IP Library Granted Patent US 8,536,224
Granted Patent B2
US 8,536,224 · App. 13/236,462 · Granted Sep 17, 2013

Pharmaceutical and nutraceutical compositions of abscisic acid

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Quick Facts
Patent No.
US 8,536,224
App. No.
13/236,462
Granted
Sep 17, 2013
Kind
B2
Abstract

The invention relates to compositions comprising abscisic acid, and/or salts, derivatives and analogs thereof, and methods of pharmaceutical and/or nutraceutical use.

Claims (40)

1. A method of treating prostate enlargement comprising administering to a patient in need thereof a therapeutically effective amount of: i) abscisic acid; ii) a compound of structure 1

wherein R 1 is selected form the group consisting of ethynyl, ethenyl, cyclopropyl, and trifluoromethyl, R 2 is selected from the group consisting of hydrogen and a lower alkyl, and R 1 is in a cis- relationship to the alcoholic hydroxyl group;

a compound of structure 2

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl; or

a compound of structure 3

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl;

wherein a cis- or trans- double bond is at a 2 nd position of a side chain, a trans- double bond or a triple bond is at a 4 th position of the side chain, the alcoholic hydroxyl groups have S—, R— or an R,S— mixture stereochemistry, and the lower alkyl is an alkyl group containing 1 to 4 carbon atoms in a straight or branched chain; or

iii) isomeric forms, racemic mixtures, enol forms, solvated forms, unsolvated forms, prodrugs, ester derivatives, ether derivatives, or salts thereof.

2. A method of increasing post-natal weight gain comprising administering to a patient in need thereof, or lactating parent of patient in need thereof, a therapeutically effective amount of: i) abscisic acid; ii) a compound of structure 1

wherein R 1 is selected form the group consisting of ethynyl, ethenyl, cyclopropyl, and trifluoromethyl, R 2 is selected from the group consisting of hydrogen and a lower alkyl, and R 1 is in a cis- relationship to the alcoholic hydroxyl group;

a compound of structure 2

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl; or

a compound of structure 3

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl;

wherein a cis- or trans- double bond is at a 2 nd position of a side chain, a trans- double bond or a triple bond is at a 4 th position of the side chain, the alcoholic hydroxyl groups have S—, R— or R,S— mixture stereochemistry, and the lower alkyl is an alkyl group containing 1 to 4 carbon atoms in a straight or branched chain; or

iii) isomeric forms, racemic mixtures, enol forms, solvated forms, unsolvated forms, prodrugs, ester derivatives, ether derivatives, or salts thereof.

3. A method of increasing post-natal survival rates of offspring comprising administering to a parent or offspring a therapeutically effective amount of: i) abscisic acid; ii) a compound of structure 1

wherein R 1 is selected form the group consisting of ethynyl, ethenyl, cyclopropyl, and trifluoromethyl, R 2 is selected from the group consisting of hydrogen and a lower alkyl, and R 1 is in a cis- relationship to the alcoholic hydroxyl group;

a compound of structure 2

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl; or

a compound of structure 3

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl;

wherein a cis- or trans- double bond is at a 2 nd position of a side chain, a trans- double bond or a triple bond is at a 4 th position of the side chain, the alcoholic hydroxyl groups have S—, R— or R,S— mixture stereochemistry, and the lower alkyl is an alkyl group containing 1 to 4 carbon atoms in a straight or branched chain; or

iii) isomeric forms, racemic mixtures, enol forms, solvated forms, unsolvated forms, prodrugs, ester derivatives, ether derivatives, or salts thereof.

4. A method of increasing immunological function due to a reduction in spleen size comprising administering to a patient in need thereof a therapeutically effective amount of: i) abscisic acid; ii) a compound of structure 1

wherein R 1 is selected form the group consisting of ethynyl, ethenyl, cyclopropyl, and trifluoromethyl, R 2 is selected from the group consisting of hydrogen and a lower alkyl, and R 1 is in a cis- relationship to the alcoholic hydroxyl group;

a compound of structure 2

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl; or

a compound of structure 3

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl;

wherein a cis- or trans- double bond is at a 2 nd position of a side chain, a trans- double bond or a triple bond is at a 4 th position of the side chain, the alcoholic hydroxyl groups have S—, R— or R,S— mixture stereochemistry, and the lower alkyl is an alkyl group containing 1 to 4 carbon atoms in a straight or branched chain; or

iii) isomeric forms, racemic mixtures, enol forms, solvated forms, unsolvated forms, prodrugs, ester derivatives, ether derivatives, or salts thereof.

5. A method of treating attention deficit disorder comprising administering to a patient in need thereof a therapeutically effective amount of: i) abscisic acid; ii) a compound of structure 1

wherein R 1 is selected form the group consisting of ethynyl, ethenyl, cyclopropyl, and trifluoromethyl, R 2 is selected from the group consisting of hydrogen and a lower alkyl, and R 1 is in a cis- relationship to the alcoholic hydroxyl group;

a compound of structure 2

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl; or

a compound of structure 3

wherein R 1 is selected from the group consisting of hydrogen and a lower alkyl;

wherein a cis- or trans- double bond is at a 2 nd position of a side chain, a trans- double bond or a triple bond is at a 4 th position of the side chain, the alcoholic hydroxyl groups have S—, R— or R,S— mixture stereochemistry, and the lower alkyl is an alkyl group containing 1 to 4 carbon atoms in a straight or branched chain; or

iii) isomeric forms, racemic mixtures, enol forms, solvated forms, unsolvated forms, prodrugs, ester derivatives, ether derivatives, or salts thereof.

Assignments (2)
MERGER Recorded May 11, 2017
From: VALENT BIOSCIENCES CORPORATION
To: VALENT BIOSCIENCES LLC
Reel/Frame 042446/0583 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 18, 2011
From: HERRERO, MARIA PILAR; SHAFER, WARREN E.
To: VALENT BIOSCIENCES CORPORATION
Reel/Frame 027254/0256 →