Polycrystalline compacts including nanoparticulate inclusions, cutting elements and earth-boring tools including such compacts, and methods of forming same
Polycrystalline compacts include non-catalytic, non-carbide-forming particles in interstitial spaces between interbonded grains of hard material in a polycrystalline hard material. Cutting elements and earth-boring tools include such polycrystalline compacts. Methods of forming polycrystalline compacts include forming a polycrystalline material including a hard material and a plurality of particles comprising a non-catalytic, non-carbide-forming material. Methods of forming cutting elements include infiltrating interstitial spaces between interbonded grains of hard material in a polycrystalline material with a plurality of non-catalytic, non-carbide-forming particles.
1. A polycrystalline compact, comprising:
a polycrystalline hard material comprising interbonded grains of hard material;
rhenium-containing particles within interstitial spaces between the interbonded grains of the hard material;
a catalyst material comprising at least one of cobalt, nickel, and iron at least partially surrounding the rhenium-containing particles within at least a portion of the interstitial spaces.
2. The polycrystalline compact of claim 1 , wherein the interbonded grains of the hard material comprise interbonded grains of diamond.
3. The polycrystalline compact of claim 1 , wherein the rhenium-containing particles comprise rhenium and at least one other refractory metal.
4. The polycrystalline compact of claim 1 , wherein the rhenium-containing particles consist essentially of rhenium.
5. The polycrystalline compact of claim 1 , wherein the catalyst material comprises cobalt.
6. The polycrystalline compact of claim 1 , wherein the rhenium-containing particles comprise at least one material having a lower thermal conductivity than a thermal conductivity of the catalyst material.
7. The polycrystalline compact of claim 1 , wherein the rhenium-containing particles comprise at least one material having a lower coefficient of thermal expansion than a coefficient of thermal expansion of the catalyst material.
8. The polycrystalline compact of claim 1 , wherein the rhenium-containing particles comprise at least one material having a negative coefficient of thermal expansion.
9. The polycrystalline compact of claim 1 , wherein at least one of the rhenium-containing particles comprises:
a core comprising a first material; and
a coating comprising rhenium directly on the core.
10. The polycrystalline compact of claim 9 , wherein the core comprises at least two particles.
11. The polycrystalline compact of claim 9 , wherein the core comprises cobalt.
12. A polycrystalline compact, comprising:
a plurality of grains of hard material, the plurality of grains of the hard material being interbonded to form a polycrystalline hard material; and
a plurality particles disposed in interstitial spaces between the grains of the hard material, the plurality of particles comprising:
a core comprising a first material;
a first coating comprising rhenium on the core;
a second coating comprising platinum; and
a third coating comprising rhenium.
13. The polycrystalline compact of claim 9 , wherein the core comprises at least one of diamond, zirconium tungstate, and scandium tungstate.
14. The polycrystalline compact of claim 1 , wherein the particles of the plurality of particles are about 0.01% to about 50% by volume of the polycrystalline compact.
15. A cutting element, comprising:
a substrate; and
the polycrystalline compact of claim 1 disposed over the substrate.
16. An earth-boring tool, comprising:
a body; and
a plurality of cutting elements carried by the body, wherein at least one cutting element of the plurality of cutting elements comprises the polycrystalline compact of claim 1 .
17. A method of forming a polycrystalline compact, comprising:
forming a polycrystalline hard material comprising interbonded grains of hard material, rhenium-containing particles within interstitial spaces between the interbonded grains of the hard material, and a catalyst material comprising at least one of cobalt, nickel, and iron at least partially surrounding the rhenium-containing particles within at least a portion of the interstitial spaces.
18. The method of claim 17 , wherein forming a polycrystalline hard material comprises sintering grains of the hard material and the rhenium-containing particles.
19. The method of claim 18 , wherein sintering grains of the hard material and the rhenium-containing particles comprises sintering the grains of the hard material and the rhenium-containing particles in at least two HTHP processes, each process of the at least two HTHP processes being less than about two minutes in duration.
20. The method of claim 17 , wherein forming a polycrystalline hard material comprises infiltrating the interstitial spaces between the interbonded grains of the hard material with the rhenium-containing particles.
21. The method of claim 17 , further comprising selecting each the hard material to comprise diamond.
22. The method of claim 17 , further comprising selecting the rhenium-containing particles to comprise rhenium and at least one other a refractory metal.
23. The method of claim 17 , further comprising selecting the rhenium-containing particles to consist essentially of rhenium.
24. The method of claim 17 , further comprising catalyzing the formation of inter-granular bonds between the interbonded grains of the hard material.
25. The method of claim 17 , further comprising forming a coating comprising rhenium directly on a core comprising a first material to form at least one of the rhenium-containing particles.