Drag reduction of asphaltenic crude oils
View Patent ↗A system for reducing pressure drop associated with the turbulent flow of asphaltenic crude oil through a conduit. The crude oil has a high asphaltene content and/or a low API gravity. Such reduction in pressure drop is achieved by treating the asphaltenic crude oil with a high molecular weight drag reducing polymer that can have a solubility parameter within about 20 percent of the solubility parameter of the heavy crude oil. The drag reducing polymer can also comprise the residues of monomers having at least one heteroatom.
1. A method comprising:
introducing a drag reducing polymer, into a pipeline, such that the friction loss associated with the turbulent flow through the pipeline is reduced by suppressing the growth of turbulent eddies, into a liquid hydrocarbon having an asphaltene content of at least 3 weight percent and an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon wherein the viscosity of the treated liquid hydrocarbon is not less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer;
wherein the drag reducing polymer is added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw; and
wherein drag reducing polymer comprises repeating units of the residues selected from the group consisting of: C4-C20 alkyls, C6-C20 unsubstituted aryls, C6-C20 substituted aryls, aryl-substituted C1-C10 alkyl ester derivatives of methacrylic acid, aryl-substituted C1-C10 alkyl ester derivatives of acrylic acids and combinations thereof;
wherein the drag reducing polymer has a solubility parameter within 4 MPa 1/2 of the solubility parameter of the liquid hydrocarbon.
2. The method of claim 1 , wherein the drag reducing polymer comprises at least about 25,000 repeating units.
3. The method of claim 1 , wherein a plurality of the repeating units comprise a heteroatom.
4. The method of claim 3 , wherein the heteroatom is selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom and/or a phosphorus atom.
5. The method of claim 1 , wherein the drag reducing polymer has a weight average molecular weight of at least 1×10 6 g/mol.
6. The method of claim 1 , wherein the solubility parameter of the liquid hydrocarbon is determined by the following equation:
δ 2 =[(Δ Hv−RT )/ V] 1/2
where ΔHv is the energy of vaporization, R is the universal gas constant, T is the temperature in Kelvin, V is the molar volume and δ 2 is the solubility parameter.
7. The method of claim 1 , wherein the solubility parameter of the drag reducing polymer is determined by the following equation:
δ=(δ d 2 +δ p 2 +δ h 2 ) 1/2
where δ is the solubility parameter, δ d =ΣF di /V, δ d =(ΣF hi /V)½, δ d =ΣF 2 pi ) 1/2 /V.
8. A method comprising:
introducing a drag reducing polymer, into a pipeline, such that the friction loss associated with the turbulent flow through the pipeline is reduced by suppressing the growth of turbulent eddies, into a liquid hydrocarbon having an asphaltene content of at least 3 weight percent and an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon wherein the viscosity of the treated liquid hydrocarbon is not less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer;
wherein the drag reducing polymer is added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw; and
wherein drag reducing polymer comprises repeating units of the residues selected from the group consisting of: C4-C20 alkyls, C6-C20 unsubstituted aryls, C6-C20 substituted aryls, aryl-substituted C1-C10 alkyl ester derivatives of methacrylic acid, aryl-substituted C1-C10 alkyl ester derivatives of acrylic acids and combinations thereof;
wherein the solubility parameter of the drag reducing polymer is at least about 17 MPa 1/2 .
9. The method of claim 8 , wherein the solubility parameter of the liquid hydrocarbon is determined by the following equation:
δ 2 =[(Δ Hv−RT )/ V] 1/2
where ΔHv is the energy of vaporization, R is the universal gas constant, T is the temperature in Kelvin, V is the molar volume and δ 2 is the solubility parameter.
10. The method of claim 8 , wherein the solubility parameter of the drag reducing polymer is determined by the following equation:
δ=(δ d 2 +δ p 2 +δ h 2 ) 1/2
where δ is the solubility parameter, δ d =ΣF di /V, δ d =(ΣF hi /V)½, δ d =ΣF 2 pi ) 1/2 /V.
11. A method comprising:
introducing a drag reducing polymer, into a pipeline, such that the friction loss associated with the turbulent flow through the pipeline is reduced by suppressing the growth of turbulent eddies, into a liquid hydrocarbon having an asphaltene content of at least 3 weight percent and an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon wherein the viscosity of the treated liquid hydrocarbon is not less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer,
wherein the drag reducing polymer is added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw; and
wherein drag reducing polymer comprises repeating units of the residues selected from the group consisting of: C4-C20 alkyls, C6-C20 unsubstituted aryls, C6-C20 substituted aryls, aryl-substituted C1-C10 alkyl ester derivatives of methacrylic acid, aryl-substituted C1-C10 alkyl ester derivatives of acrylic acids and combinations thereof;
wherein the drag reducing polymer has a solubility parameter within 2.5 MPa 1/2 of the liquid hydrocarbon.
12. The method of claim 11 , wherein the solubility parameter of the liquid hydrocarbon is determined by the following equation:
δ 2 =[(Δ Hv−RT )/ V] 1/2
where ΔHv is the energy of vaporization, R is the universal gas constant, T is the temperature in Kelvin, V is the molar volume and δ 2 is the solubility parameter.
13. The method of claim 11 , wherein the solubility parameter of the drag reducing polymer is determined by the following equation:
δ=(δ d 2 +δ p 2 +δ h 2 ) 1/2
where δ is the solubility parameter, δ d =ΣF di /V, δ d =(ΣF hi /V)½, δ d =ΣF 2 pi ) 1/2 /V.