Granted Patent B2

US 8,946,494 · App. 13/224,533 · Granted Feb 3, 2015

Abstract

Claims (27)

1. A method for processing biomass to produce biofuel, the method comprising:

decomposing lignocellulosic material into byproduct polymers that include lignin;

decomposing the lignin into targeted chemical fragments that include oxygenates; and

chemically converting the targeted chemical fragments by reacting the targeted chemical fragments with each other to produce biofuel hydrocarbons having from 9 to 16 carbon atoms.

2. The method as recited in claim 1 , including decomposing the lignocellulosic material in a slurry having a pH of 8 or greater at a temperature between 180° C. and 250° C.

3. The method as recited in claim 2 , wherein the slurry is an aqueous slurry that comprises an alkaline component.

4. The method as recited in claim 2 , including decomposing the lignocellulosic material in the presence of a heterogeneous catalyst and at a pressure that is greater than 5 atmospheres.

5. The method as recited in claim 1 , including separating the lignin from the byproduct polymers.

6. The method as recited in claim 5 , including catalytically reforming the byproduct polymers which are substantially free of the lignin, to produce hydrogen.

7. The method as recited in claim 6 , including using the hydrogen from the catalytic reforming in the decomposing of the lignocellulosic material.

8. The method as recited in claim 6 , including using the hydrogen from the catalytic reforming in the decomposition of lignin into the targeted chemical fragments.

9. The method as recited in claim 5 , wherein the byproduct polymers include cellulose, and including decomposing the cellulose to a hydrocarbon material having six carbon atoms using a catalyst material that includes at least one of cobalt, nickel, tin, platinum, rhenium, palladium and combinations thereof.

10. The method as recited in claim 1 , including catalytically converting the targeted chemical fragments of the lignin to produce the hydrocarbons having from 9 to 16 carbon atoms using a catalyst material that includes at least one of cobalt, nickel, tin, platinum, rhenium and palladium or combinations thereof.

11. The method as recited in claim 1 , wherein the targeted chemical fragments of the lignin include 9 or less carbon atoms.

12. A method for processing biomass, the method comprising:

decomposing lignocellulosic material into byproduct polymers that include lignin;

decomposing the lignin into short-chain hydrocarbon fragments having 9 carbon atoms or less; and

chemically converting the short-chain hydrocarbon fragments into a biofuel that includes hydrocarbons having from 9 to 16 carbon atoms by reacting the short-chain hydrocarbon fragments with each other.

13. The method as recited in claim 12 , including separating the lignin from the byproduct polymers.

14. The method as recited in claim 13 , including catalytically reforming the byproduct polymers which are substantially free of the lignin, to produce hydrogen, and using the hydrogen from the catalytic reforming in the decomposing of the lignocellulosic material.

15. The method as recited in claim 1 , wherein the oxygenates include at least one of simple alcohols, cyclic alcohols, and methoxy benzenes, and mixtures thereof.

16. The method as recited in claim 1 , wherein the oxygenates include cyclic alcohols.

17. The method as recited in claim 1 , wherein the oxygenates include at least one of cyclopentanols, cyclohexanols, alkylcyclopentanols, alkylcyclohexanols, phenols, alkylphenols, or mixtures thereof.

18. A method for processing biomass to produce biofuel, the method comprising:

decomposing lignocellulosic material into byproduct polymers that include lignin;

decomposing the lignin into targeted chemical fragments; and

chemically converting the targeted chemical fragments to produce a biofuel.

Assignments (8)