Moulding compound for mouldings with high weather resistance
View Patent ↗A molding compound comprises a copolymer (I)a), produced by polymerization of 90-100% by weight methylmethacrylate, styrene and malic acid anhydride, and optionally 0-10% by weight additional monomers which can be copolymerized with methylmethacrylate, a (co)polymer (II)b), produced by polymerization of 80-100% by weight methylmethacrylate and optionally 0-20% by weight additional monomers which can be copolymerized with methylmethacrylate, and has a solution viscosity in chloroform at 25° C. (ISO 1628 Part 6) of 50 to 55 ml/g, as well as c) optional conventional additives, auxiliary agents and/or fillers. The molding compound is characterized in that the copolymer (I) has a solution viscosity in chloroform at 25° C. (ISO 1628 Part) of 55 ml/g or less. Also disclosed are moldings produced by thermoplastic processing of the molding compound and their uses.
1. A molding composition, comprising:
a) a copolymer (I), containing from 90 to 100% by weight of polymerized methyl methacrylate, styrene, and maleic anhydride, and, optionally, from 0 to 10% by weight of other polymerized monomers copolymerizable with methyl methacrylate,
b) a (co)polymer (II), containing from 96 to 99.5% by weight of polymerized methyl methacrylate and from 0.5 to 4% by weight of polymerized methyl acrylate, whose solution viscosity in chloroform at 25° C. (ISO 1628—Part 6) is from 50 to 55 ml/g, and
c) optionally conventional additives, auxiliaries, and/or fillers,
wherein
the solution viscosity of the copolymer (I) in chloroform at 25° C. (ISO 1628—Part 6) is less than or equal to 55 ml/g.
2. The molding composition as claimed in claim 1 , wherein the molding composition or a test specimen produced from the molding composition has the following properties simultaneously:
a Vicat softening temperature VST (ISO 306-B50) of at least 109° C.,
a melt index MVR (ISO 1133, 230° C./3.8 kg) of from 2.5 to 5.0 cm 3 /10 min,
Xenotest weathering resistance (DIN EN ISO 4893, Part 2) after 10,000 hours characterized via a yellowness index (DIN 6167) of less than or equal to 2.0.
3. The molding composition as claimed in claim 1 , wherein the increase in the yellowness index (DIN 6167) of a test specimen produced from the molding composition is not more than 1.5 units after Xenotest weathering (DIN EN ISO 4893, Part 2) for 10,000 hours.
4. The molding composition as claimed in claim 1 , wherein when the Taber 203 scratch hardness of a test specimen produced from the molding composition is determined using an applied force of 3.0 N the value obtained is not more than 3 μm.
5. The molding composition as claimed in claim 1 , wherein the copolymer (I) and the (co)polymer (II) are present in a ratio of from 95 to 5 to 5 to 95 parts by weight.
6. The molding composition as claimed in claim 1 , wherein the copolymer (I) has been polymerized from
from 50 to 90% by weight of methyl methacrylate,
from 10 to 20% by weight of styrene, and
from 5 to 15% by weight of maleic anhydride.
7. The molding composition as claimed in claim 1 , wherein the proportion of the conventional additives, auxiliaries, and/or fillers is not more than 10% by weight.
8. The molding composition as claimed in claim 1 , wherein a lubricant is present as auxiliary.
9. The molding composition as claimed in claim 1 , wherein stearyl alcohol is present as auxiliary.
10. The molding composition as claimed in claim 1 , wherein the molding composition or a test specimen produced from the molding composition has the following properties simultaneously:
a Vicat softening temperature VST (ISO 306-B50) of at least 109° C., and
a melt index MVR (ISO 1133, 230° C./3.8 kg) of from 2.5 to 5.0 cm 3 /10 min.
11. The molding composition as claimed in claim 1 , wherein copolymer (I) has a weight-average molecular weight of 95,000 g/mol or less.
12. The molding composition as claimed in claim 11 , wherein copolymer (II) has a weight-average molecular weight of 80,000 to 200,000 g/mol.
13. One or more molded, extruded, coextruded, laminated or lacquered parts, produced entirely or to some extent from the molding composition as claimed in claim 1 via thermoplastic processing, coextrusion, lamination, or lacquering.
14. The one or more extruded parts as claimed in claim 13 , wherein the parts are solid sheets, corrugated sheets, panels having cavities, multiple-web sandwich panels, twin-web sandwich panels, triple-web sandwich panels, quadruple-web sandwich panels, sandwich panels with lattice geometry, or other sandwich panels.
15. The one or more molded parts as claimed in claim 13 , wherein the parts are parts of household devices, parts of communications devices, parts of equipment for hobbies, parts of equipment for sports, bodywork parts, parts of bodywork parts in automobile construction, parts of bodywork parts in shipbuilding, parts of bodywork parts in aircraft construction, lamp covers, instrument covers, tachometer covers, panels, or decorative strips.
16. The one or more molded parts as claimed in claim 13 , wherein said molded parts comprise at least one coextruded, laminated, or lacquered layer.
17. A method comprising producing one or more molded parts, thermoplastic processed parts, coextruded parts, laminated parts or lacquered parts from the molding composition according to claim 1 .
18. A method of coating one or more surfaces of wood, comprising coating at least one wood surface with a molding composition, comprising:
a) a copolymer (I), containing from 90 to 100% by weight of polymerized methyl methacrylate, styrene, and maleic anhydride, and, optionally, from 0 to 10% by weight of other polymerized monomers copolymerizable with methyl methacrylate,
b) a (co)polymer (II), containing from 96 to 99.5% by weight of polymerized methyl methacrylate and from 0.5 to 4% by weight of polymerized methyl acrylate, whose solution viscosity in chloroform at 25° C. (ISO 1628—Part 6) is from 50 to 55 ml/g, and
c) optionally conventional additives, auxiliaries, and/or fillers,
wherein
the solution viscosity of the copolymer (I) in chloroform at 25° C. (ISO 1628—Part 6) is less than or equal to 55 ml/g, and
the Vicat softening temperature VST (ISO 306-B50) of the copolymer (II) is at least 107° C.
19. The method as claimed in claim 18 , wherein the molding composition or a test specimen produced from the molding composition has the following properties simultaneously:
a Vicat softening temperature VST (ISO 306-B50) of at least 109° C., and
a melt index MVR (ISO 1133, 230° C./3.8 kg) of from 2.5 to 5.0 cm 3 /10 min.
20. A method of impregnating wood, comprising impregnating wood with a molding composition, comprising:
a) a copolymer (I), containing from 90 to 100% by weight of polymerized methyl methacrylate, styrene, and maleic anhydride, and, optionally, from 0 to 10% by weight of other polymerized monomers copolymerizable with methyl methacrylate,
b) a (co)polymer (II), containing from 96 to 99.5% by weight of polymerized methyl methacrylate and from 0.5 to 4% by weight of polymerized methyl acrylate, whose solution viscosity in chloroform at 25° C. (ISO 1628—Part 6) is from 50 to 55 ml/g, and
c) optionally conventional additives, auxiliaries, and/or fillers,
wherein
the solution viscosity of the copolymer (I) in chloroform at 25° C. (ISO 1628—Part 6) is less than or equal to 55 ml/g, and
the Vicat softening temperature VST (ISO 306-B50) of the copolymer (II) is at least 107° C.
21. The method as claimed in claim 20 , wherein the molding composition or a test specimen produced from the molding composition has the following properties simultaneously:
a Vicat softening temperature VST (ISO 306-B50) of at least 109° C., and
a melt index MVR (ISO 1133, 230° C./3.8 kg) of from 2.5 to 5.0 cm 3 /10 min.