Adhesives made from polymer systems
View Patent ↗The present invention relates to an adhesive, comprising at least one polymer system obtained by a process for reducing the melt viscosity of at least one polymer blend starting material, wherein the process comprises the step of treating at least one polymer blend with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend.
1. An adhesive comprising:
(i) greater than 30 wt %, based on the total weight of the adhesive, of a pre-blended, degraded polymer system consisting of:
(a) 30 to 70 wt % of an elastomeric rubber selected from the group consisting of ethylene-propylene rubber copolymer, ethylene-propylene-diene rubber terpolymer, and mixtures thereof; and
(b) 30 to 70 wt % a semi-crystalline olefinic polymer or a blend of semi-crystalline olefinic polymers;
(ii) a tackifier; and
(iii) an antioxidant;
wherein the degraded polymer system has a melt viscosity of less than 50% than the pre-blended, non-degraded polymer at 200° C.; and
wherein the semi-crystalline olefinic polymer has a heat of melting from 20 to 95 J/g.
2. The adhesive according to claim 1 , wherein the polymer system has a resulting molecular weight distribution Mw/Mn, as determined by gel permeation chromatography, from 1.5 to 5.0.
3. The adhesive according to claim 1 , wherein the polymer system has an elongation at break of at least 50% determined according to EN ISO 527-3.
4. The adhesive according to claim 1 , wherein the polymer system has a tensile strength at break of at least 2.5 MPa determined according to EN ISO 527-3.
5. The adhesive according to claim 1 , wherein the polymer system has a resulting glass transition temperature, as determined by DSC, of between 5 and −65° C.
6. The adhesive according to claim 1 , wherein the polymer system has a resulting heat of melting, as determined by DSC, from 30 to 90 J/g.
7. The adhesive according to claim 1 , wherein the polymer system has a resulting peak melting point (Tm) between 125° C. and 165° C. as determined by DSC.
8. The adhesive according to claim 1 , wherein the elastomeric rubber is ethylene-propylene rubber copolymer that contains at least 40 percent by weight of ethylene.
9. The adhesive according to claim 1 , wherein the elastomeric rubber is ethylene-propylene rubber copolymer that contains 15 to 50 percent by weight of propylene.
10. The adhesive according to claim 1 , wherein the elastomeric rubber is ethylene-propylene-diene rubber rubber terpolymer that contains 40 to 80 percent by weight of ethylene, 15 to 50 percent by weight of propylene, and 2 to 15 percent by weight of a diene.
11. The adhesive according to claim 10 , wherein the ethylene-propylene-diene rubber rubber terpolymer contains 20 to 45 percent by weight of propylene.
12. The adhesive according to claim 10 , wherein the diene is selected from the group consisting of 1,4-hexadiene, norbornadiene, ethylidene-norbornene, dicyclopentadiene, butadiene and isoprene.
13. The adhesive according to claim 1 , wherein the elastomeric rubber is ethylene-propylene rubber copolymer that contains less than 35 percent by weight of ethylene.
14. The adhesive according to claim 1 , wherein the semi-crystalline olefinic polymer is a copolymer of ethylene present at 1 to 35 wt % and at least one comonomer present at 65 to 99 wt % selected from the group consisting of C3-C20 alpha-olefins.
15. The adhesive of claim 1 , wherein the degraded polymer system is degraded with a radical donor selected from azo compounds, diazo compounds and/or peroxides.
16. The adhesive of claim 1 , wherein the adhesive comprises greater than 40 wt %, based on the total weight of the adhesive, of the degraded polymer system.
17. The adhesive of claim 16 , wherein the adhesive comprises greater than 50 wt %, based on the total weight of the adhesive, of the degraded polymer system.
18. An adhesive comprising:
(i) greater than 30 wt %, based on the total weight of the adhesive, of a pre-blended, degraded polymer system consists of:
(a) 30 to 70 wt % of an elastomeric rubber selected from the group consisting of ethylene-propylene rubber copolymer, ethylene-propylene-diene rubber terpolymer, and mixtures thereof; and
(b) 30 to 70 wt % a semi-crystalline olefinic polymer or a blend of semi-crystalline olefinic polymers;
(ii) a tackifier;
(iii) an antioxidant; and
(iv) less than 5 wt %, based on the total weight of the adhesive, of a plasticizer
wherein the degraded polymer system has a melt viscosity of less than 50% than the pre-blended, non-degraded polymer at 200° C.
19. The adhesive of claim 18 , wherein the adhesive comprises greater than 40 wt % of the degraded polymer system.
20. An adhesive comprising:
(i) greater than 40 wt %, based on the total weight of the adhesive, of a degraded polymer system consists of:
(a) an elastomeric rubber selected from the group consisting of ethylene-propylene rubber copolymer, ethylene-propylene-diene rubber terpolymer, and mixtures thereof; and
(b) a semi-crystalline olefinic polymer or a blend of semi-crystalline olefinic polymers; and
(ii) a tackifier; and
(iii) an antioxidant;
wherein the degraded polymer system has a melt viscosity of less than 50% than the non-degraded polymer at 200° C.; and
wherein the semi-crystalline olefinic polymer has a heat of melting from 20 to 95 J/g.
21. The adhesive of claim 20 , wherein the adhesive comprises 50 to 80 wt % of the degraded polymer system.
22. The adhesive of claim 20 , wherein the degraded polymer system is degraded with a radical donor selected from azo compounds, diazo compounds and/or peroxides.
23. An adhesive comprising:
(i) greater than 40 wt %, based on the total weight of the adhesive, of a pre-blended, degraded polymer system consisting of:
(a) 50 to 80 wt % of an elastomeric rubber selected from the group consisting of ethylene-propylene rubber copolymer, ethylene-propylene-diene rubber terpolymer and mixtures thereof; and
(b) a semi-crystalline olefinic polymer or a blend of semi-crystalline olefinic polymers;
(ii) a tackifier; and
(iii) an antioxidant;
wherein the degraded polymer system has a melt viscosity of less than 50% than the pre-blended, non-degraded polymer at 200° C.; and
wherein the semi-crystalline olefinic polymer has a heat of melting from 20 to 95 J/g.
24. The adhesive of claim 23 , wherein the degraded polymer system is degraded with a radical donor selected from azo compounds, diazo compounds and/or peroxides.