Method to establish viscosity as a function of shear rate for in-situ polymerized nanonylon via chain extension
View Patent ↗Chain-extended nanonylon is made from the reaction of in-situ polymerized nanonylon and chain-extending agents. Knowing the viscosity/shear rate curve for a thermoplastic polymer to be replaced, such as nylon, the method of the present invention allows via adjustment of organoclay concentration and chain extension of the nylon polymer and other reaction factors to achieve a chain-extended, in-situ polymerized nanonylon to have a viscosity/shear rate curve that essentially matches the viscosity/shear rate curve for that neat nylon within a commercially operable shear rate.
1. A multi-layer blown film article comprising a coextruded layer of chain-extended nanonylon, wherein the chain-extended nanonylon comprises a concentration of organoclay of greater than about 3 percent by weight and less than about 8 percent by weight of the chain-extended nanonylon, wherein the chain-extended nanonylon is the reaction product of an in-situ polymerized nanonylon and a chain extending agent selected from the group consisting of carbodiimides, carbodiimide hydrochlorides, multi-functional epoxies, carbonylbiscaprolactames, multi-functional acrylic oligomers, and combinations thereof and, wherein the weight average molecular weight of the in situ polymerized nanonylon has been increased from about 50,000 to 80,000 to from about 85,000 to about 110,000.
2. The article of claim 1 , wherein the in-situ polymerized nanonylon comprises polycaprolactam (nylon 6), poly(hexamethylene adipamide) (nylon 6,6), poly(hexamethylene sebacamide) (nylon 6, 10), poly(11aminondecanoic acid) (nylon 11), poly(12-aminododecanoic acid) (nylon 12) and combinations thereof.
3. The article of claim 1 , wherein the nanonylon further comprises an optional additive selected from the group consisting of optional additives include adhesion promoters; biocides (antibacterials, fungicides, and mildewcides), anti-fogging agents; anti-static agents; bonding, blowing and foaming agents; dispersants; fillers and extenders; fire and flame retardants and smoke suppresants; impact modifiers; initiators; lubricants; micas; pigments, colorants and dyes; plasticizers; processing aids; release agents; silanes, titanates and zirconates; slip and anti-blocking agents; stabilizers; stearates; ultraviolet light absorbers; viscosity regulators; waxes; and combinations of them.
4. The article of claim 1 , wherein the nanonylon further comprises another polymer selected from the group consisting of polyolefins, polyamides, polyimides, polycarbonates, polyesters, polysulfones, polylactones, polyacetals, acrylonitrile-butadiene-styrene resins (ABS), polyphenyleneoxide (PPO), polyphenylene sulfide (PPS), polystyrene, styrene-acrylonitrile resins (SAN), styrene maleic anhydride resins (SMA), aromatic polyketones (PEEK, PED, and PEKK) and mixtures thereof.
5. The article of claim 1 , wherein the nanonylon is endcapped with an endcapping agent selected from the group consisting of acetic anhydride, phthalic anhydride, hexamethyl disilazane, acetic acid, and cyclohexylamine.
6. The article of claim 1 , wherein the chain-extended nanonylon comprises in-situ polymerized nanonylon present in an amount ranging from about 10 to about 99.5 weight percent and the chain extending agent present in an amount ranging from about 0.5 to about 20 weight percent.
7. The article of claim 1 , wherein the multi-layer blown film article further comprises a layer of polyethylene or a layer of polyethylene blend.
8. The article of claim 7 , wherein the multi-layer blown film article further comprises a tie layer.
9. The article of claim 1 , wherein the chain-extended nanonylon has a viscosity/shear rate curve in a commercially operable region of shear rate that essentially matches a viscosity/shear rate curve of a layer of a nylon or a layer of an ethylene vinyl alcohol to be replaced by the chain-extended nanonylon layer.