IP Library Granted Patent US 8,764,585
Granted Patent B2
US 8,764,585 · App. 13/220,925 · Granted Jul 1, 2014

Dual core golf ball having a shallow “positive hardness gradient” thermoplastic inner core and a steep “positive hardness gradient” thermoset outer core layer

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Quick Facts
Patent No.
US 8,764,585
App. No.
13/220,925
Granted
Jul 1, 2014
Kind
B2
Abstract

A golf ball including a highly-neutralized thermoplastic inner core layer having a geometric center hardness less than a surface hardness to define a first hardness gradient, an outer core layer formed from a homogenous thermoset composition and having an interior hardness substantially less than an outer surface hardness to define a second hardness gradient, an inner cover layer, and an outer cover layer. Both the first and second hardness gradients are positive and a slope of the second hardness gradient is greater than a slope of the first hardness gradient to define a shallow hardness gradient inner core and a steep hardness gradient outer core layer.

Claims (26)

1. A golf ball comprising:

an inner core layer comprising a thermoplastic highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater, and having a geometric center hardness less than a surface hardness to define a first hardness gradient;

an outer core layer disposed about the inner core, the outer core being formed from a homogenous thermoset composition and having an interior hardness substantially less than an outer surface hardness to define a second hardness gradient;

an inner cover layer disposed about outer core layer; and

an outer cover layer disposed about the inner cover layer,

wherein the first and second hardness gradients are positive and a slope of the second hardness gradient is greater than a slope of the first hardness gradient.

2. The golf ball of claim 1 , wherein a ratio of the slope of the second hardness gradient to the slope of the first hardness gradient is greater than 1.

3. The golf ball of claim 2 , wherein a ratio of the slope of the second hardness gradient to the slope of the first hardness gradient is greater than 1.5.

4. The golf ball of claim 3 , wherein a ratio of the slope of the second hardness gradient to the slope of the first hardness gradient is greater than 2.

5. The golf ball of claim 1 , wherein the inner core layer has an outer diameter of about 0.5 inches to about 1.13 inches.

6. The golf ball of claim 1 , wherein the first hardness gradient is less than 10 Shore C and the second hardness gradient is greater than 10 Shore C.

7. The golf ball of claim 6 , wherein the first hardness gradient is less than 5 Shore C and the second hardness gradient is greater than 15 Shore C.

8. The golf ball of claim 1 , wherein the acid groups of the copolymer are neutralized by 90% or greater.

9. The golf ball of claim 8 wherein the acid groups of the copolymer are neutralized by about 100%.

10. The golf ball of claim 1 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.

11. The golf ball of claim 10 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.

12. The golf ball of claim 10 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.

13. The golf ball of claim 1 , wherein the outer core layer comprises a soft and fast agent.

14. The golf ball of claim 13 , wherein the soft and fast agent comprises a halogenated thiophenol.

15. A golf ball comprising:

an inner core layer consisting of a thermoplastic material and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient of less than 10 Shore D points;

an outer core layer disposed about the inner core, the outer core being formed from a substantially homogenous thermoset composition comprising a diene rubber and having a second positive hardness gradient of 10 Shore D points or greater;

a cover layer disposed outer core layer, the cover layer comprising an inner cover layer comprising an ionomer and an outer cover layer comprising a castable polyurethane or polyurea material.

16. The golf ball of claim 15 , wherein a ratio of the second positive hardness gradient is greater than the first positive hardness gradient.

17. The golf ball of claim 16 , wherein the ratio is greater than 1.5.

18. The golf ball of claim 17 , wherein the ratio is greater than 2.

Assignments (6)
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027346/0897) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0169 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 8, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027346/0897 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 30, 2011
From: SULLIVAN, MICHAEL J.; COMEAU, BRIAN
To: ACUSHNET COMPANY
Reel/Frame 026827/0415 →