 kgf/cm in both a machine direction and a transverse direction.
8. The cell according to claim 7 , wherein the separator is biaxially oriented.
9. The cell according to claim 1 , wherein the polyethylene comprises ultrahigh molecular weight polyethylene.
10. The cell according to claim 1 , wherein the electrolyte includes at least one solvent selected from: sulfolane and 1,3-dioxolane.
11. The cell according to claim 1 , wherein the microporous membrane has a dielectric breakdown voltage of at least 2000 volts.
12. The cell according to claim 1 , wherein the dielectric breakdown voltage is between 2000 volts and 2400 volts.
13. The cell according to claim 8 , wherein the polyethylene comprises ultrahigh molecular weight polyethylene.
14. The cell according to claim 13 , wherein the microporous membrane has a dielectric breakdown voltage of at least 2000 volts.
15. The cell according to claim 13 , wherein the dielectric breakdown voltage is between 2000 volts and 2400 volts.