Phosphor materials and related devices
View Patent ↗A phosphor material is presented that includes a blend of a first phosphor, a second phosphor and a third phosphor. The first phosphor includes a composition having a general formula of ((Sr 1−z M z ) 1−(x+w) A w Ce x ) 3 (Al 1−y Si y )O 4+y+3(x−w) F 1−y−3(x−w) , wherein 0<x≦0.10, 0≦y≦0.5, 0≦z≦0.5, 0≦w≦x, A comprises Li, Na, K, or Rb; and M comprises Ca, Ba, Mg, Zn, or Sn. The second phosphor includes a complex fluoride doped with manganese (Mn 4+ ), and the third phosphor include a phosphor composition having an emission peak in a range from about 520 nanometers to about 680 nanometers. A lighting apparatus including such a phosphor material is also presented. The light apparatus includes a light source in addition to the phosphor material.
1. A phosphor material comprising a blend of:
a first phosphor comprising a composition having a general formula of ((Sr 1−z M z ) 1−(x+w) A w Ce x ) 3 (Al 1−y Si y )O 4+y+3(x−w) F 1−y−3(x−w) , wherein 0<x≦0.10, 0<y≦0.5, 0≦z≦0.5, 0.5≦[1−y−3(x−w)]<1, A comprises Li, Na, K, or Rb; and M comprises Ca, Ba, Mg, Zn, or Sn;
a second phosphor comprising a complex fluoride doped with manganese (Mn 4+ ), and
a third phosphor comprising a garnet of general formula (A, Ce) 3 M 5−a O 12−3/2a , wherein 0≦a≦0.5, A comprises Y, Gd, Tb, La, Sm, Pr, or Lu; and M comprises Sc, Al, or Ga or a nitride of general formula (A, Eu) x Si y N z , wherein 2x+3y=4z, and A comprises Ba, Ca, or Sr.
2. The phosphor material of claim 1 , wherein at least a portion of Al in the first phosphor is substituted by B, Ga, Sc, or Y.
3. The phosphor material of claim 1 , wherein at least a portion of F in the first phosphor is substituted by Cl, Br, or I.
4. The phosphor material of claim 1 , wherein the first phosphor is doped with an additional activator ion.
5. The phosphor material of claim 4 , wherein the additional activator ion comprises Pr, Sm, Eu, Tb, Dy, Tm, Er, Ho, Nd, Bi, Pb, Yb, Mn, Ag, or Cu.
6. The phosphor material of claim 1 , wherein the first phosphor comprises a general formula of ((Sr 1−x M z ) 1−x Ce x ) 3 (Al 1−y Si y )O 4+y+3x F 1−y−3x , wherein 0<x≦0.10, 0<y≦0.5, 0≦z≦0.5, and M comprises Ca, Ba, Mg, Zn, or Sn.
7. The phosphor material of claim 1 , wherein the first phosphor comprises (Sr 0.98 Na 0.01 Ce 0.01 ) 3 (Al 0.9 Si 0.1 )O 4.1 F 0.9 , (Sr 0.98 Na 0.01 Ce 0.01 ) 3 (Al 0.8 Si 0.2 )O 4.2 F 0.8 , (Sr 0.75 Ca 0.23 Na 0.01 Ce 0.01 ) 3 (Al 0.75 Si 0.25 )O 4.25 F 0.75 , or (Sr 0.595 Ca 0.4 Ce 0.005 ) 3 (Al 0.6 Si 0.4 )O 4.415 F 0.585 .
8. The phosphor material of claim 1 , wherein the second phosphor comprises a general formula A 2 [MF 6 ]:Mn 4+ , wherein A comprises Na, K, Rb, Cs, or NH 4 ; and M comprises Si, Ti, Zr, or Mn.
9. The phosphor material of claim 1 , wherein the second phosphor comprises K 2 [SiF 6 ]:Mn 4+ , or K 2 [TiF 6 ]:Mn 4+ .
10. The phosphor material of claim 1 , wherein the third phosphor comprises Y 3 A 15 O 12 :Ce 3+ .
11. The phosphor material of claim 1 , wherein the third phosphor comprises A 2 Si 5 N 8 :Eu 2+ , wherein A comprises Ba, Ca, or Sr.
12. The phosphor material of claim 11 , wherein the nitride is further doped with cerium.
13. The phosphor material of claim 1 , wherein the first phosphor is present in a spectral weight from about 1 percent to about 70 percent, the second phosphor is present in a spectral weight from about 1 percent to about 70 percent, and the third phosphor is present in a spectral weight from about 1 percent to about 70 percent.
14. A lighting apparatus comprising: a light source and a phosphor material radiationally coupled to the light source, the phosphor material comprising a blend of:
a first phosphor comprising
composition having a general formula of ((Sr 1−z M z ) 1−(x+w) A w Ce x ) 3 (Al 1−y Si y )O 4+y+3(x−w) F 1−y−3(x−w) , wherein 0<x≦0.10, 0<y≦0.5, 0≦z≦0.5, 0.5≦[1−y−3(x−w)]≦1, A is Li, Na, K, or Rb; and M is Ca, Ba, Mg, Zn, or Sn;
a second phosphor comprising a complex fluoride doped with manganese (Mn 4+ ), and
a third phosphor comprising a garnet of general formula (A, Ce) 3 M 5−a O 12−3/2a , wherein 0≦a≦0.5, A comprises Y, Gd, Tb, La, Sm, Pr, or Lu; and M comprises Sc, Al, or Ga or a nitride of general formula (A, Eu) x Si y N z , wherein 2x+3y=4z, and A comprises Ba, Ca, or Sr.
15. The lighting apparatus of claim 14 , wherein the light source comprises a light emitting device (LED).
16. The lighting apparatus of claim 14 , further comprising an encapsulant surrounding the light source.
17. The lighting apparatus of claim 14 , wherein the phosphor material is coated on a surface of the light source.
18. The lighting apparatus of claim 16 , wherein the phosphor material is dispersed in the encapsulant.
19. The lighting apparatus of claim 14 , has a CRI (Rg) greater than 80.