IP Library Granted Patent US 8,808,815
Granted Patent B2
US 8,808,815 · App. 13/218,900 · Granted Aug 19, 2014

Inkjet-receptive article

Inventors: David K. Hood (Basking Ridge, NJ); Surya Kamin (Skillman, NJ); Karyn Visscher (Morris Plains, NJ)
Assignee: ISP Investments Inc.
D06P5/30B41M5/5218B41M5/508B41M5/52B41M5/506B41M5/5254
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Quick Facts
Patent No.
US 8,808,815
App. No.
13/218,900
Granted
Aug 19, 2014
Kind
B2
Abstract

An inkjet-receptive article comprising a substrate having a coating thereon comprising a vinyl lactam polymer or copolymer and a polymer resin diluent coated from a solvent. A preferred vinyl lactam copolymer is polyvinylcaprolactam (PVCap)—vinyl acetate (VA). Also disclosed are solvent-based compositions for forming an inkjet-receptive coating on a substrate comprising: (i) a vinyl lactam polymer or copolymer; (ii) a solvent; (iii) optionally, a pigment; and (iv) polymer resin diluent.

Claims (9)

1. The inkjet-receptive article comprising a substrate having a coating thereon comprising a vinyl lactam polymer or copolymer and a polymer resin diluent coated from a solvent wherein said vinyl lactam copolymer is polyvinylcaprolactam (PVCap)-vinyl acetate (VA) having a molecular weight of about 6,000g/mol to about 40,000 g/mol.

2. The inkjet-receptive article according to claim 1 wherein said substrate is vinyl plastic, polyester plastic, polyolefin plastic, paper, canvas, glass, ceramic, wood or a metal.

3. The inkjet-receptive article according to claim 1 comprises a pigment selected from the group consisting of silica, barium sulfate, calcium carbonate, titanium dioxide, alumina, silver alone or in combinations thereof.

4. The inkjet-receptive article according to claim 3 wherein said pigment is present in the range of about 5 wt. % to about 90 wt. % of the solid coating.

5. The inkjet-receptive article according to claim 1 comprising a diluent in an amount of about 5 wt. % to about 80 wt. % of the coating.

6. The inkjet-receptive article according to claim 5 wherein said diluent is a powdered polymer resin selected from the group consisting of vinyl chloride-vinyl acetate copolymer, a carboxyl-modified vinyl copolymer, an epoxy-modified vinyl copolymer, a hydroxyl-modified vinyl copolymer, acrylate based copolymers or mixture thereof.

7. The inkjet-receptive article according to claim 1 further comprising a surfactant in amount of up to 4 wt. % of the coating.

8. The inkjet-receptive article according to claim 7 wherein said surfactant is selected from the group consisting of anionic, cationic, non-ionic, amphoteric, alkali metal soaps, ammonium salts of long chain fatty acids, quaternary fatty ammonium halides, quaternary fatty ammonium acetates, quaternary fatty ammonium suphates, or polyethylene oxide chains attached to hydrocarbons.

9. The inkjet-receptive article according to claim 1 , optionally comprising plasticizers, wax, driers, chelating agents, antioxidants, deodorants, biocides, fluorescent agents, reflecting agents, and/or fragrances.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
CHANGE OF NAME Recorded May 22, 2017
From: ISP INVESTMENTS INC.
To: ISP INVESTMENTS LLC
Reel/Frame 042521/0083 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 17, 2014
From: HOOD, DAVID K.; KAMIN, SURYA; VISSCHER, KARYN
To: ISP INVESTMENTS INC.
Reel/Frame 032230/0322 →
RELEASE OF SECURITY AGREEMENT Recorded Aug 28, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND INC.; HERCULES INCORPORATED; ISP INVESTMENTS INC.; ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 031106/0682 →
SECURITY AGREEMENT Recorded Oct 6, 2011
From: ISP INVESTMENTS INC.
To: ASHLAND INC.
Reel/Frame 027023/0500 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA ADDRESS CHANGE EMAIL ADDRESS PREVIOUSLY RECORDED ON REEL 027023 FRAME 0500. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT. Recorded Oct 6, 2011
From: ISP INVESTMENTS INC.
To: THE BANK OF NOVA SCOTIA, GWS LOAN OPERATIONS
Reel/Frame 027027/0526 →
Continuity (3)
Continuation In Part 11546067 · Oct 11, 2006
Provisional Application 61377778 · Aug 27, 2010
Related Publication 20120027964A1 · Feb 2, 2012