Process for producing 2,3,3,3-tetrafluoropropene
View Patent ↗The object is to provide a process for producing highly pure 2,3,3,3-tetrafluoropropene, whereby formation of 3,3,3-trifluoropropene is suppressed. A process for producing 2,3,3,3-tetrafluoropropene, which comprises reacting a raw material compound composed of 1,1-dichloro-2,3,3,3-tetrafluoropropene and/or 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen in a gas phase in a reactor having a catalyst layer packed with a catalyst-supporting carrier, while maintaining the maximum temperature of the catalyst layer to be at most 130° C., to obtain formed gas containing 2,3,3,3-tetrafluoropropene, and then, contacting the formed gas discharged from the reactor, with alkali at a temperature of at most 100° C.
1. A process for producing 2,3,3,3-tetrafluoropropene, which comprises reacting a raw material compound composed of 1,1-dichloro-2,3,3,3-tetrafluoropropene and/or 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen in a gas phase in a reactor having a catalyst layer packed with a catalyst-supporting carrier, while maintaining the maximum temperature of the catalyst layer to be at most 130° C., to obtain formed gas containing 2,3,3,3-tetrafluoropropene, and then, contacting the formed gas discharged from the reactor, with water.
2. A process for producing 2,3,3,3-tetrafluoropropene, which comprises reacting a raw material compound composed of 1,1-dichloro-2,3,3,3-tetrafluoropropene and/or 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen in a gas phase in a reactor having a catalyst layer packed with a catalyst-supporting carrier, while maintaining the maximum temperature of the catalyst layer to be at most 130° C., to obtain formed gas containing 2,3,3,3-tetrafluoropropene, and then, contacting the formed gas discharged from the reactor, with alkali, while adjusting the temperature of the formed gas to be at most 100° C. immediately before the contact with alkali.
3. The process for producing 2,3,3,3-tetrafluoropropene according to claim 2 , wherein the alkali is an alkali aqueous solution.
4. The process for producing 2,3,3,3-tetrafluoropropene according to claim 3 , wherein the alkali aqueous solution is an aqueous solution of at least one metal hydroxide selected from the group consisting of sodium hydroxide, potassium hydroxide and calcium hydroxide.
5. The process for producing 2,3,3,3-tetrafluoropropene according to claim 4 , wherein the concentration of the metal hydroxide is from 0.01 to 40 mass % in the alkali aqueous solution (100 mass %).
6. The process for producing 2,3,3,3-tetrafluoropropene according to any one of claims 1 to 5 , wherein the catalyst is palladium.
7. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the carrier is active carbon.
8. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the packed density of the catalyst-supporting carrier in the catalyst layer is from 0.5 to 1 g/cm 3 .
9. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the catalyst is palladium or a palladium alloy.
10. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the catalyst comprises a mixture of palladium with another metal.
11. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the catalyst comprises palladium.
12. The method for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the catalyst comprises palladium and the catalyst is supported on a carrier.
13. The method for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , wherein the isolated 2,3,3,3-tetrafluoropropene has a purity of 99.5 to 99.9 mol %.
14. The method for producing 2,3,3,3-tetrafluoropropene according to claim 1 or 2 , further comprising isolating the 2,3,3,3-tetrafluoropropene and wherein the isolated 2,3,3,3-tetrafluoropropene has a purity of 99.5 to 99.9 mol %.