IP Library Granted Patent US 8,962,400
Granted Patent B2
US 8,962,400 · App. 13/178,294 · Granted Feb 24, 2015

In-situ doping of arsenic for source and drain epitaxy

Inventors: Ji-Yin Tsai (Zhudong Township, TW); Yao-Tsung Huang (Kaohsiung, TW); Chih-Hsin Ko (Fongshan, TW); Clement Hsingjen Wann (Carmel, NY)
Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
H01L29/7848H01L21/823807H01L21/823814H01L29/66636H01L29/66651H01L29/1054H01L29/66795H01L29/665H01L29/66628Y10S438/933
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Quick Facts
Patent No.
US 8,962,400
App. No.
13/178,294
Granted
Feb 24, 2015
Kind
B2
Abstract

A method includes forming a gate stack over a semiconductor region, and recessing the semiconductor region to form a recess adjacent the gate stack. A silicon-containing semiconductor region is epitaxially grown in the recess to form a source/drain stressor. Arsenic is in-situ doped during the step of epitaxially growing the silicon-containing semiconductor region.

Claims (43)

1. A method comprising:

forming isolation regions in a semiconductor substrate;

etching a portion of the semiconductor substrate between opposite sidewalls of the isolation regions to form a first recess;

epitaxially growing a first silicon germanium layer in the first recess, wherein the first silicon germanium layer has a first germanium concentration;

epitaxially growing a second silicon germanium layer in the recess and over the first silicon germanium layer, wherein the second silicon germanium layer has a second germanium concentration lower than the first germanium concentration;

forming a gate stack over the second silicon germanium layer;

recessing the second silicon germanium layer to form a second recess adjacent the gate stack; and

epitaxially growing a silicon-containing semiconductor region in the second recess to form a source/drain stressor, wherein arsenic is in-situ doped during the step of epitaxially growing the silicon-containing semiconductor region, wherein the silicon-containing semiconductor region comprises silicon germanium stressor having a third germanium concentration lower than the first germanium concentration and the second germanium concentration.

2. The method of claim 1 , wherein in the epitaxially growing the first silicon germanium layer and the second silicon germanium layer, a precursor selected from the group consisting essentially of AsH 3 , trimethyl arsenic (TMAs), tertiarybutylarsine (TBAs), and combination thereof is used.

3. The method of claim 1 , wherein the silicon-containing semiconductor region comprises a silicon stressor that is substantially free from germanium.

4. The method of claim 1 further comprising recessing the isolation regions, so that a portion of the second silicon germanium layer forms a semiconductor fin that is above top surfaces of remaining portions of the isolation regions, wherein the gate stack comprises a first portion directly over the semiconductor fin, and a second portion on a sidewall of the semiconductor fin.

5. The method of claim 1 , wherein the gate stack comprises a gate dielectric, and wherein the gate dielectric is in contact with a top surface of the second silicon germanium layer.

6. A method comprising:

epitaxially growing a first silicon germanium layer over and in contact with a portion of a silicon substrate, wherein the first silicon germanium layer has a first germanium concentration;

epitaxially growing a second silicon germanium layer over and in contact with the first silicon germanium layer, wherein the second silicon germanium layer has a second germanium concentration lower than the first germanium concentration;

forming a gate stack over the second silicon germanium layer, wherein a portion of the second silicon germanium layer forms a channel region of an n-type metal-oxide-semiconductor (NMOS) field-effect transistor (FET);

recessing the second silicon germanium layer to form recesses on opposite sides of the gate stack; and

epitaxially growing semiconductor stressors in the recesses, wherein the semiconductor stressors comprise silicon germanium having a third germanium concentration lower than both the first germanium concentration and the second germanium concentration.

7. The method of claim 6 further comprising:

forming isolation regions in the silicon substrate; and

etching a portion of the silicon substrate between opposite sidewalls of the isolation regions to form a trench, wherein the first silicon germanium layer and the second silicon germanium layer are epitaxially grown in the trench.

8. The method of claim 7 further comprising recessing the isolation regions, so that a top portion of the second silicon germanium layer forms a semiconductor fin, wherein the gate stack comprises a first portion directly over the semiconductor fin, and a second portion on a sidewall of the semiconductor fin.

9. A method comprising:

forming isolation regions in a silicon substrate;

etching a portion of the silicon substrate between opposite sidewalls of the isolation regions to form a first recess;

epitaxially growing a first silicon germanium layer in the first recess, wherein the first silicon germanium layer has a first germanium concentration;

epitaxially growing a second silicon germanium layer in the first recess and over the first silicon germanium layer, wherein the second silicon germanium layer has a second germanium concentration lower than the first germanium concentration;

recessing portions of the isolation regions on opposite sides of the second silicon germanium layer to form a fin, wherein the fin comprises a top portion of the second silicon germanium layer;

forming a gate stack on a top surface and sidewalls of the fin;

forming second recesses on opposite sides of the gate stack, wherein the second recesses penetrate through the second silicon germanium layer and extends into a top portion of the first silicon germanium layer; and

epitaxially growing silicon-containing semiconductor regions in the second recesses to form source/drain regions, wherein the silicon-containing semiconductor regions comprise silicon germanium having a third germanium concentration lower than both the first germanium concentration and the second germanium concentration.

10. The method of claim 9 , wherein the step of epitaxially growing the silicon-containing semiconductor regions comprises growing silicon germanium regions.

11. The method of claim 9 , wherein the step of epitaxially growing the silicon-containing semiconductor regions comprises growing silicon regions that are substantially free from germanium.

12. The method of claim 9 , wherein during the step of epitaxially growing the silicon-containing semiconductor regions, AsH 3 is used as a process gas.

13. The method of claim 1 , wherein the second recess penetrates through the second silicon germanium layer and extends into the first silicon germanium layer.

14. The method of claim 13 , wherein a bottom of the second recess is at an intermediate level between a top surface and a bottom surface of the first silicon germanium layer.

15. The method of claim 6 , wherein the gate stack comprises a gate dielectric, and wherein the gate dielectric is in contact with a top surface of the second silicon germanium layer.

16. The method of claim 9 , wherein the gate stack comprises a gate dielectric, and wherein the gate dielectric is in contact with a top surface of the second silicon germanium layer.

17. The method of claim 9 , wherein the second recesses comprise bottom surfaces at an intermediate level between a top surface and a bottom surface of the first silicon germanium layer.

18. The method of claim 4 , wherein the recessing the isolation regions stops before a top surface of the recessed isolation regions is lowered to a level of an interface between the first silicon germanium layer and the second silicon germanium layer.

19. The method of claim 1 , wherein the recessing the second silicon germanium layer stops before the first silicon germanium layer is exposed.

20. The method of claim 9 , wherein the recessing the portions of the isolation regions stops before a top surface of the recessed isolation regions is lowered to a same level as an interface between the first silicon germanium layer and the second silicon germanium layer.

21. The method of claim 6 , wherein the recessing the second silicon germanium layer stops after the first silicon germanium layer is exposed to the recesses.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 13, 2011
From: TSAI, JI-YIN; HUANG, YAO-TSUNG; KO, CHIH-HSIN; WANN, CLEMENT HSINGJEN
To: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
Reel/Frame 026582/0377 →
Continuity (1)
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