IP Library Granted Patent US 8,434,860
Granted Patent B2
US 8,434,860 · App. 13/207,994 · Granted May 7, 2013

Method for jet printing using nanoparticle-based compositions

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Quick Facts
Patent No.
US 8,434,860
App. No.
13/207,994
Granted
May 7, 2013
Kind
B2
Abstract

Apparatus and methods for controlling application of a substance to a substrate involve the use of a nanoparticle-based gating agent that blocks the substance from or attracts the substance to the substrate. The apparatus and methods may utilize ink jet technology to apply the gating agent directly to the substrate or to an intermediate surface.

Claims (45)

1. A method for high speed variable printing comprising the steps of:

jetting a gating agent composition onto a substrate in a pattern, the gating agent composition comprising:

from about 5% and about 20% of a water dispersible component;

from about 5% and about 15% of an amine selected from the group consisting of amine ethoxylates, amine propoxylates, amine ethoxylate/propoxylates and mixtures thereof; and

from about 75% to about 95% of water; and

applying a printing agent to the substrate to form a print image in areas not covered by the pattern of the gating agent.

2. The method of claim 1 , wherein the water-dispersible component includes one of silica, alumina, zirconia, zinc oxide, colloidal coria, antimony oxide, and combinations thereof.

3. The method of claim 2 , wherein the water-dispersible component is less than about 20 nanometers.

4. The method of claim 1 , wherein the amine is an amine ethoxylate.

5. The method of claim 1 , wherein the HLB of the amine is between about 2 to about 18.

6. The method of claim 1 , wherein the nanoparticle-based gating agent has a pH of between about 4 to about 6.

7. The method of claim 1 , wherein the composition includes a pH modifier.

8. The method of claim 1 , wherein the amine is an amine ethoxylate/propoxylate.

9. A method for high speed variable printing comprising the steps of:

applying a printing agent to a substrate;

jetting a gating agent composition in a pattern onto at least one of a final print medium, the printing agent applied to the substrate, and the substrate, the gating agent composition comprising:

from about 0.05 to about 10% by weight of a blocking agent;

up to about 3% by weight of a surface tension modifying compound;

up to about 8% by weight of viscosity modifier such that the composition has a viscosity within the range of about 1 to 14 mPa s; and

the balance of the gating agent composition comprises a solvent;

wherein the gating agent has a dynamic surface tension of less than about 60 dynes/cm; and

forming a print image in areas not covered by the pattern of the gating agent;

wherein the pattern of the gating agent composition determines where the print image is formed.

10. The method of claim 9 , wherein the gating agent composition is jetted onto the substrate prior to the application of the printing agent and the gating agent composition prevents the adherence of the printing agent to the substrate in areas where the gating agent has been jetted.

11. The method of claim 9 , wherein the substrate is a media upon which the print image is formed.

12. The method of claim 9 , wherein the substrate is an intermediate surface that transfers the print image to a final print media.

13. The method of claim 9 , wherein the gating agent composition is jetted onto the substrate subsequent to the application of the printing agent and the gating agent composition blocks the transfer of the printing agent to a final print media in areas where the gating agent has been jetted.

14. The method of claim 9 , wherein the substrate is a print cylinder.

15. The method of claim 9 , wherein the composition has a viscosity in the range of from about 1 to about 3 mPa s.

16. A method for high speed variable printing comprising the steps of:

applying a printing agent to a substrate;

jetting a gating agent composition in a pattern onto at least one of a final print medium, the printing agent applied to the substrate, and the substrate, the gating agent composition comprising:

from about 0.05 to about 10% by weight of a blocking agent;

up to about 15% by weight of a surface tension modifying compound;

up to about 8% by weight of viscosity modifier such that the composition has a viscosity within the range of about 1to 14 mPa s; and

the balance of the gating agent composition comprises a solvent;

wherein the gating agent has a dynamic surface tension of less than about 60 dynes/cm; and

forming a print image in areas not covered by the pattern of the gating agent;

wherein the pattern of the gating agent composition determines where the print image is formed.

17. The method of claim 16 , wherein the gating agent composition is jetted onto the substrate prior to the application of the printing agent and the gating agent composition prevents the adherence of the printing agent to the substrate in areas where the gating agent has been jetted.

18. The method of claim 16 , wherein the substrate is a media upon which the print image is formed.

19. The method of claim 16 , wherein the substrate is an intermediate surface that transfers the print image to a final print media.

20. The method of claim 16 , wherein the gating agent composition is jetted onto the substrate subsequent to the application of the printing agent and the gating agent composition blocks the transfer of the printing agent to a final print media in areas where the gating agent has been jetted.

21. The method of claim 16 , wherein the substrate is a print cylinder.

22. The method of claim 16 , wherein the composition has a viscosity in the range of from about 1 to about 3 mPa s.

Assignments (20)
INTELLECTUAL PROPERTY ASSIGNMENT AGREEMENT Recorded Apr 22, 2025
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: BANK OF AMERICA, N.A.
Reel/Frame 070919/0394 →
PATENT SECURITY AGREEMENT Recorded Aug 9, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.; VALASSIS COMMUNICATIONS, INC.; VALASSIS DIGITAL CORP.; VALASSIS DIRECT MAIL, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 068534/0447 →
PATENT SECURITY AGREEMENT Recorded Aug 9, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.; VALASSIS DIGITAL CORP.; VALASSIS DIRECT MAIL, INC.; VALASSIS COMMUNICATIONS, INC.
To: APOLLO ADMINISTRATIVE AGENCY LLC
Reel/Frame 068533/0812 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS (R/F 064462/0445) Recorded Aug 9, 2024
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
To: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 068534/0306 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS (R/F 064463/0597) Recorded Aug 9, 2024
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
To: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 068534/0330 →
PATENT SECURITY AGREEMENT Recorded Aug 9, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.; VALASSIS COMMUNICATIONS, INC.; VALASSIS DIGITAL CORP.; VALASSIS DIRECT MAIL, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 068534/0366 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2024
From: APOLLO ADMINISTRATIVE AGENCY LLC, AS ADMINISTRATIVE AGENT
To: R.R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 068467/0314 →
RELEASE OF SECURITY INTEREST RECORDED AT RF 056122/0839; ASSIGNED VIA RF 059203/0333 TO JEFFERIES AND RF 063487/0449 TO APOLLO Recorded Apr 17, 2024
From: APOLLO ADMINISTRATIVE AGENCY LLC
To: R.R. DONNELLEY & SONS COMPANY
Reel/Frame 067131/0845 →
SECURITY INTEREST Recorded Apr 3, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: APOLLO ADMINISTRATIVE AGENCY LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 067000/0669 →
PATENT SECURITY AGREEMENT Recorded Aug 1, 2023
From: R.R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 064462/0445 →
PATENT SECURITY AGREEMENT Recorded Aug 1, 2023
From: R.R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS 2028 NOTES COLLATERAL AGENT
Reel/Frame 064463/0597 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS, PREVIOUSLY RECORDED AT REEL 056079, FRAME 0534 Recorded Jul 31, 2023
From: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 064441/0646 →
ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL RECORDED AT REEL/FRAME 056122/0839 AND 059203/0333 Recorded Apr 28, 2023
From: JEFFERIES FINANCE LLC
To: APOLLO ADMINISTRATIVE AGENCY LLC
Reel/Frame 063487/0449 →
INTELLECTUAL PROPERTY ASSIGNMENT AGREEMENT Recorded Feb 10, 2023
From: BANK OF AMERICA, N.A.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 062702/0648 →
ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL RECORDED AT R/F 056122/0839 Recorded Feb 25, 2022
From: BANK OF AMERICA, N.A.
To: JEFFERIES FINANCE LLC
Reel/Frame 059203/0333 →
SECURITY INTEREST Recorded May 3, 2021
From: R. R. DONNELLEY & SONS COMPANY
To: BANK OF AMERICA, N.A.
Reel/Frame 056122/0810 →
SECURITY INTEREST Recorded May 3, 2021
From: R. R. DONNELLEY & SONS COMPANY
To: BANK OF AMERICA, N.A.
Reel/Frame 056122/0839 →
SECURITY INTEREST Recorded Apr 28, 2021
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 056079/0534 →
MERGER Recorded Aug 12, 2013
From: MOORE WALLACE NORTH AMERICA, INC.
To: R.R. DONNELLEY & SONS COMPANY
Reel/Frame 030991/0468 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 11, 2011
From: HOOK, KEVIN J.; LITMAN, STANLEY; ZALOOM, JEFFREY
To: MOORE WALLACE NORTH AMERICA, INC.
Reel/Frame 026737/0142 →