Boron-10 compounds for neutron capture layer
View Patent ↗A neutron detector includes a shell bounding an interior volume. A portion of the neutron detector serves as a cathode. The detector includes a central structure located within the interior volume and serving as an anode. The detector includes a boron coating on the interior of the wall wherein at least some of the boron coating is heat diffused into the wall from a boron-containing powder to form the boron coating which is sensitive to neutrons. The detector includes an electrical connector operatively connected to the central structure for transmission of a signal collected by the central structure. An associated method of heat diffusing the boron includes subjecting boron-containing powder to an elevated temperature so that a quantity of the boron-containing powder heat diffuses.
1. A neutron detector including:
a shell bounding an interior volume;
a metallic portion serving as a cathode;
a central structure located within the interior volume and serving as an anode;
a boron coating on the cathode portion wherein at least some of the boron coating is heat diffused into the cathode portion from a boron-containing powder with some boron atoms at depth into the metallic portion to form the boron coating which is sensitive to neutrons; and
an electrical connector operatively connected to the central structure for transmission of a signal collected by the central structure.
2. A The neutron detector according to claim 1 , including:
a shell bounding an interior volume;
a portion serving as a cathode;
a central structure located within the interior volume and serving as an anode;
a boron coating on the cathode portion wherein at least some of the boron coating is heat diffused into the cathode portion from a boron-containing powder to form the boron coating which is sensitive to neutrons; and
an electrical connector operatively connected to the central structure for transmission of a signal collected by the central structure;
wherein all of the boron coating is diffused into the cathode portion.
3. The neutron detector according to claim 1 , wherein the shell includes a bounding wall and the cathode portion is at least part of the wall.
4. The neutron detector according to claim 3 , wherein at least 85% of a surface of the wall is covered by the boron coating.
5. The neutron detector according to claim 3 , wherein the wall is a cylinder.
6. The neutron detector according to claim 1 , wherein the boron coating includes a minimum total boron content of about 97% by weight and a minimum ratio of 10 B isotope to a total boron content of about 98% by weight.
7. The neutron detector according to claim 1 , wherein the boron coating includes less than 7.00×10 −4 grams of a soluble residue per gram of boron.
8. A method of diffusing a boron-containing powder into a substrate surface to create a neutron capture layer for neutron detectors, the method including:
providing an electrically conductive, metallic substrate;
placing the boron-containing powder into contact with the electrically conductive substrate;
subjecting the electrically conductive substrate to a surrounding elevated temperature to simultaneously raise the temperature of all of the boron-containing powder and the entire electrically conductive substrate to an the elevated temperature so that a quantity of the boron-containing powder heat diffuses into the electrically conductive substrate simultaneously over the electrically conductive substrate to which the boron-containing powder is placed in contact with some boron atoms at depth into the electrically conductive substrate forming a boron coating which is sensitive to neutrons; and
incorporating the electrically conductive substrate and the boron coating into a neutron detector as at least a portion of an exterior shell.
9. The method according to claim 8 , wherein all of the boron coating is diffused into the electrically conductive substrate.
10. The method according to claim 8 , wherein the step of providing an electrically conductive substrate includes providing the substrate as at least part of a wall of a shell that bounds an interior volume.
11. The method according to claim 8 , wherein at least 85% of a surface of the wall is covered by the boron coating.
12. The method according to claim 8 , wherein the wall is a cylinder.
13. The method according to claim 8 , wherein the boron coating includes a minimum total boron content of about 97% by weight and a minimum ratio of 10 B isotope to a total boron content of about 98% by weight.
14. The method according to claim 8 , wherein the boron coating includes less than
7.00×10 −4 grams of a soluble residue per gram of boron.
15. The neutron detector according to claim 1 , wherein the shell includes aluminum.
16. The neutron detector according to claim 1 , wherein the some boron atoms are to a uniform depth into the metallic portion.
17. The method according to claim 8 , wherein the some boron atoms diffused into the metallic substrate and the metallic substrate form an intermetallic compound.
18. The method according to claim 8 , wherein the electrically conductive, metallic substrate includes aluminum.
19. The method according to claim 8 , wherein the some boron atoms are to a uniform depth into the metallic portion.
20. The method according to claim 8 , wherein the some boron atoms diffused into the metallic substrate and the metallic substrate form an intermetallic compound, and with the heat diffusion begin at about an annealing temperature of the substrate.