CATALYST FOR REDUCING NITROGEN OXIDES AND METHOD FOR PRODUCING THE SAME
The object is to provide an exhaust gas reduction catalyst that exhibit high nitrogen oxide reduction performance, and to provide a simple and efficient method for producing the catalyst, in which the amount of the waste liquid is reduced, further, an object of the invention is to provide a zeolite-containing catalyst for reducing nitrogen oxides, which does not use an expensive noble metal or the like and which has high nitrogen oxide reduction performance. The present invention relates to a catalyst for reducing nitrogen oxides, which comprises: zeolite at least containing an aluminium atom and a phosphorus atom in the framework thereof; and a metal supported on the zeolite, wherein a coefficient of variation of intensity of the metal is at least 20%, when performing an elemental mapping of the metal in the catalyst with an electron probe microanalyzer, and, a catalyst for reducing nitrogen oxides, which comprises the zeolite containing at least a silicon atom, a phosphorus atom and an aluminium atom, and having an adsorption retention rate of at least 80% in a water vapor cyclic adsorption/desorption test at 90° C.
1 . A nitrogen oxide reduction catalyst, which comprises:
a zeolite containing at least an aluminium atom and a phosphorus atom in the framework thereof; and
a metal supported on the zeolite,
wherein the metal is, as observed with a transmission electron microscope, supported in the catalyst as particles having a diameter of from 0.5 nm to 20 nm.
2 . The nitrogen oxide reduction catalyst as claimed in claim 1 , wherein the metal is, when observed with a transmission electron microscope after the catalyst is treated with water vapor at 800° C. for 5 hours in an atmosphere containing 10% water vapor, supported in the catalyst as particles having a diameter of from 0.5 nm to 20 nm.
3 . The nitrogen oxide reduction catalyst as claimed in claim 1 , wherein the zeolite further contains a silicon atom in the framework.
4 . The nitrogen oxide reduction catalyst as claimed in claim 1 , wherein the zeolite has, when treated with water vapor at 800° C. for 10 hours in an atmosphere containing 10% water vapor and then measured a solid 29 Si-DD/MAS-NMR spectrum, an integral intensity area at a signal intensity of from −105 to −125 ppm of at most 25%, relative to an integral intensity area at a signal intensity of from −75 to −125 ppm.
5 . The nitrogen oxide reduction catalyst as claimed in claim 1 , wherein the zeolite has a CHA framework type as defined by IZA.
6 . The nitrogen oxide reduction catalyst as claimed in claim 4 , wherein, when a ratio of the silicon atom to the total of the silicon atom, the aluminium atom and the phosphorus atom contained in the zeolite framework is represented by x, a ratio of the aluminium atom thereto is represented by y and a ratio of the phosphorus atom thereto is represented by z, x is from 0 to 0.3, y is from 0.2 to 0.6, and z is from 0.3 to 0.6.
7 . The nitrogen oxide reduction catalyst as claimed in claim 1 , wherein the metal is Cu or Fe.
8 . The nitrogen oxide reduction catalyst as claimed in claim 1 , obtained by a process comprising:
preparing a mixture of the zeolite, a metal source for the metal and a dispersion medium and
spray-drying the mixture to remove the dispersion medium.
9 . A nitrogen oxide reduction catalyst, which comprises:
a zeolite containing at least an aluminium atom and a phosphorus atom in the framework thereof; and
a metal supported on the zeolite,
wherein a coefficient of variation of intensity of the metal is at least 20%, when performing an elemental mapping of the metal in the catalyst with an electron probe microanalyzer.
10 . A nitrogen oxide reduction catalyst, which comprises:
a zeolite having an 8-membered ring structure in the framework thereof; and
a metal supported on the zeolite,
wherein a coefficient of variation of intensity of the metal is at least 20%, when performing an elemental mapping of the metal in the catalyst with an electron probe microanalyzer.
11 . A nitrogen oxide reduction catalyst, which comprises:
a zeolite containing at least an aluminium atom and a phosphorus atom in the framework thereof; and
a metal supported on the zeolite,
wherein a peak top temperature for ammonia desorption after water vapor treatment of the catalyst according to an ammonia TPD (temperature programmed desorption) method falls between 250° C. and 500° C.
12 . The nitrogen oxide reduction catalyst as claimed in claim 11 , wherein an adsorption amount of the ammonia in the catalyst according to an ammonia TPD (temperature programmed desorption) method is at least 0.6 mol/kg.
13 . A method for producing a nitrogen oxide reduction catalyst comprising a zeolite containing at least an aluminium atom and a phosphorus atom in the framework thereof; and a metal supported on the zeolite, wherein the method comprises:
preparing a mixture of the zeolite, a metal source of the metal and a dispersion medium;
removing the dispersion medium from the mixture; and then
calcinating the mixture,
wherein the removal of the dispersion medium is attained within a period of at most 60 minutes.
14 . The method as claimed in claim 13 , wherein the zeolite has an 8-membered ring structure in the framework thereof.
15 . The method as claimed in claim 13 , wherein the mixture contains a template.
16 . The method as claimed in claim 13 , wherein the dispersion medium is removed by spray-drying.
17 . The method as claimed in claim 13 , wherein the zeolite further contains a silicon atom in the framework.
18 . The method as claimed in claim 13 , wherein the zeolite has a CHA framework type as defined by IZA.
19 . The method as claimed in claim 13 , wherein the metal is Cu or Fe.
20 . The method as claimed in claim 13 , wherein the removing includes spray-drying by contacting a heat carrier with the mixture, wherein the temperature of the heat carrier is from 80° C. to 350° C.