Granted Patent B2

US 10,066,097 · App. 13/243,533 · Granted Sep 4, 2018

Abstract

Claims (67)

1. A thermofusible composition in the form of pellets and/or powder, with a particle size of 1400 μm or less comprising:

(i) from about 40 to about 70 weight percent of a selectively hydrogenated styrenic block copolymer (HSBC) as defined hereinafter,

(ii) from 0 to about 15 weight percent of a propylene homopolymer and/or propylene copolymer (PP),

(iii) from about 1 to about 30 weight percent of a polybutylene (PB); wherein the polybutylene comprises wherein the PB comprises a butylene homopolymer (iiia) and a butylene copolymer (iiib), and a ratio of butylene homopolymer (iiia) vs. butylene copolymer (iiib) is from about 1:1 to about 10:1 and wherein a melt flow rate of (iiia), (iiib), or (iiic) is from about 0.1 to about 500 g/10 min measured at 190° C. employing a 2.16 kg weight,

(iv) from 0 to about 20 weight percent of a plasticizing oil selected from naphthenic oils and paraffinic oils,

(v) from 0 to about 10 weight percent of a scratching agent,

(vi) from 0 to about 10 weight percent of a dusting agent, and

(vii) from 0 to about 10 weight percent of one or more additives,

wherein the HSBC (i) is a linear or branched hydrogenated block copolymer having the general configuration A-B-A, (A-B)n, (A-B-A)n, (A-B-A)nX, (A-B)nX or mixtures thereof, where n is an integer from 2 to about 30, and X is coupling agent residue and wherein:

a. prior to hydrogenation each A block is a mono alkenyl arene polymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene;

b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;

c. each A block has a number average molecular weight from about 5.0 to about 7.5 kg/mol and, wherein the linear HSBC has a total apparent number average molecular weight from about 70 to less than 144 kg/mol or the branched HSBC has a total apparent number average molecular weight from about 35 to about 75 kg/mol per arm;

d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units;

e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 to about 45 weight percent;

f. the weight percent of mono alkenyl arene in each B block is from about 10 to about 40 weight percent;

g. each B block has a styrene blockiness index of less than 10 percent; and

h. the weight percent of vinyl in each B block is at least about 40 weight percent; and

wherein the thermofusible composition has a Shore A hardness greater than 50 and a tensile strength greater than or equal to 8 MPa.

2. The thermofusible composition according to claim 1 , wherein the mono alkenyl arene is styrene and wherein the conjugated diene is butadiene.

3. The thermofusible composition according to claim 1 , wherein the HSBC (i) is present in an amount of 45 to 55 weight percent.

4. The thermofusible composition according to claim 1 , wherein the linear HSBC has a total apparent number average molecular weight of 125 to less than 144 kg/mol.

5. The thermofusible composition according to claim 1 , wherein the total amount of mono alkenyl arene in the HSBC is from about 30 to about 40 weight percent.

6. The thermofusible composition according to claim 1 , wherein the weight percent of mono alkenyl arene in each B block is from about 15 to about 30 weight percent and, wherein the weight percent of vinyl in each B block is at least about 60 weight percent.

7. The thermofusible composition according to claim 1 , wherein the butylene copolymer (iiib) has a melt flow rate of about 0.8 g/10 min measured at 190° C. employing a 2.16 kg weight.

8. The thermofusible composition according to claim 1 , wherein the additive (iv) comprises one or more plasticizing agents, scratch resistant agents, dusting agents, colouring agents, stabilizers and/or fillers.

9. The thermofusible composition of claim 1 , wherein said Shore A hardness is from about 60 to about 90, and said tensile strength is between 8 and 30 MPa.

10. A method for producing a fused thermoplastic layer on the inner surface of a mould using the thermofusible composition of claim 1 , comprising the method steps of:

a. pouring the thermofusible composition in the form of a powder and/or in the form of micropellets into the mould;

b. rotating, or rotating and shaking, and heating the mould at conditions sufficient to sinter the thermofusible composition into a thermoplastic layer; and

c. allowing the mould and the thermoplastic layer to cool.

11. The method according to claim 10 , wherein the thermofusible composition is sintered at a temperature from about 180° C. to about 260° C.

12. An article comprising a fused thermoplastic layer, wherein the thermoplastic layer is based on the thermofusible composition of claim 1 .

13. The article according to claim 12 , wherein the article is a dashboard.

14. A thermofusible composition in the form of pellets and/or powder, with a particle size of 1400 μm or less comprising:

(A) from about 40 to about 70 weight percent of a selectively hydrogenated styrenic block copolymer (HSBC) as defined hereinafter,

(B) from about 1 to about 30 weight percent of a polybutylene (PB), wherein the PB comprises (i) a butylene homopolymer and (ii) a butylene copolymer and a ratio of butylene homopolymer (i) vs. butylene copolymer (ii) is from about 1:1 to about 10:1 and wherein a melt flow rate of (i), (ii), or (iii) is from about 0.1 to about 500 g/10 min measured at 190° C. employing a 2.16 kg weight,

wherein the HSBC (i) is a linear or branched hydrogenated block copolymer having the general configuration A-B-A, (A-B)n, (A-B-A)n, (A-B-A)nX, (A-B)nX or mixtures thereof, where n is an integer from 2 to about 30, and X is coupling agent residue and wherein:

a. prior to hydrogenation each A block is a mono alkenyl arene polymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene;

b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;

c. each A block has a number average molecular weight from about 5.0 to about 7.5 kg/mol and, wherein the linear HSBC has a total apparent number average molecular weight from about 70 to less than 144 kg/mol or the branched HSBC has a total apparent number average molecular weight from about 35 to about 75 kg/mol per arm;

d. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 to about 45 weight percent;

e. the weight percent of mono alkenyl arene in each B block is from about 10 to about 40 weight percent;

f. each B block has a styrene blockiness index of less than 10 percent; and

g. the weight percent of vinyl in each B block is at least about 40 weight percent; and

wherein the thermofusible composition has a Shore A hardness greater than 50 and a tensile strength ≥to 8 MPa.

15. The thermofusible composition according to claim 14 , wherein the mono alkenyl arene is styrene and wherein the conjugated diene is butadiene.

16. The thermofusible composition according to claim 14 , wherein the HSBC is present in an amount of 45 to 55 weight percent.

17. The thermofusible composition according to claim 14 , wherein the linear HSBC has a total apparent number average molecular weight of 125 to less than 144 kg/mol.

18. The thermofusible composition according to claim 14 , wherein the total amount of mono alkenyl arene in the HSBC is from about 30 to about 40 weight percent.

19. The thermofusible composition according to claim 14 , wherein the weight percent of mono alkenyl arene in each B block is from about 15 to about 30 weight percent, and wherein the weight percent of vinyl in each B block is at least about 60 weight percent.

20. The thermofusible composition according to claim 14 , wherein the butylene copolymer has a melt flow rate of about 0.8 g/10 min measured at 190° C. employing a 2.16 kg weight.

21. The thermofusible composition according to claim 14 , further comprising one or more plasticizing agents, scratch resistant agents, dusting agents, colouring agents, stabilizers and/or fillers.

22. The thermofusible composition of claim 14 , wherein said Shore A hardness is from about 60 to about 90, said tensile strength is between 8 and 30 MPa, or the elongation at break is at least 250%.

23. An article comprising a fused thermoplastic layer, wherein the thermoplastic layer is based on the thermofusible composition of claim 14 .

24. The article according to claim 23 , wherein the article is a dashboard.

25. A thermofused composition comprising a uniformed blend before thermofusion of:

(A) from about 40 to about 70 weight percent of a selectively hydrogenated styrenic block copolymer (HSBC) as defined hereinafter,

(B) from about 1 to about 30 weight percent of a polybutylene (PB), wherein the PB comprises a butylene homopolymer (i) and a butylene copolymer (ii), and a ratio of butylene homopolymer (i) vs. butylene copolymer (ii) is from about 1:1 to about 10:1 and the butylene homopolymer wherein a melt flow rate of (i), (ii), or (iii) is from about 0.1 to about 500 g/10 min measured at 190° C. employing a 2.16 kg weight,

wherein the HSBC (i) is a linear or branched hydrogenated block copolymer having the general configuration A-B-A, (A-B)n, (A-B-A)n, (A-B-A)nX, (A-B)nX or mixtures thereof, where n is an integer from 2 to about 30, and X is coupling agent residue and wherein:

a. prior to hydrogenation each A block is a mono alkenyl arene polymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene;

b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;

c. each A block has a number average molecular weight from about 5.0 to about 7.5 kg/mol and, wherein the linear HSBC has a total apparent number average molecular weight from about 70 to less than 144 kg/mol or the branched HSBC has a total apparent number average molecular weight from about 35 to about 75 kg/mol per arm;

d. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 to about 45 weight percent;

e. the weight percent of mono alkenyl arene in each B block is from about 10 to about 40 weight percent;

f. each B block has a styrene blockiness index of less than 10 percent; and

g. the weight percent of vinyl in each B block is at least about 40 weight percent; and

wherein the thermofusible composition has a Shore A hardness greater than 50 and a tensile strength ≥to 8 MPa.

Assignments (10)