Battery
Provided is a battery which has less tendency to experience delamination or loss of short circuit prevention layer and/or active material layer during manufacture and use. A battery comprising a laminated electrode assembly in which a positive electrode, a negative electrode, and a separator are laminated together; wherein an alumina-containing layer containing γ-alumina particles is formed on at least one species selected from among the group consisting of the positive electrode, the negative electrode, and the separator. The fact that alumina-containing layer(s) is or are made to contain γ-alumina particles makes it possible to obtain high bond strength between alumina-containing layer(s) and electrode(s) comprising metal(s), current collector(s) and/or active material(s) making up electrode(s), and/or separator(s).
1. A battery comprising:
a laminated electrode assembly in which a positive electrode, a negative electrode, and a separator are laminated together; and
an alumina-containing layer comprising γ-alumina particles formed on at least one member selected from among the group consisting of the positive electrode, the negative electrode, and the separator,
wherein a primary particle diameter median value of the 7-alumina particles is not less than 1 nm and not more than 100 nm,
at least one of the positive electrode and the negative electrode includes a current collector and an active material layer,
the active material layer includes a tapered zone having a thickness which tapers off, and a bulk zone,
a thickness of the alumina-containing layer is less than a thickness of the bulk zone of the active material layer, and wherein
a specific surface area of the γ-alumina particles is in a range from 96 m 2 /g to 234 m 2 /g.
2. A battery according to claim 1 , wherein the laminated electrode assembly comprises a wound electrode assembly.
3. A battery according to claim 1 , wherein the battery comprises a nonaqueous electrolyte battery.
4. A battery according to claim 3 , wherein the battery comprises a lithium ion battery.
5. A battery according to claim 1 , wherein the alumina-containing layer is formed on at least either the positive electrode or the negative electrode.
6. A battery according to claim 5 , wherein the alumina-containing layer is formed on at least the positive electrode.
7. A battery according to claim 5 , wherein the alumina-containing layer is disposed so as to face, by way of the separator which intervenes therebetween, an edge of the active material layer of a second electrode of different polarity from a first electrode on which said alumina-containing layer is formed, and
the first electrode and the second electrode are in mutually neighboring relationship by way of the separator which intervenes therebetween.
8. A battery according to claim 5 , wherein an electrode on which the alumina-containing layer is formed includes the current collector and the active material layer, and
said alumina-containing layer is formed so as to be in direct contact with a surface of the current collector.
9. A battery according to claim 8 , wherein the current collector comprises a current collector foil consisting substantially of metal foil.
10. A battery according to claim 9 , wherein the alumina-containing layer is formed so as to be adjacent to and in direct contact with the active material layer, and so as to be in direct contact with a surface of the current collector foil.
11. A battery according to claim 8 , wherein the current collector consists substantially of aluminum.
12. A battery according to claim 9 , wherein a thickness of the alumina-containing layer is less than a thickness of the active material layer formed on a same face of the current collector foil on which said alumina-containing layer is formed.
13. A battery according to claim 9 , wherein the active material layer is subjected to working by a press, and the alumina-containing layer is not subjected to working by the press.
14. A battery according to claim 1 , wherein the alumina-containing layer includes polyvinylidene difluoride.
15. A battery according to claim 14 , wherein a content of the polyvinylidene difluoride within the alumina-containing layer is not less than 45 wt % and not more than 60 wt %.
16. A battery according to claim 1 , wherein a primary particle diameter median value of the γ-alumina particles is not less than 1 nm and not more than 10 nm.
17. A battery according to claim 1 , wherein a tap density of the γ-alumina particles is not less than 0.02 g/cm 3 and not more than 0.6 g/cm 3 .
18. A battery according to claim 1 , wherein a first electrode on which the alumina-containing layer is formed has the active material layer, and the current collector which consists substantially of metal foil,
the alumina-containing layer is formed so as to be adjacent to and in direct contact with the active material layer and in direct contact with a surface of the current collector foil, and is disposed so as to face, by way of the separator which intervenes therebetween, an edge of the active material layer of a second electrode of different polarity from the first electrode on which said alumina-containing layer is formed, and
the first electrode and the second electrode are in mutually neighboring relationship by way of the separator which intervenes therebetween.
19. A battery according to claim 18 , wherein the alumina-containing layer includes polyvinylidene difluoride.
20. A battery according to claim 19 , wherein a content of the polyvinylidene difluoride within the alumina-containing layer is not less than 45 wt % and not more than 60 wt %.