Systems for purifying silane
View Patent ↗Processes and systems for purifying silane-containing streams are disclosed with relatively less silane being lost in impurity streams by use of distillation and/or condensation operations.
1. A system for purifying a silane-containing stream comprising silane and one or more compounds having a boiling point less than silane and being substantially free of trichlorosilane, tetrachlorosilane and tetrafluorosilane, the system comprising:
a silane-containing stream conveying apparatus for conveying the silane-containing stream to a light-ends distillation column, wherein the silane-containing stream conveying apparatus is operatively connected to the light-ends distillation column;
a light-ends distillation column for producing a silane-depleted overhead fraction and a silane-enriched bottoms fraction relative to the silane-containing stream, the silane-depleted overhead fraction comprising silane and compounds having a boiling point less than silane;
a condenser for condensing a portion of the silane in the silane-depleted overhead fraction produced from the light-ends distillation column; and
a gas-liquid separator for producing a gaseous stream and a liquid stream containing condensed silane.
2. The system as set forth in claim 1 comprising:
a conveying apparatus for conveying the silane-depleted overhead fraction produced from the light-ends distillation column to the condenser; and
a conveying apparatus for conveying the silane-condensed overhead fraction to the gas-liquid separator.
3. The system as set forth in claim 1 comprising:
an interchanger for thermally contacting the liquid stream with the silane-depleted overhead fraction produced from the light-ends distillation column to condense a portion of the silane in the silane-depleted overhead fraction produced from the light-ends distillation column; and
a conveying apparatus for conveying the silane-depleted overhead fraction produced from the light-ends distillation column to the interchanger; and
a conveying apparatus for conveying the partially condensed silane-depleted overhead fraction produced in the interchanger to the condenser.
4. The system as set forth in claim 1 comprising a conveying apparatus for conveying the liquid stream or a vaporized product thereof into the light-ends distillation column.
5. The system as set forth in claim 1 comprising:
a heavy-ends distillation column to produce a silane-enriched overhead fraction and a silane-depleted bottoms fraction relative to the silane-enriched bottoms fraction produced from the light-ends distillation column, the silane-depleted bottoms fraction produced from the heavy-ends distillation column being enriched in compounds having a boiling point greater than silane;
a conveying apparatus for conveying the silane-enriched bottoms fraction from the light-ends distillation column to the heavy-ends distillation column.
6. The system as set forth in claim 1 comprising:
a heavy-ends distillation column to produce a silane-enriched overhead fraction enriched in compounds having a boiling point less than silane and a silane-depleted bottoms fraction enriched in compounds having a boiling point greater than silane relative to a feed stream introduced into the heavy-ends distillation column; and
a conveying apparatus for conveying the silane-enriched overhead fraction produced from the heavy-ends distillation column to the light-ends distillation column.
7. The system as set forth in claim 5 comprising:
an adsorber for removing a portion of ethylene from the silane-enriched overhead fraction produced from the heavy-ends distillation column and form an ethylene-depleted effluent stream; and
a conveying apparatus for conveying the silane-enriched overhead fraction produced from the heavy-ends distillation column to the adsorber.
8. The system as set forth in claim 7 wherein the adsorber comprises a molecular sieve which causes a portion of the ethylene to react with silane and form ethylsilane, the system comprising:
an ethylsilane distillation column to produce an ethylsilane-depleted overhead fraction comprising purified silane product and an ethylsilane-enriched bottoms fraction relative to the ethylene-depleted effluent stream produced from the adsorber; and
a conveying apparatus for conveying the ethylene-depleted effluent stream comprising ethylsilane to the ethylsilane distillation column.
9. The system as set forth in claim 8 comprising a conveying apparatus for conveying the ethylsilane-enriched bottoms fraction into the light-ends distillation column.
10. A system for purifying a silane-containing stream comprising silane and one or more compounds having a boiling point greater than silane and one or more compounds with a boiling point less than silane and being substantially free of trichlorosilane, tetrachlorosilane and tetrafluorosilane, the system comprising:
a silane-containing stream conveying apparatus for conveying the silane-containing stream to a light-ends distillation column, wherein the silane-containing stream conveying apparatus is operatively connected to the light-ends distillation column;
a light-ends distillation column for producing a silane-depleted overhead fraction and a silane-enriched bottoms fraction relative to the silane-containing stream, the silane-depleted overhead fraction comprising silane and compounds having a boiling point less than silane;
a condenser for condensing a portion of the silane in the silane-depleted overhead fraction produced from the light-ends distillation column;
a heavy-ends distillation column for producing a silane-enriched overhead fraction and a silane-depleted bottoms fraction relative to the silane-enriched bottoms fraction produced from the light-ends distillation column, the silane-depleted bottoms fraction produced from the heavy-ends distillation column comprising silane and being enriched in one or more compounds having a boiling point greater than silane relative to the silane-containing stream; and
a silane-recovery distillation column for producing a silane-recovery distillation column silane-enriched overhead fraction and a silane-recovery distillation column silane-depleted bottoms fraction relative to the silane-depleted bottoms fraction produced from the heavy-ends distillation column.
11. The system as set forth in claim 10 comprising:
a conveying apparatus for conveying the silane-depleted overhead fraction produced from the light-ends distillation column to the condenser;
a conveying apparatus for conveying the silane-enriched bottoms fraction produced from the light-ends distillation column to the heavy-ends distillation column; and
a conveying apparatus for conveying the silane-depleted bottoms fraction produced from the heavy-ends distillation column to the silane-recovery distillation column.
12. The system as set forth in claim 10 comprising:
a gas-liquid separator for producing a gaseous stream and a liquid stream containing condensed silane; and
a conveying apparatus for conveying the silane-condensed overhead fraction produced from the condenser to the gas-liquid separator.
13. The system as set forth in claim 12 comprising a conveying apparatus for conveying the liquid stream or a vaporized product thereof to the light-ends distillation column.
14. The system as set forth in claim 10 comprising:
an interchanger for thermally contacting the liquid stream with the silane-depleted overhead fraction produced from the light-ends distillation column to condense a portion of the silane in the silane-depleted overhead fraction produced from the light-ends distillation column; and
a conveying apparatus for conveying the silane-depleted overhead fraction produced from the light-ends distillation column to the interchanger; and
a conveying apparatus for conveying the partially condensed silane-depleted overhead fraction produced in the interchanger to the condenser.
15. The system as set forth in claim 10 comprising:
an adsorber for removing a portion of ethylene from the silane-enriched overhead fraction produced from the heavy-ends distillation column and to form an ethylene-depleted effluent stream; and
a conveying apparatus for conveying the silane-enriched overhead fraction produced from the heavy-ends distillation column to the adsorber.
16. The system as set forth in claim 15 wherein the adsorber comprises a molecular sieve which causes a portion of the ethylene to react with silane and form ethylsilane, the system comprising:
an ethylsilane distillation column to produce an ethylsilane-depleted overhead fraction comprising purified silane product and an ethylsilane-enriched bottoms fraction relative to the ethylene-depleted effluent stream produced from the adsorber; and
a conveying apparatus for conveying the ethylene-depleted effluent stream comprising ethylsilane to the ethylsilane distillation column.
17. The system as set forth in claim 16 comprising a conveying apparatus for conveying the ethylsilane-enriched bottoms fraction into the light-ends distillation column.
18. A system for purifying a silane-containing stream comprising silane and one or more compounds having a boiling point greater than silane and one or more compounds with a boiling point less than silane, the system comprising:
a light-ends distillation column for producing a silane-depleted overhead fraction and a silane-enriched bottoms fraction relative to the silane-containing stream, the silane-depleted overhead fraction comprising silane and compounds having a boiling point less than silane;
a condenser for condensing a portion of the silane in the silane-depleted overhead fraction produced from the light-ends distillation column;
a heavy-ends distillation column for producing a silane-enriched overhead fraction and a silane-depleted bottoms fraction relative to the silane-enriched bottoms fraction produced from the light-ends distillation column, the silane-depleted bottoms fraction produced from the heavy-ends distillation column comprising silane and being enriched in one or more compounds having a boiling point greater than silane relative to the silane-containing stream;
a silane-recovery distillation column for producing a silane-recovery distillation column silane-enriched overhead fraction and a silane-recovery distillation column silane-depleted bottoms fraction relative to the silane-depleted bottoms fraction produced from the heavy-ends distillation column;
a conveying apparatus for conveying the silane-recovery distillation column silane-enriched overhead fraction produced from the silane-recovery distillation column to the light-ends distillation column.