Sizing and rheology agents for gypsum stucco systems for water resistant panel production
Emulsions, and processes for making the emulsions, useful for imparting water resistance to gypsum products are disclosed. Process for making the emulsion and gypsum products made from the emulsion are also disclosed. The emulsions of the invention include at least one paraffin wax and a hydrophilic metallic salt. The emulsions of the invention may further include a saponifiable wax substitute for montan wax. The emulsions of the invention may further include a biocide.
1. An emulsion for providing water-resistance to a gypsum product, comprising:
at least one paraffin wax, wherein each paraffin wax of the at least one paraffin wax, comprises a melting point from about 57° C. and about 66° C., an oil content from about 0.1% to less than 1% by weight of the paraffin wax, a flash point from about 200° C. to about 240° C., and an average carbon number of the paraffin from 29 to 32;
a hydrophilic metallic salt selected from the group consisting of magnesium sulfate, potassium sulfate, lithium sulfate, ammonium sulfate, potassium acetate, ammonium heptamolybdate, and combinations thereof; and
water, wherein the emulsion is free of an alkyl phenol.
2. The emulsion of claim 1 , further comprising one or more components selected from the group consisting of a saponifiable wax, an ionic dispersant, an alkali metal hydroxide, and combinations thereof.
3. The emulsion of claim 2 , wherein the saponifiable wax comprises a wax selected from the group consisting of montan wax, carnauba wax, beeswax, bayberry-myrtle wax, candelilla wax, caranday wax, castor bean wax, esparto grass wax, Japan wax, ouricury wax, retamo-ceri mimibi wax, shellac, spermaceti wax, sugar cane wax, wool-lanolin wax, and combinations thereof.
4. The emulsion of claim 2 , wherein the at least one paraffin wax is in an amount of about 25% to about 40% by weight based on the total weight of the emulsion, and wherein the emulsion further comprises a saponifiable wax in an amount of about 2.5% to about 4.5% by weight, based on the total weight of the emulsion.
5. The emulsion of claim 1 , wherein the hydrophilic metallic salt is present in an amount of about 0.05% to about 5% by weight, based on the total weight of the emulsion.
6. The emulsion of claim 1 , wherein the hydrophilic metallic salt comprises magnesium sulfate.
7. The emulsion of claim 2 , wherein the ionic disperser is selected from the group consisting of a polynaphthalenesulfonic acid or salt compound, a lignosulfonate compound, and combinations thereof, and the disperser comprises from about 0.25% to about 5.0% by weight based on the total weight of the emulsion.
8. The emulsion of claim 2 , wherein the alkali metal hydroxide comprises from about 0.5% to about 1.5% by weight, based on the total weight of the emulsion.
9. The emulsion of claim 1 , wherein the emulsion comprises a solids content of at least 30% by weight, based on the total weight of the emulsion.
10. The emulsion of claim 1 , wherein the emulsion comprises a solids content of greater than 45% by weight, based on the total weight of the emulsion.
11. The emulsion of claim 1 , further comprising a biocide.
12. The emulsion of claim 11 , wherein the biocide comprises a heterocycle compound containing nitrogen and sulfur.
13. The emulsion of claim 12 , wherein the heterocycle compound comprises thiabendazole (2-(4-thiazolyl)-1H-benzimidazole).
14. A method for making an emulsion according to claim 1 , comprising the steps of
providing a first mixture comprising at least one paraffin wax, wherein each paraffin wax of the at least one paraffin wax, comprises a melting point from about 57° C. and about 66° C., an oil content from about 0.1% to less than 1% by weight of the wax, a flash point from about 200° C. to about 240° C., and an average carbon number of the paraffin from 29 to 32;
providing a second mixture comprising a hydrophilic metallic salt and water;
combining the first mixture and the second mixture to form a resultant mixture; and
homogenizing the resultant mixture, wherein the hydrophilic metallic salt selected from the group consisting of magnesium sulfate, potassium sulfate, lithium sulfate, ammonium sulfate, potassium acetate, ammonium heptamolybdate, and combinations thereof, and wherein the emulsion is free of an alkyl phenol.
15. The emulsion of claim 1 , wherein the emulsion is free of a starch component.