Osmotically driven membrane processes and systems and methods for draw solute recovery
The invention relates to osmotically driven membrane processes and systems and methods for recovering draw solutes in the osmotically driven membrane processes. Osmotically driven membrane processes involve the extraction of a solvent from a first solution to concentrate solute by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. Draw solute recovery may be carried out by various means including with the use of a membrane device. The draw solute recovery may also include the use of multi-stage solute recovery using distillation columns and/or membranes, where the recovery may be assisted by a heat pump.
1. An apparatus for recovering draw solution solutes from an osmotically driven membrane system, the apparatus comprising:
an osmotically driven membrane system comprising a semi-permeable membrane having a first side in fluid communication with a first solution and a second side in fluid communication with a source of concentrated draw solution, where the osmotically driven membrane system receives the first solution and the concentrated draw solution and outputs a concentrated first solution and a dilute draw solution;
a first distillation apparatus in fluid communication with the second side of the semi-permeable membrane, the apparatus comprising:
a first inlet coupled to a first source of the dilute draw solution for introducing a portion of the dilute draw solution into a first end of the first distillation apparatus;
a first heat transfer means coupled to the first distillation apparatus at a second end, the first heat transfer means having an inlet coupled to a first source of thermal energy and an outlet coupled to the first distillation apparatus for directing thermal energy to the first distillation apparatus to cause draw solutes within the dilute draw solution in the first distillation apparatus to vaporize;
a first outlet for removing the vaporized draw solution solutes from the first distillation apparatus; and
a second outlet for removing a bottoms product from the first distillation apparatus;
a compressor coupled to the first outlet of the first distillation apparatus for receiving the vaporized draw solution solutes; and
a second distillation apparatus in fluid communication with the first side of the semi-permeable membrane and configured for parallel operation with the first distillation apparatus, the second distillation apparatus comprising:
a first inlet coupled to a source of the concentrated first solution for introducing a portion of the concentrated first solution into a first end of the second distillation apparatus;
a second heat transfer means coupled to the second distillation apparatus at a second end, the second heat transfer means having an inlet coupled to the compressor for receiving the compressed vaporized draw solution solutes therefrom for use as a second source of thermal energy, a first outlet coupled to the second distillation apparatus for directing the second source of thermal energy to the second distillation apparatus to cause any draw solution solutes in the second distillation apparatus to vaporize, and a second outlet configured to return the vaporized draw solution solutes from the first distillation apparatus condensed within the second heat transfer means to the osmotically driven membrane system;
a first outlet for removing the vaporized draw solution solutes from the second distillation apparatus; and
a second outlet for removing a bottoms product from the second distillation apparatus.
2. The apparatus of claim 1 , further comprising:
a second compressor coupled to the first outlet of the second distillation column; and
at least a third distillation apparatus in fluid communication with the second side of the semi-permeable membrane, the apparatus comprising:
a first inlet coupled to a second source of the dilute draw solution for introducing a portion of dilute draw solution into a first end of the third distillation column;
a third heat transfer means coupled to the third distillation column at a second end, the third heat transfer means having an inlet coupled to the second compressor for receiving the vaporized draw solutes therefrom for use as a third source of thermal energy for use with the third distillation column, a first outlet coupled to the third distillation column for directing the third source of thermal energy to the third distillation column to cause draw solutes within the dilute draw solution in the third distillation chamber to vaporize, and a second outlet configured to return the vaporized draw solutes from the second distillation column condensed within the third heat transfer means to the osmotically driven membrane system;
a first outlet for removing the vaporized draw solution solutes from the third distillation column; and
a second outlet for removing a bottoms product from the third distillation column.
3. The apparatus of claim 2 , wherein the first and third distillation apparatus are configured for series operation and the second source of the dilute draw solution is the bottoms product of the first distillation column.
4. The apparatus of claim 1 , wherein at least one of the first distillation apparatus or the second distillation apparatus comprises a membrane distillation apparatus.
5. The apparatus of claim 1 further comprising at least one recycling system disposed downstream of at least one of the first distillation apparatus or the second distillation apparatus.
6. The apparatus of claim 5 , wherein the at least one recycling system comprises at least one of a compressor or an eductor.
7. The apparatus of claim 5 , wherein the at least one recycling system comprises an absorbing system.
8. The apparatus of claim 7 , wherein the absorbing system comprises at least one of a membrane contactor or a packed column.
9. The apparatus of claim 7 , wherein the absorbing system comprises an absorbent comprising at least one of dilute draw solution or a product solvent.
10. The apparatus of claim 7 , wherein the absorbing system comprises a catalyst.