Polycarbonate resin composition
Disclosed are a polycarbonate resin composition and a molded product formed of the same. The polycarbonate resin composition includes a polycarbonate resin and three types of UV stabilizers including a first benzotriazole UV stabilizer, a second benzotriazole UV stabilizer, and a bismalonate UV stabilizer to improve heat stability, weather resistance, and visible light transmittance.
1. A polycarbonate resin composition comprising:
a polycarbonate resin;
a first benzotriazole UV stabilizer represented by Formula 1,
wherein R is hydrogen, linear or branched C1 to C20 alkyl, C6 to C20 aryl, or C6 to C 20 aryl substituted by C1 to C10 alkyl;
a second benzotriazole UV stabilizer represented by Formula 2,
wherein R1 and R2 are the same or different and are each independently hydrogen, linear or branched C1 to C20 alkyl, C6 to C20 aryl, or C6 to C20 aryl substituted by C1 to C10 alkyl;
a bismalonate UV stabilizer represented by Formula 3,
wherein R3, R4, R5, and R6 are the same or different and are each independently hydrogen, linear or branched C1 to C20 alkyl, C6 to C20 aryl, or C6 to C20 aryl substituted by C1 to C10 alkyl; and
a phosphorus heat stabilizer.
2. The polycarbonate resin composition of claim 1 , comprising the first benzotriazole UV stabilizer in an amount of about 0.05 to about 0.3 phr based on about 100 parts by weight of the polycarbonate resin.
3. The polycarbonate resin composition of claim 1 , comprising the second benzotriazole UV stabilizer in an amount of about 0.05 to about 0.3 phr based on about 100 parts by weight of the polycarbonate resin.
4. The polycarbonate resin composition of claim 1 , comprising the bismalonate UV stabilizer in an amount of about 0.05 to about 0.3 phr based on about 100 parts by weight of the polycarbonate resin.
5. The polycarbonate resin composition of claim 1 , comprising the first benzotriazole UV stabilizer, the second benzotriazole UV stabilizer, and the bismalonate UV stabilizer at a weight ratio of about 1:1 to about 3:1 to about 3.
6. The polycarbonate resin composition of claim 1 , wherein the polycarbonate resin is prepared by transesterification of an aromatic dihydroxyl compound or an aromatic carbonate derivative compound and diaryl carbonate in the presence of an alkali metal catalyst, an alkaline earth metal catalyst, or a combination thereof.
7. The polycarbonate resin composition of claim 1 , wherein the phosphorus heat stabilizer comprises tris(2,4-di-tert-butylphenyl)phosphate, triethyl phosphate, trimethyl phosphate, diphenyl isooctyl phosphite, distearyl pentaerythritol diphosphite, or a combination thereof.
8. The polycarbonate resin composition of claim 1 , comprising the phosphorus heat stabilizer in an amount of about 0.01 to about 0.2 phr based on about 100 parts by weight of the polycarbonate resin.
9. The polycarbonate resin composition of claim 1 , wherein the resin composition further comprises a sulfonic acid compound.
10. The polycarbonate resin composition of claim 9 , wherein the sulfonic acid compound is represented by Formula 4:
wherein each R9 is the same or different and is independently C1 to C20 alkyl or halogen substituted C1 to C20 alkyl, R10 is C11 to C20 alkylene or halogen substituted C11 to C20 alkylene, and n is an integer from 0 to 5.
11. The polycarbonate resin composition of claim 9 , wherein the sulfonic acid compound is present in an amount of about 1×10 −5 to about 5×10 −3 phr based on about 100 parts by weight of the polycarbonate resin.
12. The polycarbonate resin composition of claim 1 , wherein a specimen formed of the resin composition has a change in yellowness index (ΔYI) of about 2.4 or less as measured by ASTM D1925 after storage at about 320° C. for about 5 minutes.
13. The polycarbonate resin composition of claim 1 , wherein a specimen formed of the resin composition has a change in yellowness index (ΔYI) of about 8.2 or less as measured by ASTM D1925 after subjected to irradiation of light with a wavelength of about 340 nm and an intensity of about 0.35 W/m 2 for about 1,000 hours.
14. The polycarbonate resin composition of claim 1 , wherein a specimen formed of the resin composition has a visible light transmittance of about 86% or more at a thickness of about 2.5 mm.
15. The polycarbonate resin composition of claim 1 , wherein the resin composition further comprises at least one additive selected from the group consisting of antimicrobial agents, release agents, antioxidants, compatibilizers, inorganic additives, fillers, plasticizers, impact modifiers, admixtures, coloring agents, stabilizers, lubricants, anti-static agents, pigments, weather proof agents, UV blocking agents, and combinations thereof.
16. A molded product formed of the resin composition of claim 1 .