IP Library Granted Patent US 9,012,558
Granted Patent B2
US 9,012,558 · App. 13/231,629 · Granted Apr 21, 2015

Moisture-curable, elastomeric, translucent silicone waterproofing coating and method of making the same

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Quick Facts
Patent No.
US 9,012,558
App. No.
13/231,629
Granted
Apr 21, 2015
Kind
B2
Abstract

There is provided herein a one-part, moisture-curable, elastomeric, translucent coating composition comprising: (a) a di-hydroxy-terminated dimethylpolysiloxane polymer; (b) a reinforcing filler; (c) an organic solvent; (d) a polyalkoxysilane crosslinking agent; (e) an organo-silane adhesion promoter; and, (f) a titanium condensation cure catalyst, wherein the composition is a one-part, moisture-curable, elastomeric, translucent coating composition, and a process of making the composition.

Claims (58)

1. A one-part, moisture-curable, elastomeric, translucent coating composition comprising:

(a) a di-hydroxy-terminated dimethylpolysiloxane polymer having a viscosity of less than about 5,000 cps at 25 degrees Celsius;

(b) a reinforcing filler;

(c) an organic solvent;

(d) a polyalkoxysilane crosslinking agent;

(e) an organo-silane adhesion promoter; and,

(f) a titanium condensation cure catalyst,

wherein the composition is a one-part, moisture-curable, elastomeric, translucent coating composition.

2. The coating composition of claim 1 wherein the reinforcing filler (b) is fumed silica filler doubly treated with D4 and hexamethyldisilazane.

3. The coating composition of claim 1 wherein the organic solvent (c) is a linear aliphatic hydrocarbon.

4. The coating composition of claim 1 wherein the polyalkoxysilane crosslinking agent (d) is methyltrimethoxysilane.

5. The coating composition of claim 1 wherein the organo-silane adhesion promoter (e) is tris-trimethoxysilylpropylisocyanurate.

6. The coating composition of claim 1 wherein the titanium curing catalyst is di-isopropyl titanium bis-acetylacetonate.

7. The coating composition of claim 1 which has a stability of at least 1 month.

8. A process of forming a one-part, moisture-curable, elastomeric, translucent coating composition comprising:

combining the parts;

(a) a di-hydroxy-terminated dimethylpolysiloxane polymer having a viscosity of less than about 5,000 cps at 25 degrees Celsius;

(b) a reinforcing filler;

(c) an organic solvent;

(d) a polyalkoxysilane crosslinking agent;

(e) an organo-silane adhesion promoter; and,

(f) a titanium condensation cure catalyst

to provide a one-part moisture-curable, elastomeric, translucent coating composition.

9. The process of claim 8 further comprising:

applying the combined parts of the coating composition onto a substrate; and,

exposing the coating composition to sufficient moisture to provide for curing of the one-part, moisture-curable, elastomeric, translucent coating composition into a cured coating onto the substrate.

10. A substrate containing the cured coating made by the process of claim 9 .

11. The substrate of claim 10 wherein the coating has a modulus at 50% elongation per ASTM D-412 of from about 40 psi to about 150 psi.

12. The substrate of claim 10 wherein the coating has a Shore A durometer value per ASTM C-661 of from about 10 to about 40.

13. The substrate of claim 10 wherein the coating has a translucency which is greater than that of coating of an identical substrate coated with an identical coating composition.

14. The substrate of claim 10 wherein the coating has one or more of a durability or UV resistance which is greater than that of coating of an identical substrate coated with an identical coating composition.

15. The substrate of claim 10 wherein the coating provides water proofing protection for a longer period of time than that of coating of an identical substrate coated with an identical coating composition.

16. The substrate of claim 10 wherein the coating maintains the original appearance of the substrate more so than that of an identical substrate coated with an identical coating composition.

17. A method of treating a building façade comprising applying to an exterior portion of the building façade a one-part, moisture-curable, elastomeric, translucent coating composition comprising:

(a) a di-hydroxy-terminated dimethylpolysiloxane polymer;

(b) a reinforcing tiller;

(c) an organic solvent;

(d) a polyalkoxysilane crosslinking agent;

(e) an organo-silane adhesion promoter; and,

(f) a titanium condensation cure catalyst,

and curing the coating composition to provide a cured coating on the building facade.

18. A building facade containing the cured coating of claim 17 .

19. A one-part, moisture-curable, elastomeric, translucent coating composition comprising:

(a) a di-hydroxy-terminated dimethylpolysiloxane polymer;

(b) a reinforcing filler which is fumed silica filler doubly treated with D4 and hexamethyldisilazane;

(c) an organic solvent;

(d) a polyalkoxysilane crosslinking agent;

(e) an organo-silane adhesion promoter; and,

(f) a titanium condensation cure catalyst,

wherein the composition is a one-part, moisture-curable, elastomeric, translucent coating composition.

20. A one-part, moisture-curable, elastomeric, translucent coating composition comprising:

(a) a di-hydroxy-terminated dimethylpolysiloxane polymer;

(b) a reinforcing filler;

(c) an organic solvent;

(d) a polyalkoxysilane crosslinking agent;

(e) an organo-silane adhesion promoter; and,

(f) a titanium condensation cure catalyst which is di-isopropyl titanium bis-acetylacetonate,

wherein the composition is a one-part, moisture-curable, elastomeric, translucent coating composition.

Assignments (20)
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (063213/0472) Recorded Oct 22, 2025
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 073168/0715 →
RELEASE OF SECURITY INTEREST Recorded Jul 18, 2025
From: KOOKMIN BANK NEW YORK BRANCH
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 072039/0906 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS Recorded Mar 31, 2023
From: BNP PARIBAS
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 063259/0133 →
FIRST LIEN TERM LOAN PATENT SECURITY AGREEMENT Recorded Mar 31, 2023
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 063213/0472 →
RELEASE OF SECURITY INTEREST Recorded Mar 30, 2023
From: KOOKMIN BANK NEW YORK
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 063197/0373 →
SECURITY INTEREST Recorded Mar 30, 2023
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: KOOKMIN BANK NEW YORK BRANCH
Reel/Frame 063197/0475 →
RELEASE OF SECURITY INTEREST Recorded Nov 11, 2020
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 054336/0023 →
ABL PATENT AGREEMENT Recorded Jun 5, 2019
From: MOMENTIVE PERFORMANCE MATERIALS INC.; MOMENTIVE PERFORMANCE MATERIALS GMBH
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 049388/0252 →
SECOND LIEN TERM LOAN PATENT AGREEMENT Recorded Jun 5, 2019
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: KOOKMIN BANK, NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 049388/0220 →
FIRST LIEN TERM LOAN PATENT AGREEMENT Recorded Jun 5, 2019
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: BNP PARIBAS, AS ADMINISTRATIVE AGENT
Reel/Frame 049387/0782 →
RELEASE OF SECURITY INTEREST Recorded May 15, 2019
From: BOKF, NA
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 049194/0085 →
RELEASE OF SECURITY INTEREST Recorded May 15, 2019
From: BOKF, NA
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 049249/0271 →
NOTICE OF CHANGE OF COLLATERAL AGENT - ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Mar 6, 2015
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
To: BOKF, NA, AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 035136/0457 →
NOTICE OF CHANGE OF COLLATERAL AGENT - ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY - SECOND LIEN Recorded Mar 6, 2015
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
To: BOKF, NA, AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 035137/0263 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Nov 20, 2014
From: JPMORGAN CHASE BANK, N.A.
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 034410/0607 →
SECURITY INTEREST Recorded Oct 27, 2014
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS COLLATERAL AGENT
Reel/Frame 034066/0662 →
SECURITY INTEREST Recorded Oct 27, 2014
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS COLLATERAL AGENT
Reel/Frame 034066/0570 →
SECURITY INTEREST Recorded Apr 22, 2014
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 032754/0774 →
SECURITY INTEREST Recorded Apr 22, 2014
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 032736/0552 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 14, 2011
From: LUCAS, GARY MORGAN
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 026901/0070 →