Membrane post treatment
View Patent ↗The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, poly(ethylene chlorotrifluoroethylene) (HALAR®), PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.
1. A polymeric ultra or microfiltration membrane comprising poly(vinyl methyl ether) and at least one of poly(ethylene chlorotrifluoroethylene), polyvinylidene fluoride (PVDF), and polypropylene, wherein the poly(vinyl methyl ether) (PVME) is incorporated in the membrane as a homogeneous or heterogeneous dispersion throughout the membrane.
2. The polymeric ultra or microfiltration membrane according to claim 1 , wherein the PVME is incorporated in the membrane as a homogeneous dispersion throughout the membrane.
3. The polymeric ultra or microfiltration membrane according to claim 1 , wherein the PVME is incorporated in the membrane as a heterogeneous dispersion throughout the membrane.
4. The polymeric ultra or microfiltration membrane according to claim 1 , wherein the membrane is hydrophilic.
5. The polymeric ultra or microfiltration membrane according to claim 1 , comprising an asymmetric structure.
6. The polymeric ultra or microfiltration membrane according to claim 1 , having reduced pore size as a result of the addition of PVME.
7. The polymeric ultra or microfiltration membrane according to claim 1 , that is substantially free from macrovoids.
8. The polymeric ultra or microfiltration membrane according to claim 1 , wherein the membrane comprises cross-linked PVME.
9. The polymeric ultra or microfiltration membrane according to claim 1 , comprising PVDF and PVME in a ratio of 0.1:24 to 0.5:24.
10. The polymeric ultra or microfiltration membrane according to claim 1 , comprising poly(ethylene chlorotrifluoroethylene) and PVME in a ratio of 0.5:18 to 1:18.
11. The polymeric ultra or microfiltration membrane according to claim 1 , comprising PVDF and PVME in a ratio of 0.4:13 to 2.3:13.
12. The polymeric ultra or microfiltration membrane according to claim 1 , comprising 0.4 to 30 wt % PVME.
13. The polymeric ultra or microfiltration membrane according to claim 1 , wherein upon soaking for 8 hours produces a detectable quantity of PVME.
14. The polymeric ultra or microfiltration membrane according to claim 1 , wherein upon soaking for 48 hours produces a leachate having at least 5 ppm PVME.
15. The polymeric ultra or microfiltration membrane according to claim 4 , rendered hydrophilic by contacting the membrane with an aqueous or alcoholic solution of PVME with a concentration of 0.05 to 5 wt %.
16. The polymeric ultra or microfiltration membrane according to claim 1 , rendered hydrophilic by contacting the membrane with an aqueous or alcoholic solution of PVME with a concentration of 0.05 to 5 wt %, at a pressure of 0.5 to 50 bar.