Solid state deformation processing of crosslinked high molecular weight polymeric materials
View Patent ↗Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a combination of high tensile strength and high oxidative stability. The materials are especially suitable for use as bearing components in artificial hip and other implants. Treated bulk materials are anisotropic, with enhanced strength oriented along the axial direction. The material is oxidatively stable even after four weeks of accelerated aging in a pressure vessel containing five atmospheres of oxygen (ASTM F2003). Because of its oxidative stability, the deformation processed material is a suitable candidate for air-permeable packaging and gas sterilization, which has thus far been reserved for remelted crosslinked UHMWPE.
1. A method for solid state deformation processing of gamma-irradiated ultra high molecular weight polyethylene (UHMWPE) comprising deforming the UHMWPE by extruding it through a reducing die at a temperature below its melt transition.
2. A method according to claim 1 , wherein the UHMWPE is crosslinked with a gamma-irradiation dose of from 0.1 to 10 Mrad.
3. A method according to claim 1 , wherein the UHMWPE is crosslinked with gamma-irradiation dose of from 0.1 to 5 Mrad.
4. A method according to claim 1 , comprising extruding at a draw ratio of 1.1 to 3.
5. A method according to claim 1 , comprising extruding at a draw ratio of 1.2 to 2.
6. A method according to claim 1 , comprising extruding at a draw ratio of 1.2 to 1.8.
7. A method according to claim 1 , further comprising cooling the extruded UHMWPE to a temperature below its solidification temperature, while maintaining the extruded UHMWPE in a deformed state.