Manufacturing apparatus and method for large-scale production of thin-film solar cells
View Patent ↗A method of manufacturing improved thin-film solar cells entirely by sputtering includes a high efficiency back contact/reflecting multi-layer containing at least one barrier layer consisting of a transition metal nitride. A copper indium gallium diselenide (Cu(In X Ga 1-X )Se 2 ) absorber layer (X ranging from 1 to approximately 0.7) is co-sputtered from specially prepared electrically conductive targets using dual cylindrical rotary magnetron technology. The band gap of the absorber layer can be graded by varying the gallium content, and by replacing the gallium partially or totally with aluminum. Alternately the absorber layer is reactively sputtered from metal alloy targets in the presence of hydrogen selenide gas. RF sputtering is used to deposit a non-cadmium containing window layer of ZnS. The top transparent electrode is reactively sputtered aluminum doped ZnO. A unique modular vacuum roll-to-roll sputtering machine is described. The machine is adapted to incorporate dual cylindrical rotary magnetron technology to manufacture the improved solar cell material in a single pass.
1. A method of manufacturing a solar cell, comprising:
providing a substrate;
depositing a first electrode over the substrate;
depositing at least one p-type semiconductor absorber layer over the first electrode, wherein the p-type semiconductor absorber layer comprises a copper indium selenide (CIS) based alloy material;
depositing a sacrificial layer comprising zinc on the p-type semiconductor absorber layer;
diffusing the zinc from the sacrificial layer into the p-type semiconductor absorber layer to form a n-type zinc doped, selenium containing semiconductor layer located on the p-type semiconductor absorber layer; and
depositing a second electrode over the n-type zinc doped, selenium containing semiconductor layer.
2. The method of claim 1 , wherein the sacrificial layer comprises a pure zinc layer.
3. The method of claim 1 , wherein:
the p-type semiconductor absorber layer comprises a p-type copper indium gallium selenide (CIGS) layer; and
the n-type zinc doped, selenium containing semiconductor layer comprises a n-type zinc doped copper indium gallium selenide (CIGS) layer.
4. The method of claim 3 , further comprising exposing the sacrificial layer to an oxygen containing plasma to convert the sacrificial layer to a zinc oxide layer located on the n-type zinc doped copper indium gallium selenide (CIGS) layer.
5. The method of claim 3 , further comprising exposing the sacrificial layer to a sulfur containing plasma to convert the sacrificial layer to a zinc sulfide layer located on the n-type zinc doped copper indium gallium selenide (CIGS) layer.
6. The method of claim 1 , further comprising forming a first transparent oxide layer comprising zinc oxide by reactive sputtering over the sacrificial layer and forming a second transparent oxide layer over the first transparent oxide layer.
7. The method of claim 6 , wherein the second transparent oxide layer comprises zinc oxide having a higher conductivity than the first transparent oxide layer.
8. The method of claim 1 , wherein the substrate comprises a metallic foil web.
9. The method of claim 1 , wherein the second electrode comprises at least one transparent conductive oxide layer located directly on the n-type zinc doped, selenium containing semiconductor layer.
10. The method of claim 1 , further comprising forming a n-type CdS, ZnO, ZnS or ZnSe window layer over the n-type zinc doped, selenium containing semiconductor layer.
11. The method of claim 10 , wherein the second electrode comprises at least one transparent conductive oxide layer located over the n-type CdS, ZnO, ZnS or ZnSe layer.
12. The method of claim 1 , wherein the steps of depositing the first electrode, the p-type semiconductor absorber layer, the n-type zinc doped selenium containing semiconductor layer, the sacrificial layer and the second electrode are performed by sputtering.