Method for removing arsenic as scorodite
View Patent ↗The invention relates to a method for removing arsenic as scorodite from solutions that contain iron and arsenic. In accordance with the method, arsenic is first precipitated as ferric arsenate and subsequently processed hydrothermally into crystalline scorodite.
1. A method for precipitating iron and arsenic as a poorly soluble compound from acidic aqueous solutions, characterised in that an iron-containing solution and an arsenic-containing solution are oxidised by means of an oxidant so that the iron is oxidised to trivalent and the arsenic to pentavalent and that iron and arsenic are precipitated in a ferric arsenate precipitation stage as ferric arsenate at atmospheric pressure, whereby the iron-arsenic ratio and the pH are adjusted in the ferric arsenate precipitation stage to the region of 1-3.5, and the pH in the region of 1.5-4.5; the ferric arsenate precipitate formed is routed to hydrothermal conversion at a temperature of 150-200° C., at which the ferric arsenate crystallises as poorly soluble scorodite.
2. A method according to claim 1 , characterised in that the iron-arsenic ratio in the ferric arsenate precipitation stage is adjusted to between 1-1.5.
3. A method according to claim 1 , characterised in that the pH in the ferric arsenate precipitation stage is in the region of 1.5-2.
4. A method according to claim 1 , characterised in that hydrothermal conversion is carried out at a temperature of 160-180° C.
5. A method according to claim 1 , characterised in that arsenic remaining in solution after the ferric arsenate precipitation stage is removed from solution in a the purification precipitation stage.
6. A method according to claim 5 , characterised in that liquid-solids separation is performed after the ferric arsenate precipitation stage, and the solids resulting from the liquid-solids are routed to hydrothermal conversion and a solution resulting from the liquid-solids separation at least partially to the purification precipitation stage.
7. A method according to claim 5 , characterised in that liquid-solids separation is performed after the purification precipitation stage, and the solids resulting from the liquid-solids are treated so that arsenic contained in the solids dissolves and a solution resulting from the liquid-solids separation is routed to the ferric arsenate precipitation stage.
8. A method according to claim 5 , characterised in that liquid-solids separation is performed after the purification precipitation stage, and exiting solution is effluent.
9. A method according to claim 5 , characterised in that the iron-arsenate ratio of the purification precipitation stage is adjusted to the range 3-5 and the pH to the range of 3.5-5.
10. A method according to claim 1 , characterised in that solution obtained from the ferric arsenate precipitation stage is routed at least partially back to the ferric arsenate precipitation stage.
11. A method according to claim 1 , characterised in that a hydrothermal conversion solution is routed at least partially back to the ferric arsenate precipitation stage.
12. A method according to claim 1 , characterised in that a hydrothermal conversion solution is routed at least partially to a purification precipitation stage.
13. A method according to claim 1 , characterised in that the oxidation of iron and arsenic is performed separately before the ferric arsenate precipitation stage.
14. A method according to claim 1 , characterised in that the iron- and arsenic-containing solutions are routed together and are oxidised simultaneously in the ferric arsenate precipitation stage.
15. A method according to claim 1 , characterised in that the oxidant in the ferric arsenate precipitation stage is selected from at least one of the following group consisting of: oxygen, hydrogen peroxide, manganese dioxide, and oxygen with sulphur dioxide.
16. A method according to claim 5 , characterised in that a solution hydrothermal conversion solution is routed at least partially to the purification precipitation stage.