SOLVENTLESS PROCESS TO PRODUCE AROMATIC GROUP-CONTAINING ORGANOSILANES
Disclosed herein is a process for producing an aromatic group-containing organosilane, The process includes reacting a reaction mixture comprising an aromatic organic compound of the formula R 1 X and a halosilane or alkoxysilane represented by the formula R 2 a SiZ 4-a in the presence of magnesium metal in order to produce the organosilane with the proviso that said reaction mixture is essentially free of any organic solvent, wherein R 1 is an aryl group, each R 2 is independently a phenyl group, a vinyl group or a C1-C4 alkyl group, X is chlorine or bromine, Z is chlorine, bromine or alkoxy, and a has a value of 0, 1, 2, or 3.
1 . A process for producing an aromatic group-containing organosilane, the process comprising reacting a reaction mixture comprising an aromatic organic compound of the formula R 1 X and a halosilane or alkoxysilane represented by the formula R 2 a SiZ 4-a in the presence of magnesium metal in order to produce said aromatic group-containing organosilane with the proviso that said reaction mixture is essentially free of any organic solvent, wherein R 1 is an aryl group, each R 2 is independently a phenyl group, a vinyl group or a C1-C4 alkyl group, X is chlorine or bromine, Z is chlorine, bromine or alkoxy, and a has a value of 0, 1, 2, or 3.
2 . The process of claim 1 wherein the process is carried out at a temperature in the range of about 150° C. to about 220° C.
3 . The process of claim 1 wherein the process is carried out at a pressure of about ambient to super atmospheric pressure.
4 . The process of claim 1 wherein the process is carried out in an inert atmosphere.
5 . The process of claim 4 wherein the inert atmosphere is nitrogen.
6 . The process of claim 1 wherein said organic solvent is an ether.
7 . The process of claim 1 wherein said reaction mixture does not contain tetrahydrofuran.
8 . The process of claim 1 wherein R 1 is phenyl.
9 . The process of claim 8 wherein the aromatic organic compound is chlorobenzene.
10 . The process of claim 1 wherein the halosilane is phenyltrichlorosilane.
11 . The process of claim 1 wherein there is present at least one mole of magnesium for every mole of the aromatic organic compound.
12 . A process for producing a diphenyldichlorosilane composition, the process comprising reacting a reaction mixture comprising chlorobenzene and phenyltrichlorosilane in the presence of magnesium metal in order to produce the diphenyldichlorosilane composition with the proviso that said reaction mixture is essentially free of any organic solvent.
13 . The process of claim 12 wherein the organic solvent is ether.
14 . The process of claim 12 wherein the reaction mixture does not contain tetrahydrofuran.
15 . The process of claim 12 wherein the process is conducted at a temperature of about 150° C. to about 220° C. for a period of time varying from about 10 to about 36 hours.
16 . The process of claim 12 wherein the molar ratio of chlorobenzene relative to phenyltrichlorosilane is from about 0.5 to about 1.5.
17 . The process of claim 12 wherein the molar ratio of chlorobenzene relative to phenyltrichlorosilane is about 0.9 to about 1.1.
18 . The process of claim 12 further comprising removing the magnesium chloride byproduct from the diphenyldichlorosilane composition by filtration.