Process for producing 2,3,3,3-tetrafluoropropene
View Patent ↗The object is to provide a process for producing highly pure 2,3,3,3-tetrafluoropropene, whereby formation of 3,3,3-trifluoropropene as a by-product is suppressed. A process for producing 2,3,3,3-tetrafluoropropene, which comprises introducing and reacting a raw material compound composed of at least one of 1,1-dichloro-2,3,3,3-tetrafluoropropene and 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen, in a catalyst layer packed with a catalyst-supporting carrier, wherein the temperature of the catalyst layer is controlled to be higher than the dew point of the raw material mixed gas comprising the raw material compound and the hydrogen, and the maximum temperature of the catalyst layer is maintained to be at most 130° C. during the reaction.
1. A process for producing 2,3,3,3-tetrafluoropropene, which comprises introducing and reacting a raw material compound composed of at least one of 1,1-dichloro-2,3,3,3-tetrafluoropropene and 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen, in a gas phase in a palladium catalyst layer packed with a catalyst-supporting carrier, wherein the temperature of the palladium catalyst layer is controlled to be higher than the dew point of the raw material mixed gas comprising the raw material compound and the hydrogen, and the maximum temperature of the palladium catalyst layer is maintained to be at most 130° C. during the reaction.
2. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 , wherein the temperature of the palladium catalyst layer is at least 50° C.
3. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the catalyst-supporting carrier is active carbon.
4. The process for producing 2,3,3,3-tetrafluoropropene according to claim 3 , wherein the amount of the palladium supported is from 0.1 to 10 mass % based on the active carbon.
5. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 4 , wherein the packed density of the catalyst-supporting carrier in the palladium catalyst layer is from 0.5 to 1 g/cm 3 .
6. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 4 , wherein the palladium catalyst layer is maintained to be at most 80° C. except for the reaction zone of the raw material mixed gas and its vicinity in the palladium catalyst layer during the reaction.
7. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 4 , wherein the raw material mixed gas further contains an inert gas.
8. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 4 , wherein in the raw material mixed gas, the ratio of the number of moles of hydrogen to the number of moles of chlorine atoms in the raw material compound (H 2 /Cl) is adjusted to be at most 0.7.
9. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 4 , wherein the hydrogen is introduced, as divided, to at least two positions in the palladium catalyst layer.
10. The process for producing 2,3,3,3-tetrafluoropropene according to claim 9 , wherein the ratio of the total amount of hydrogen to the total amount of the raw material compound introduced to the palladium catalyst layer is adjusted to be at most 0.7 by the ratio of the number of moles of hydrogen to the number of moles of chlorine atoms in the raw material compound (H 2 /Cl).
11. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 4 , wherein the linear velocity u of the raw material mixed gas represented by the following formula (I) in the catalyst layer is from 1 to 30 cm/sec.:
u =( W/ 100)× V/S (I)
(In the formula (I), W is the concentration (mol %) of the raw material compound in the entire gas flowing in the catalyst layer, V is the flow rate (cm 3 /sec.) of the entire gas flowing in the palladium catalyst layer, and S is the cross-sectional area (cm 2 ) of the palladium catalyst layer to the flow direction of the gas.)
12. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 , wherein the palladium catalyst is palladium, a palladium alloy, a mixture of palladium and another metal or a composite catalyst having palladium and another metal separately supported on carriers.