IP Library Granted Patent US 8,497,503
Granted Patent B2
US 8,497,503 · App. 13/231,090 · Granted Jul 30, 2013

Manufacture of photovoltaic devices

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Quick Facts
Patent No.
US 8,497,503
App. No.
13/231,090
Granted
Jul 30, 2013
Kind
B2
Abstract

A method and apparatus for depositing a film on a substrate includes subjecting material to an energy beam.

Claims (25)

1. A photovoltaic device comprising:

a glass superstrate having a first surface for receiving solar radiation;

an energy beam deposited copper indium diselenide layer opposite the first surface of the superstrate glass, and

an encapsulant comprising at least one of ethylene propylene diene copolymer, polyisobutylene and a rubber material,

wherein the copper indium diselenide layer is deposited opposite the first surface of the superstrate glass at substantially atmospheric pressure.

2. The photovoltaic device of claim 1 , further comprising a transparent conducting layer on the superstrate glass.

3. The photovoltaic device of claim 1 , wherein the copper indium diselenide includes copper indium gallium diselenide.

4. The photovoltaic device of claim 1 , wherein the copper indium diselenide includes copper indium gallium diselenide.

5. The photovoltaic device of claim 1 , wherein the energy beam is a radio frequency beam.

6. The photovoltaic device of claim 5 , wherein the radio frequency beam includes microwave radiation.

7. A method for manufacturing a photovoltaic device comprising:

providing a glass superstrate having a first surface for receiving solar radiation;

exposing a starting material to an energy beam at substantially atmospheric pressure, thereby causing the starting material to vaporize;

forming a semiconductor layer of the vaporized starting material opposite the first surface of a superstrate glass; and

forming an encapsulant at least partially encapsulating the device, the encapsulant comprising at least one of ethylene propylene diene copolymer, polyisobutylene and a rubber material.

8. The method of claim 7 , wherein the energy beam has a power of between 50 and 500 watts.

9. The method of claim 7 , further comprising depositing a transparent conducting layer onto the superstrate glass.

10. The method of claim 9 , wherein the transparent conducting layer includes a zinc oxide, a tin oxide or an indium oxide.

11. The method of claim 9 , further comprising depositing a cadmium sulfide layer onto the transparent conducting layer.

12. The method of claim 9 , further comprising depositing at least one additional semiconductor layer opposite the surface receiving solar radiation of the superstrate glass.

13. The method of claim 7 , wherein the energy beam is a radio frequency beam.

14. The method of claim 13 , wherein the radio frequency beam includes microwave radiation.

15. The method of claim 7 , wherein the method occurs at a pressure between about 0.5 atmospheres and about 1.5 atmospheres.

16. The method of claim 7 , wherein the method occurs at a pressure between about 0.8 atmospheres and about 1.2 atmospheres.

17. The method of claim 7 , wherein the method occurs at a pressure between about 0.9 atmospheres and about 1.1 atmospheres.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Feb 13, 2026
From: JPMORGAN CHASE BANK, N.A.
To: FIRST SOLAR, INC.
Reel/Frame 074858/0364 →
SECURITY INTEREST Recorded Jul 10, 2023
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 064237/0462 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Nov 15, 2021
From: JPMORGAN CHASE BANK, N.A.
To: FIRST SOLAR, INC.
Reel/Frame 058132/0566 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Nov 15, 2021
From: JPMORGAN CHASE BANK, N.A.
To: FIRST SOLAR, INC.
Reel/Frame 058132/0261 →
PATENT SECURITY AGREEMENT Recorded Jul 12, 2017
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 043177/0581 →
CORRECTIVE ASSIGNMENT TO CORRECT THE PATENT APPLICATION 13/895113 ERRONEOUSLY ASSIGNED BY FIRST SOLAR, INC. TO JPMORGAN CHASE BANK, N.A. ON JULY 19, 2013 PREVIOUSLY RECORDED ON REEL 030832 FRAME 0088. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT PATENT APPLICATION TO BE ASSIGNED IS 13/633664. Recorded Sep 19, 2014
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 033779/0081 →
SECURITY AGREEMENT Recorded Jul 19, 2013
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 030832/0088 →