Process for producing a single-crystal component made of a nickel-based superalloy
View Patent ↗In a process for producing a large single-crystal component or directionally solidified component made of a nickel-based superalloy, the component is first cast into shape in a known manner to form a microstructure comprising dendrites, and then solution annealing for homogenizing the cast microstructure of the component and two-stage precipitation heat treatment are carried out. In order to avoid chemical inhomogeneities and internal stresses caused thereby, a HIP process with a pressure of higher than 160 MPa is carried out following the solution annealing.
1. A process for producing a single-crystal component or directionally solidified component made of a nickel-based superalloy, from a component which has been cast into shape to form a microstructure having dendrites, the process comprising:
A) determining the dendrite arm spacing (λ) in various regions of the component;
B) identifying the slowest diffusion element in the composition of the nickel-based superalloy and determining the diffusion coefficient (D);
C) calculating the time (t) required to reduce the segregation of said slowest diffusion element to ≦5% at a solution annealing temperature (T 1 ) which is lower than the initiation melting temperature (T mi );
D) solution annealing the component, comprising heating the component to the solution annealing temperature (T 1 ), holding the component at said solution annealing temperature (T 1 ) for the time (t) calculated in step C), and chilling from the temperature (T 1 ) to room temperature (RT) at a rate (v1) of ≧50° C./min; and
E) two-stage precipitation treating to precipitate the γ′ phase at in each case lower temperatures (T 2 ) and (T 3 ) following step D), including, in a first stage of the two-stage precipitation treating, performing a HIP process with an isostatic pressure (p) of higher than 160 MPa at the holding temperature (T 2 ) and subsequently cooling from the temperature (T 2 ) to room temperature (RT) at a cooling rate (v2) of ≧50° C./min, and, in a subsequent, second stage of the two-stage precipitation treatment, subjecting the component to heat treatment at a holding temperature (T 3 ) with subsequent cooling from the temperature (T 3 ) to room temperature (RT) at a cooling rate (v3) of 10 to 50° C./min.
2. The process as claimed in claim 1 , wherein determining the dendrite arm spacing (λ) comprises determining metallographically.
3. The process as claimed in claim 1 , wherein the chilling rate (v1) in step D) is >70° C./min.
4. The process as claimed in claim 1 , wherein:
the nickel-based superalloy has the following chemical composition (in % by weight): 5.6 Al, 9.0 Co, 6.5 Cr, 0.1 Hf, 0.6 Mo, 3 Re, 6.5 Ta, 1.0 Ti, 6.0 W, remainder Ni; and
said solution annealing is performed with 1290-1310° C./4-6 h/rapid cooling, where v1 is >50° C./min;
said first stage of the two-stage precipitation treating comprises a HIP process with an isostatic pressure (p) of >160 MPa at a holding temperature (T 2 ) of 1150° C. and a holding time of 4-8 h; and
said second stage of the two-stage precipitation treating comprises heating and holding at 870° C./16-20 h/.