Compatibilized biopolyamide-poly(arylene ether) thermoplastic resin
View Patent ↗Disclosed herein are compatibilized polyamide-poly(arylene ether) thermoplastic resin compositions, comprising: (a) about 10 to about 50 weight percent of a poly(arylene ether); (b) about 5 percent to about 20 percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene and a copolymer of ethylene; (c) about 30 to about 60 percent of a biopolyamide; and wherein all weight percents are based on the total weight of the composition; and wherein the biomass carbon content of the resin composition is at least 13 percent as measured by ASTM D6866. Also disclosed are methods for making such resins and articles derived therefrom.
1. A compatibilized polyamide-poly(arylene ether) thermoplastic resin composition, comprising:
(a) about 10 to about 50 weight percent of a poly(arylene ether);
(b) about 5 percent to about 20 percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene and a copolymer of ethylene;
(c) about 30 to about 60 percent of a biopolyamide selected from the group consisting of polyamide-410, polyamide-610, and polyamide-1010, polyamide 10T or mixtures thereof; and
wherein all weight percents are based on the total weight of the composition; and wherein the biomass carbon content of the resin composition is at least 13 percent as measured by ASTM D6866.
2. The thermoplastic resin of claim 1 wherein the hydrogenated block copolymer is a polystyrene-poly(ethylene butylene)-polystyrene block copolymer.
3. The composition of claim 1 , wherein at least a portion of the hydrogenated block copolymer is provided in the form of a styrene-ethylene/propylene-(styrene) polymer.
4. The resin of claim 1 , wherein the biopolyamide is Zytel® RS PA610, Grilamid® 2S (PA610), or Grilamid® 1S (PA 1010).
5. The composition of claim 1 , wherein the biopolyamide has a biobased carbon content of up to 100 percent.
6. The composition of claim 1 , wherein the biopolyamide has an amine end group content of 15 to 70 meq/kg.
7. The composition of claim 1 , wherein the functionalizing agent is a dicarboxylic acid.
8. The composition of claim 1 , wherein the functionalizing agent is selected from the group consisting of citric acid and fumaric acid or mixtures thereof.
9. The composition of claim 1 , further comprising a functionalizing agent selected from the group consisting of potassium iodide and copper (I) iodide, or mixtures thereof.
10. The composition of claim 1 , wherein the biomass carbon content is at least 25 percent as measured by D6866.
11. The composition of claim 1 , wherein the moisture absorption is less than 1.1 weight percent at 23° C. at 50 percent relative humidity after 3750 hours.
12. The composition of claim 1 , wherein the biopolyamide is present as a continuous phase wherein the polyarylene ether and styrene polymer are dispersed individually, independently, or in a mixture thereof to form a dispersion phase having an average particle size diameter of 5 μm or less.
13. The composition of claim 1 , further comprising an electrically conductive agent selected from the group consisting of carbon black and carbon nanotubes, or a combination thereof.
14. The composition of claim 1 further comprising an additive selected from the group consisting of glass fiber, talc, mica, wollastonite, clay, and flame retardants or mixtures thereof.
15. A compatibilized polyamide-poly(arylene ether) thermoplastic resin composition, comprising:
(a) about 10 to about 50 weight percent of a poly(arylene ether);
(b) about 5 percent to about 20 percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene and a copolymer of ethylene;
(c) about 30 to about 60 percent of a biopolyamide selected from the group consisting of a polyamide-410, polyamide-610, polyamide-1010, or mixtures thereof;
(d) about 0.1 to about 2 percent of a Functionalizing Agent selected from the group consisting of citric acid and fumaric acid or mixtures thereof; and
(e) about 0.005 to about 0.015 percent of a stabilizer selected from the group consisting of potassium iodide and copper (I) iodide and mixtures thereof;
wherein all weight percents are based on the total weight of the composition; and wherein the biomass carbon content of the resin is at least 13 percent as measured by D6866.
16. A process for making a compatibilized polyamide-poly(arylene ether) thermoplastic resin composition, comprising:
(a) about 10 to about 50 weight percent of a poly(arylene ether);
(b) about 5 percent to about 20 percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene and a copolymer of ethylene;
(c) about 30 to about 60 percent of a biopolyamide selected from the group consisting of a polyamide-410, polyamide-610, polyamide-1010, or mixtures thereof;
(d) about 0.1 to about 2 percent of a Functionalizing Agent selected from the group consisting of citric acid and fumaric acid or mixtures thereof; and
(e) about 0.005 to about 0.015 percent of a stabilizer selected from the group consisting of potassium iodide and copper (I) iodide and mixtures thereof;
wherein all weight percents are based on the total weight of the composition; and wherein the biomass carbon content of the resin is at least 13 percent as measured by D6866;
wherein the process comprises:
(i) extruding a mixture comprising components (a) (b), (d), and (e);
(ii) adding component (c) added downstream to the extruding mixture of step (i).
17. The process of claim 16 , wherein the extruder was set with a barrel temperature of 150 to 285° C. with the screw rotating at 400 rotation per minute (rpm) and a vacuum of 100 millibar (mbar) to 500 mbar and a torque between 60 to 70 percent.
18. A compatibilized polyimide-poly(arylene ether) thermoplastic resin composition, comprising:
(a) about 10 to about 50 weight percent of a poly(arylene ether);
(b) about 5 percent to about 20 percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene and a copolymer of ethylene;
(c) about 30 to about 60 percent of a biopolyamide selected from the group consisting of a polyamide-410, polyamide-610, polyamide-1010, or mixtures thereof;
(d) about 0.1 to about 2 percent of a Functionalizing Agent selected from the group consisting of citric acid and fumaric acid or mixtures thereof; and
(e) about 0.005 to about 0.015 percent of a stabilizer selected from the group consisting of potassium iodide and copper (I) iodide and mixtures thereof;
wherein all weight percents are based on the total weight of the composition; and wherein the biomass carbon content of the resin is at least 13 percent as measured by ASTM D6866;
prepared by a process comprising:
(i) extruding a mixture comprising components (a) (b), (d), and (e);
(ii) adding component (c) added downstream to the extruding mixture of step (i).
19. An article comprising a thermoplastic resin composition, wherein the thermoplastic resin comprises:
(a) about 10 to about 50 weight percent of a poly(arylene ether);
(b) about 5 percent to about 20 percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene and a copolymer of ethylene;
(c) about 30 to about 60 percent of a biopolyamide; and
(d) about 0.1 to about 2 percent of a Functionalizing Agent;
wherein all weight percents are based on the total weight of the composition; and wherein the biomass carbon content of the resin is at least 13 percent as measured by ASTM D6866.