IP Library Granted Patent US 8,287,695
Granted Patent B2
US 8,287,695 · App. 13/210,274 · Granted Oct 16, 2012

Manufacturing carbon nanotube paper

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Quick Facts
Patent No.
US 8,287,695
App. No.
13/210,274
Granted
Oct 16, 2012
Kind
B2
Abstract

Techniques and apparatuses for making carbon nanotube (CNT) papers are provided. In one embodiment, a method for making a CNT paper may include disposing a structure having an edge portion including a relatively sharp edge into a CNT colloidal solution and withdrawing the structure from the CNT colloidal solution.

Claims (32)

1. An apparatus for making a carbon nanotube (CNT) paper comprising:

a blade having a sharp edge portion;

a container configured to contain a CNT colloidal solution;

a manipulator configured to dispose the blade in the CNT colloidal solution; and

extensions slidably engaging two opposing sides of the blade.

2. The apparatus of claim 1 , wherein the sharp edge portion of the blade has a thickness of about 0.5 nm to about 300 μmm.

3. The apparatus of claim 1 , wherein the sharp edge portion of the blade comprises a hydrophilic surface property.

4. The apparatus of claim 1 , wherein the sharp edge portion of the blade comprises a metal.

5. The apparatus of claim 4 , wherein the metal comprises tungsten.

6. The apparatus of claim 1 , wherein the sharp edge portion of the blade comprises a self-assembled monolayer coating.

7. A processor-readable storage medium storing instructions that, when executed by a processor, cause the processor to control an apparatus to perform a method comprising:

disposing a blade having a sharp edge portion into a CNT colloidal solution such that CNTs in the CNT colloidal solution adhere to the sharp edge portion; and

withdrawing the blade from the CNT colloidal solution to form the CNT paper at the interface between the sharp edge portion and the CNT colloidal solution, wherein an influx of carbon nanotubes from the CNT colloidal solution towards the blade occurs due to a meniscus and the influx is in the range of about 1 cm/hour to about 9 cm/hour.

8. The processor-readable storage medium of claim 7 , wherein withdrawing the blade comprises withdrawing the blade from the CNT colloidal solution at a predetermined withdrawal velocity.

9. The processor-readable storage medium of claim 8 , wherein the predetermined withdrawal velocity is about 0.3 mm/min to about 3 mm/min.

10. The processor-readable storage medium of claim 7 , wherein the method further comprises dispersing the CNTs in a solvent to form the CNT colloidal solution.

11. The processor-readable storage medium of claim 10 , wherein a concentration of CNTs dispersed in the CNT colloidal solution is in the range from about 0.05 mg/mL to about 0.2 mg/mL.

12. An apparatus for making carbon nanotube (CNT) paper, the apparatus comprising:

a blade having a sharp edge portion;

a container;

a motor coupled to the blade, wherein the motor is configured to dispose the sharp edge portion of the blade into the container and withdraw the sharp edge portion of the blade from the container; and

a processor operably coupled to at least the motor, wherein the processor is configured to facilitate making a CNT paper by a method comprising:

disposing the sharp edge portion of the blade into a CNT colloidal solution within the container such that CNTs in the CNT colloidal solution adhere to the sharp edge portion; and

withdrawing the blade from the CNT colloidal solution to form the CNT paper at the interface between the sharp edge portion and the CNT colloidal solution, wherein an influx of carbon nanotubes from the CNT colloidal solution towards the blade occurs due to a meniscus and the influx is in the range of about 1 cm/hour to about 9 cm/hour.

13. The apparatus of claim 12 , wherein the sharp edge of the blade has a thickness of about 0.5 nm to about 300 μm.

14. The apparatus of claim 12 , wherein the sharp edge portion of the blade comprises a hydrophilic surface property.

15. The apparatus of claim 12 , wherein the sharp edge portion of the structure comprises a self-assembled monolayer coating.

16. The apparatus of claim 12 , wherein the apparatus further comprising two extensions slidably engaging opposing sides of the blade.

17. The apparatus of claim 16 , wherein the extensions each comprise a sharp edge adjacent to the opposing sides of the blade.

18. The apparatus of claim 12 , the apparatus further comprising the CNT colloidal solution disposed within the container.

19. The apparatus of claim 12 , wherein withdrawing the blade comprises withdrawing the blade from the CNT colloidal solution at a predetermined withdrawal velocity.

20. The apparatus of claim 19 , wherein where the predetermined withdrawal velocity is about 0.3 mm/min. to about 3 mm/min.

Assignments (3)
RELEASE OF SECURITY INTEREST IN PATENTS, RECORDED ON JANUARY 29, 2019 AT REEL 048373 FRAME 0217 Recorded Sep 22, 2025
From: CRESTLINE DIRECT FINANCE, L.P., AS COLLATERAL AGENT
To: EMPIRE TECHNOLOGY DEVELOPMENT LLC
Reel/Frame 072936/0464 →
RELEASE OF SECURITY INTEREST Recorded Jul 31, 2019
From: CRESTLINE DIRECT FINANCE, L.P.
To: EMPIRE TECHNOLOGY DEVELOPMENT LLC
Reel/Frame 049924/0794 →
SECURITY INTEREST Recorded Jan 29, 2019
From: EMPIRE TECHNOLOGY DEVELOPMENT LLC
To: CRESTLINE DIRECT FINANCE, L.P.
Reel/Frame 048373/0217 →