Deposition system with a rotating drum

1. A deposition system comprising

a metallization zone including a sputtering system for metal film deposition;

a reaction zone including an ionization source for generating at least one reactive ionic species;

a rotatable mount configured to hold at least one substrate and to pass at least a portion of the substrate alternately through said metallization and reaction zones so as to deposit a metal film on said substrate portion in the metallization zone and to react the metal film with said at least one reactive ionic species in said reaction zone; and

at least one diffusive gas barrier disposed between said metallization and reaction zones for maintaining a pressure differential therebetween, wherein the reaction zone comprises a pair of inner baffles interposed between a pair of differential pumps, and a pair of outer baffles between which the differential pumps are interposed.

2. The system of claim 1 , further comprising an electrical bias for application to said substrate.

3. The system of claim 1 , wherein the sputtering system comprises an anode, a cathode and a metal target and is configured to ionize a gas and to direct the ionized gas to the metal target such that an impact of the gas ions on the target results in sputtering of metal from the target onto said substrate portion, wherein the target is interposed between the anode and the gas so as to substantially isolate the anode from the gas.

4. The system of claim 1 , wherein the sputtering system comprises a mask interposed between the target and the at least one substrate, the mask configured to form a wavefront of a sputtered material parallel to a surface of the at least one substrate.

5. The system of claim 1 , further comprising another metallization zone including a second sputtering system for depositing another metal on the substrate portion.

6. The system of claim 1 , wherein the sputtering system includes a magnetron with a length substantially equal to a height of the rotatable mount plus twice a width of the target and wherein the length of the magnetron is collinear with the height of the rotatable mount and is perpendicular to the width of the target.

7. The system of claim 1 , wherein the ionization source is a linear ion source.

8. The system of claim 1 , wherein the metallization zone is pressurized with a first gas at a first pressure and the reaction zone is pressurized with a second gas at a second pressure, and wherein said second pressure is less than said first pressure.

9. The system of claim 1 , wherein the reaction zone is configured to switch the second gas with another reactive gas after a number of rotations of the rotatable mount.

10. The deposition system of claim 8

wherein a distance between the metallization zone and the reaction zone along the circumference of the rotatable mount exceeds a mean free path of the second gas at said second pressure.

11. The system of claim 1 , further comprising a liquid coolant for cooling said rotatable mount.

12. The system of claim 8 , wherein the reaction zone further comprises an electron source for injecting electrons into the reaction zone so as to maintain plasma neutrality.

13. The system of claim 2 , wherein said electrical bias comprises any of a DC, RF or pulsed electrical bias.

14. The system of claim 1 , wherein said at least one barrier comprises at least a pair of baffles disposed between the metallization zone and the reaction zone.

15. The system of claim 8 , wherein the first gas comprises an inert gas and the second gas comprises a reactive gas.

16. The system of claim 15 , wherein said inert gas comprises any of argon and xenon, and wherein said reactive gas comprises oxygen.

17. The system of claim 16 , wherein said metal target comprises aluminum.

18. The system of claim 8 , wherein said first pressure is in a range of about 1×10 −3 to about 1×10 −2 torr.

19. The system of claim 8 , wherein said second pressure is in a range of about 1×10 −4 to 5×10 −4 ton.

20. The system of claim 6 , wherein said magnetron is enclosed in a vestibule configured to receive gas from a gas source, said vestibule having an aperture configured to allow a pressure within the vestibule to build up to a value greater than a pressure in the reaction zone.

21. A deposition system comprising

a metallization zone including a sputtering system for metal film deposition,

a reaction zone including an ionization source for generating at least one reactive ionic species; and

a rotatable mount configured to hold at least one substrate and to pass at least a portion of the substrate alternately through said metallization and reaction zones so as to deposit a metal film on said substrate portion in the metallization zone and to react the metal film with said at least one reactive ionic species in said reaction zone, and

means for maintaining a pressure differential therebetween, wherein the reaction zone comprises a pair of inner baffles interposed between a pair of differential pumps, and a pair of outer baffles between which the differential pumps are interposed.

22. The system of claim 21 , wherein said means is configured to maintain a pressure in the reaction zone that is less than a respective pressure in the metallization zone.

23. The system of claim 21 , wherein said means comprises at least a pair of baffles disposed between the metallization and the reaction zones.

24. The system of claim 21 , wherein said metallization zone is pressurized with a first gas at a first pressure and said reaction zone is pressurized with a second gas a second pressure less than said first pressure.

25. The system of claim 24 , wherein a distance between said metallization zone and said reaction zone along a circumference of said rotatable mount exceeds a mean free path of said second gas at said second pressure.