Method for producing seamless steel pipe for oil wells excellent in sulfide stress cracking resistance
A high-strength seamless steel pipe for oil wells excellent in sulfide stress cracking resistance which comprises, on the percent by mass basis, C: 0.1 to 0.20%, Si: 0.05 to 1.0%, Mn: 0.05 to 1.0%, Cr: 0.05 to 1.5%, Mo: 0.05 to 1.0%, Al: 0.10% or less, Ti: 0.002 to 0.05% and B: 0.0003 to 0.005%, with a value of equation “C+(Mn/6)+(Cr/5)+(Mo/3)” of 0.43 or more, with the balance being Fe and impurities, and in the impurities P: 0.025% or less, S: 0.010% or less and N: 0.007% or less. The seamless steel pipe may contain a specified amount of one or more element(s) of V and Nb, and/or a specified amount of one or more element(s) of Ca, Mg and REM. The seamless steel pipe can be produced at a low cost by adapting an in-line tube making and heat treatment process having a high production efficiency since a reheating treatment for refinement of grains is not required.
1. A method for producing a seamless steel pipe for oil wells, which comprises the steps of making a pipe by hot-piercing a steel billet having a chemical composition consisting of, on the percent by mass basis, C: 0.1 to 0.20%, Si: 0.05 to 1.0%, Mn: 0.05 to 1.0%, Cr: 0.05 to 1.5%, Mo: 0.05 to 1.0%, Al: 0.10% or less, Ti: 0.002 to 0.05% and B: 0.0003 to 0.005%, with the balance being Fe and impurities, and in the impurities P: 0.025% or less, S: 0.010% or less and N: 0.007% or less, with a value of A determined by the following equation (1) of 0.43 or more followed by elongating and rolling, and then finally rolling at a final rolling temperature adjusted to the Ar 3 transformation point to 1100 degrees centigrade, then following the final rolling step, the finally rolled steel pipe is assistantly heated in a temperature range from the Ar 3 transformation point to 1000 degrees centigrade in-line before the surface temperature becomes lower than the Ar 3 transformation point, and then the assistantly heated pipe is quenched from a temperature of the Ar 3 transformation point or higher and then tempered at a temperature lower than the Ac 1 transformation point, while keeping the pipe at a temperature of the Ar 3 transformation point or higher from tube-making to quenching:
A =C+(Mn/6)+(Cr/5)+(Mo/3) (1),
wherein, in the equation (1), C, Mn, Cr and Mo each represent % by mass of the respective elements.
2. The method for producing a seamless steel pipe for oil wells according to claim 1 , wherein the temperature of assistant heating in-line is the Ac 3 transformation point to 1000 degrees centigrade.
3. The method for producing a seamless steel pipe for oil wells according to claim 1 , wherein the tensile strength is not more than 931 MPa.
4. A method for producing a seamless steel pipe for oil wells, which comprises the steps of making a pipe by hot-piercing a steel billet having a chemical composition consisting of, on the percent by mass basis, C: 0.1 to 0.20%, Si: 0.05 to 1.0%, Mn: 0.05 to 1.0%, Cr: 0.05 to 1.5%, Mo: 0.05 to 1.0%, Al: 0.10% or less, Ti: 0.002 to 0.05%, B: 0.0003 to 0.005%, and V: 0.03 to 0.2%, with the balance being Fe and impurities, and in the impurities P: 0.025% or less, S: 0.010% or less and N: 0.007% or less, with a value of A determined by the following equation (1) of 0.43 or more followed by elongating and rolling, and then finally rolling at a final rolling temperature adjusted to the Ar 3 transformation point to 1100 degrees centigrade, then following the final rolling step, the finally rolled steel pipe is assistantly heated in a temperature range from the Ar 3 transformation point to 1000 degrees centigrade in-line before the surface temperature becomes lower than the Ar 3 transformation point, and then the assistantly heated pipe is quenched from a temperature of the Ar 3 transformation point or higher and then tempered at a temperature lower than the Ac 1 transformation point, while keeping the pipe at a temperature of the Ar 3 transformation point or higher from tube-making to quenching:
A =C+(Mn/6)+(Cr/5)+(Mo/3) (1),
wherein, in the equation (1), C, Mn, Cr and Mo each represent % by mass of the respective elements.
5. The method for producing a seamless steel pipe for oil wells according to claim 4 , wherein the tensile strength is not more than 931 MPa.
6. The method for producing a seamless steel pipe for oil wells according to claim 4 , wherein the temperature of assistant heating in-line is the Ac 3 transformation point to 1000 degrees centigrade.
7. A method for producing a seamless steel pipe for oil wells, which comprises the steps of making a pipe by hot-piercing a steel billet having a chemical composition consisting of, on the percent by mass basis, C: 0.1 to 0.20%, Si: 0.05 to 1.0%, Mn: 0.05 to 1.0%, Cr: 0.05 to 1.5%, Mo: 0.05 to 1.0%, Al: 0.10% or less, Ti: 0.002 to 0.05%, B: 0.0003 to 0.005%, and one or more element(s) selected from a group of Ca of 0.0003 to 0.005%, Mg of 0.0003 to 0.005% and REM of 0.0003 to 0.005%, with the balance being Fe and impurities, and in the impurities P: 0.025% or less, S: 0.010% or less and N: 0.007% or less, with a value of A determined by the following equation (1) of 0.43 or more followed by elongating and rolling, and then finally rolling at a final rolling temperature adjusted to the Ar 3 transformation point to 1100 degrees centigrade, then following the final rolling step, the finally rolled steel pipe is assistantly heated in a temperature range from the Ar 3 transformation point to 1000 degrees centigrade in-line before the surface temperature becomes lower than the Ar 3 transformation point, and then the assistantly heated pipe is quenched from a temperature of the Ar 3 transformation point or higher and then tempered at a temperature lower than the Ac 1 transformation point, while keeping the pipe at a temperature of the Ar 3 transformation point or higher from tube-making to quenching:
A =C+(Mn/6)+(Cr/5)+(Mo/3) (1),
wherein, in the equation (1), C, Mn, Cr and Mo each represent % by mass of the respective elements.
8. The method for producing a seamless steel pipe for oil wells according to claim 7 , wherein the tensile strength is not more than 931 MPa.
9. The method for producing a seamless steel pipe for oil wells according to claim 7 , wherein the temperature of assistant heating in-line is the Ac 3 transformation point to 1000 degrees centigrade.
10. A method for producing a seamless steel pipe for oil wells, which comprises the steps of making a pipe by hot-piercing a steel billet having a chemical composition consisting of, on the percent by mass basis, C: 0.1 to 0.20%, Si: 0.05 to 1.0%, Mn: 0.05 to 1.0%, Cr: 0.05 to 1.5%, Mo: 0.05 to 1.0%, Al: 0.10% or less, Ti: 0.002 to 0.05%, B: 0.0003 to 0.005%, V: 0.03 to 0.2%, and one or more element(s) selected from a group of Ca of 0.0003 to 0.005%, Mg of 0.0003 to 0.005% and REM of 0.0003 to 0.005%, with the balance being Fe and impurities, and in the impurities P: 0.025% or less, S: 0.010% or less and N: 0.007% or less, with a value of A determined by the following equation (1) of 0.43 or more followed by elongating and rolling, and then finally rolling at a final rolling temperature adjusted to the Ar 3 transformation point to 1100 degrees centigrade, then following the final rolling step, the finally rolled steel pipe is assistantly heated in a temperature range from the Ar 3 transformation point to 1000 degrees centigrade in-line before the surface temperature becomes lower than the Ar 3 transformation point, and then the assistantly heated pipe is quenched from a temperature of the Ar 3 transformation point or higher and then tempered at a temperature lower than the Ac 1 transformation point, while keeping the pipe at a temperature of the Ar 3 transformation point or higher from tube-making to quenching:
A =C+(Mn/6)+(Cr/5)+(Mo/3) (1),
wherein, in the equation (1), C, Mn, Cr and Mo each represent % by mass of the respective elements.
11. The method for producing a seamless steel pipe for oil wells according to claim 10 , wherein the tensile strength is not more than 931 MPa.
12. The method for producing a seamless steel pipe for oil wells according to claim 10 , wherein the temperature of assistant heating in-line is the Ac 3 transformation point to 1000 degrees centigrade.