Multi-layer core golf ball having thermoset rubber cover
View Patent ↗A golf ball with one or more thermosetting rubber core layers, intermediate layers and cover layers. At least one of the ball's layers has a moisture vapor barrier property, and the thermosetting rubber layers follow a cis- or a trans-polybutadiene gradient from the center of the ball to its cover. Each of the core layer, intermediate layer and cover layer comprises a cross-linked thermoset rubber composition having a primary rubber component of polybutadiene having a polydispersity of no greater than about 2 or a weight average molecular weight M w greater than about 400,000 in an amount of greater than about 80% by weight and a crosslinking initiator.
1. A golf ball comprising a core layer, a cover layer, and at least one intermediate layer disposed between the core and the cover, wherein said core layer, said cover layer, and said at least one intermediate layer each comprises a cross-linked thermoset rubber composition having a primary rubber component of polybutadiene having a polydispersity of no greater than about 2 in an amount of greater than about 80% by weight and a crosslinking initiator, the core layer having a cis-1,4-polybutadiene content (δ cr ), the at least one intermediate layer having a cis-1,4-polybutadiene content (δ im ), and the cover layer having a cis-1,4-polybutadiene content (δ cv ) such that δ cr ≧δ im ≧, δ cv , wherein a layer outside the core comprises a specific gravity higher than that of the core by greater than about 0.1 g/cm 3 , wherein at least one of the core layer, cover layer and intermediate layer comprises a moisture vapor barrier layer and wherein the overall ball comprises a compression of from 60 to 110 and a coefficient of restitution of from 0.750 to 0.850.
2. The golf ball of claim 1 , wherein the cover layer has a trans-1,4-polybutadiene content (ε cv ), the at least one intermediate layer has a trans-1,4-polybutadiene content (ε im ), and the core layer has a trans-1,4-polybutadiene content (ε cr ) such that ε cv ≧ε im ≧ε cr .
3. The golf ball of claim 2 , where ε cv is at least about 50% trans-1,4polybutadiene.
4. The golf ball of claim 1 , wherein δ cr is at least about 95% cis-1,4-polybutadiene.
5. The golf ball of claim 1 , wherein one of the core layer, cover layer and at least one intermediate layer has a moisture vapor transmission rate of less than about 0.95 grams·mm/(m 2 ·day).
6. The golf ball of claim 1 , wherein the thermoset rubber composition further comprises at least one compound chosen from antioxidants, antiozonants, light stabilizers,
UV absorbers, moisture scavengers, photoinitiators, silane crosslinkers, colorants, fillers, fibers, flakes, metal oxides, zinc oxide, zinc stearate, microparticles and specific gravity reducing agents.
7. The golf ball of claim 1 , wherein the at least one intermediate layer or cover layer has a specific gravity of at least about 1.2.
8. The golf ball of claim 1 , wherein the at least one inteimediate layer or cover layer has a specific gravity of less than about 1.0.
9. The golf ball of claim 1 , wherein the crosslinking initiator is chosen from di-t-amyl peroxide, di-t-butyl peroxide, t-butyl cumyl peroxide, di-cumyl peroxide, di(2-t-buylperoxyisopropyl)benzene, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3, 1,1-di(t-butylperoxy)-3,3,5- trimethylcyclohexane, 4,4-di(t-butylperoxy)-n-butylvalerate, and mixtures thereof.