Polyamide/polyphenylene ether fibers and fiber-forming method
View Patent ↗A fiber is prepared by melt extruding a composition including specific amounts of a polyamide and a polyphenylene ether along with a compatabilizer. Particular combinations produce fibers having a desirable combination of good tenacity and low denier per fiber. Compared to a fiber prepared from polyamide alone, the present fiber exhibits improved heat resistance and flame resistance.
1. A fiber comprising a compatibilized polyamide-polyphenylene ether blend,
wherein the compatibilized polyamide-polyphenylene ether blend is the product of melt blending components comprising
about 40 to about 95 weight percent of a polyamide having a an amine end group concentration of less than or equal to 100 microequivalents per gram,
about 5 to about 60 weight percent of a polyphenylene ether having an intrinsic viscosity of from about 0.2 to 0.38 deciliter per gram, measured at 25° C. in chloroform, and
about 0.35 to about 1.2 weight percent of a compatibilizing agent;
wherein all weight percents are based on the total weight of the polyamide and polyphenylene ether polymers;
wherein the fiber has a diameter of about 20 micrometers to about 500 micrometers;
wherein the compatibilized polyamide-polyphenylene ether blend comprises a continuous phase comprising the polyamide, and a disperse phase comprising the polyphenylene ether;
wherein the mean cross-sectional area of the disperse phase particles is less than or equal to about 0.7 micrometer 2 , and no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 5.5 micrometer 2 , based on the number of disperse phase particles, when measured by scanning transmission electron microscopy;
wherein the compatibilized polyamide-polyphenylene ether blend is free of any polymer other than the polyamide and the polyphenylene ether; and
wherein the compatibilized polyamide-polyphenylene ether blend comprises 0 to 0.005 weight percent of electrically conductive fillers.
2. The fiber of claim 1 , wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6, and mixtures thereof.
3. The fiber of claim 1 , wherein the polyamide comprises polyamide-6,6.
4. The fiber of claim 1 , wherein the polyamide has an amine end group concentration of 20 to 100 microequivalents per gram.
5. The fiber of claim 1 , wherein the melt blended components comprise the polyamide in an amount of about 50 to about 90 weight percent and the polyphenylene ether in an amount of about 10 to about 50 weight percent.
6. The fiber of claim 1 , wherein the polyphenylene ether comprises poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of from about 0.24 to about 0.35 deciliter per gram.
7. The fiber of claim 1 , wherein the melt blended components comprise the compatibilizing agent in an amount of about 0.4 to about 1.1 weight percent.
8. The fiber of claim 1 , wherein the compatibilizing agent comprises fumaric acid.
9. The fiber of claim 1 , wherein no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 4.5 micrometer 2 when measured by scanning transmission electron microscopy.
10. A fiber comprising a compatibilized polyamide-polyphenylene ether blend,
wherein the compatibilized polyamide-polyphenylene ether blend is the product of melt blending components comprising
about 50 to about 89.5 weight percent of a polyamide having an amine end group concentration of less than or equal to 100 microequivalents per gram,
about 10 to about 49.5 weight percent of a polyphenylene ether, and
about 0.35 to about 1.0 weight percent of a compatibilizing agent comprising fumaric acid;
wherein all weight percents are based on the total weight of the polyamide and polyphenylene ether polymers;
wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6, and mixtures thereof;
wherein the polyamide has an amine end group concentration of less than or equal to 100 microequivalents per gram;
wherein the polyphenylene ether comprises poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of about 0.24 to about 0.35 deciliter per gram, measured at 25° C. in chloroform;
wherein the fiber has a diameter of about 20 micrometers to about 500 micrometers;
wherein the compatibilized polyamide-polyphenylene ether blend comprises a continuous phase comprising the polyamide, and a disperse phase comprising the polyphenylene ether;
wherein the mean cross-sectional area of the disperse phase particles is less than or equal to about 0.7 micrometer 2 , and no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 5.5 micrometer 2 , based on the number of disperse phase particles, when measured by scanning transmission electron microscopy;
wherein the compatibilized polyamide-polyphenylene ether blend is free of any polymer other than the polyamide and the polyphenylene ether; and
wherein the compatibilized polyamide-polyphenylene ether blend comprises 0 to 0.005 weight percent of electrically conductive fillers.
11. A core/sheath fiber comprising:
a core comprising the fiber of claim 1 ; and
a sheath substantially surrounding the core, wherein the sheath comprises a second polyamide and is substantially free of polyphenylene ether.
12. A core/sheath fiber comprising:
a core comprising the fiber of claim 10 ; and
a sheath substantially surrounding the core, wherein the sheath comprises a second polyamide and is substantially free of polyphenylene ether.
13. A core/sheath fiber comprising:
a core comprising a polyamide and being substantially free of polyphenylene ether; and
a sheath substantially surrounding the core and comprising a compatibilized polyamide-polyphenylene ether blend;
wherein the compatibilized polyamide-polyphenylene ether blend is the product of melt blending components comprising
about 40 to about 95 weight percent of a polyamide having an amine end group concentration of less than or equal to 100 microequivalents per gram,
about 5 to about 60 weight percent of a polyphenylene ether having an intrinsic viscosity of about 0.2 to 0.38 deciliter per gram, measured at 25° C. in chloroform, and
about 0.35 to about 1.2 weight percent of a compatibilizing agent,
wherein all weight percents are based on the total weight of the polyamide and polyphenylene ether polymers;
wherein the fiber has a diameter of about 20 micrometers to about 500 micrometers;
wherein the compatibilized polyamide-polyphenylene ether blend comprises a continuous phase comprising the polyamide, and a disperse phase comprising the polyphenylene ether;
wherein the mean cross-sectional area of the disperse phase particles is less than or equal to about 0.7 micrometer 2 , and no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 5.5 micrometer 2 , based on the number of disperse phase particles, when measured by scanning transmission electron microscopy;
wherein the compatibilized polyamide-polyphenylene ether blend is free of any polymer other than the polyamide and the polyphenylene ether; and
wherein the compatibilized polyamide-polyphenylene ether blend comprises 0 to 0.005 weight percent of electrically conductive fillers.
14. A core/sheath fiber comprising:
a core comprising a polyamide and being substantially free of polyphenylene ether; and
a sheath substantially surrounding the core and comprising a compatibilized polyamide-polyphenylene ether blend;
wherein the compatibilized polyamide-polyphenylene ether blend is the product of melt blending components comprising
about 50 to about 89.5 weight percent of a polyamide having an amine end group concentration of less than or equal to 100 microequivalents per gram,
about 10 to about 49.5 weight percent of a polyphenylene ether having an intrinsic viscosity of about 0.24 to about 0.35 deciliter per gram, measured at 25° C. in chloroform, and
about 0.35 to about 1 weight percent of a compatibilizing agent;
wherein all weight percents are based on the total weight of the polyamide and polyphenylene ether polymers;
wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6, and mixtures thereof;
wherein the polyamide has an amine end group concentration of less than or equal to 100 microequivalents per gram;
wherein the fiber has a diameter of about 20 micrometers to about 500 micrometers;
wherein the compatibilized polyamide-polyphenylene ether blend comprises a continuous phase comprising the polyamide, and a disperse phase comprising the polyphenylene ether;
wherein the mean cross-sectional area of the disperse phase particles is less than or equal to about 0.7 micrometer 2 , and no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 5.5 micrometer 2 , based on the number of disperse phase particles, when measured by scanning transmission electron microscopy;
wherein the compatibilized polyamide-polyphenylene ether blend is free of any polymer other than the polyamide and the polyphenylene ether; and
wherein the compatibilized polyamide-polyphenylene ether blend comprises 0 to 0.005 weight percent of electrically conductive fillers.
15. A method of melt spinning a fiber, comprising:
melt extruding a compatibilized polyamide-polyphenylene ether blend to form a fiber;
wherein the compatibilized polyamide-polyphenylene ether blend is the product of melt blending components comprising
about 40 to about 95 weight percent of a polyamide having an amine end group concentration of less than or equal to 100 microequivalents per gram,
about 5 to about 60 weight percent of a polyphenylene ether having an intrinsic viscosity of about 0.2 to about 0.38 deciliter per gram, measured at 25° C. in chloroform, and
about 0.35 to about 1.2 weight percent of a compatibilizing agent;
wherein all weight percents are based on the total weight of the polyamide and polyphenylene ether polymers;
wherein the fiber has a diameter of about 20 micrometers to about 500 micrometers;
wherein the compatibilized polyamide-polyphenylene ether blend comprises a continuous phase comprising the polyamide, and a disperse phase comprising the polyphenylene ether;
wherein the mean cross-sectional area of the disperse phase particles is less than or equal to about 0.7 micrometer 2 , and no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 5.5 micrometer 2 , based on the number of disperse phase particles, when measured by scanning transmission electron microscopy;
wherein the compatibilized polyamide-polyphenylene ether blend is free of any polymer other than the polyamide and the polyphenylene ether; and
wherein the compatibilized polyamide-polyphenylene ether blend comprises 0 to 0.005 weight percent of electrically conductive fillers.
16. The method of claim 15 , wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6.
17. The method of claim 15 , wherein the polyamide comprises polyamide-6,6.
18. The method of claim 15 , wherein the melt blended components comprise the polyamide in an amount from about 50 to about 90 weight percent and the polyphenylene ether in an amount of about 10 to about 50 weight percent.
19. The method of claim 15 , wherein the polyphenylene ether comprises poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of from about 0.24 to about 0.35 deciliter per gram.
20. The method of claim 15 , wherein the melt blended components comprise the compatibilizing agent in an amount from about 0.5 to about 1.0 weight percent.
21. The method of claim 15 , wherein the compatibilizing agent comprises fumaric acid.
22. A method of melt spinning a fiber, comprising:
melt extruding a compatibilized polyamide-polyphenylene ether blend to form a fiber;
wherein the compatibilized polyamide-polyphenylene ether blend is the product of melt blending components comprising
about 50 to about 89.5 weight percent of a polyamide,
about 10 to about 49.5 weight percent of a polyphenylene ether, and
about 0.35 to about 1 weight percent of a compatibilizing agent selected from the group consisting of citric acid, fumaric acid, maleic acid, and mixtures thereof;
wherein all weight percents are based on the total weight of the polyamide and polyphenylene ether polymers;
wherein the polyamide is selected from the group consisting of polyamide-6, polyamide-6,6, and mixtures thereof;
wherein the polyamide has an amine end group concentration of less than or equal to 100 micro equivalents per gram;
wherein the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of about 0.24 to about 0.35 deciliter per gram, measured at 25° C. in chloroform;
wherein the fiber has a diameter of about 20 micrometers to about 500 micrometers;
wherein the compatibilized polyamide-polyphenylene ether blend comprises a continuous phase comprising the polyamide, and a disperse phase comprising the polyphenylene ether;
wherein the mean cross-sectional area of the disperse phase particles is less than or equal to about 0.7 micrometer 2 , and no more than 0.5 percent of the total disperse phase particles have a cross-sectional area of greater than 5.5 micrometer 2 , based on the number of disperse phase particles, when measured by scanning transmission electron microscopy;
wherein the compatibilized polyamide-polyphenylene ether blend is free of any polymer other than the polyamide and the polyphenylene ether; and
wherein the compatibilized polyamide-polyphenylene ether blend comprises 0 to 0.005 weight percent of electrically conductive fillers.
23. A textile comprising the fiber of claim 1 .