Aqueous pigmented yellow inkjet ink composition
View Patent ↗The invention relates to an aqueous yellow inkjet ink composition for use in ink jet printers comprising an aqueous carrier, a yellow pigment, a polymeric dispersant, a surfactant, and a specific cosolvent mixture comprising a C 2 -C 8 terminal alkanediol or a mixture thereof, a polyol/polyalkylene oxide condensate, a cyclic amide and its derivative, and a trihydric alcohol. The yellow inkjet ink demonstrates excellent stability, good maintenance characteristics and high heater reliability in permanent and semi permanent printheads. The ink also reduced post print paper curl without sacrificing print quality.
1. An aqueous yellow inkjet ink composition for use in ink jet printers comprising:
(a) from about 1.0% to about 5.0% by weight, based on the total weight of the yellow inkjet ink composition, of an insoluble yellow pigment;
(b) from about 0.5% to about 2.0% by weight, based on the total weight of the yellow inkjet ink composition, of a polymeric dispersant for said insoluble yellow pigment;
(c) from about 0.1% to about 3% by weight, based on the total weight of the yellow inkjet ink composition, of a surfactant;
(d) from about 15.0% to about 25.0% by weight, based on the total weight of the yellow inkjet ink composition, of a cosolvent mixture having:
(1) a C 2 -C 8 terminal alkanediol or a mixture thereof;
(2) a polyol/polyalkylene oxide condensate having the formula
wherein X is H or C 1 -C 6 alkyl, R is H, C 1 -C 6 alkyl or CH 2 O(CH 2 CH 2 O) e H, b is 0 or 1, a+d+f (c+e) is from about 2 to about 100, and f is from about 1 to about 6;
(3) a cyclic amide or its derivative;
(4) a trihydric alcohol; and
(e) the balance an aqueous carrier,
wherein the ink has excellent print quality, idle times, and long heater reliability.
2. The aqueous yellow inkjet ink composition according to claim 1 wherein the cosolvent mixture comprises:
(1) 1,3-propanediol present in the amount of about 9.0%, based on the total weight of the yellow inkjet ink composition;
(2) polyol/alkylene oxide condensate wherein X is hydrogen, R is C 2 H 5 , b is 1, f is 1, and a+d+f (c+e) is 20, present in the amount of about 1.0%, based on the total weight of the yellow inkjet ink composition;
(3) 1-(2-hydroxyethyl)-2-pyrrolidone present in the amount of about 6.0%, based on the total weight of the yellow inkjet ink composition; and
(4) glycerol present in the amount of about 3.0%, based on the total weight of the yellow inkjet ink composition.
3. The aqueous yellow inkjet ink composition of claim 1 wherein the surfactant is ethoxylated 2,4,7,9-tetramethyl-5-decyn-4,7-diol and is present in the amount of about 0.8%, based on the total weight of the yellow inkjet ink composition.
4. The aqueous yellow inkjet ink composition of claim 1 wherein the yellow pigment is present in the amount of about 4%, based on the total weight of the yellow inkjet ink composition.
5. The aqueous yellow inkjet ink composition of claim 1 wherein the polymer dispersant is present in the amount of about 0.9%, based on the total weight of the yellow inkjet ink composition.
6. The aqueous yellow inkjet ink composition of claim 1 wherein the polymer dispersant contains at least three components: a hydrophilic polymeric component, a hydrophobic polymeric component, and a protective colloid component.
7. The aqueous yellow inkjet ink composition of claim 6 wherein hydrophilic component is methacrylic acid, the hydrophobic component is polypropylene glycol nonylphenylether acrylate and the protective colloid component is poly(ethylene glycol)-2,4,6-tris-(1-phenylethyl)phenyl-methacylate.
8. The aqueous yellow inkjet ink composition of claim 7 wherein molar ratio of the methacrylic acid to the polypropylene glycol nonylphenylether acrylate to the poly (ethylene glycol)-2,4,6-tris-(1-phenylethyl)phenyl-methacrylate is 6:1:1.
9. The aqueous yellow inkjet ink composition of claim 7 wherein molar ratio of the methacrylic acid to the polypropylene glycol nonylphenylether acrylate to the poly(ethylene glycol)-2,4,6-tris-(1-phenylethyl)phenyl-methacrylate is 15:1:1.
10. The aqueous yellow inkjet ink composition of claim 1 further comprising a biocide.
11. The aqueous yellow inkjet ink composition according to claim 1 wherein the cosolvent mixture comprises:
(1) 1,3-propanediol present in the amount of about 11.0%, based on the total weight of the yellow inkjet ink composition;
(2) polyol/alkylene oxide condensate wherein X is hydrogen, R is C 2 H, b is 1, f is 1, and a+d+f (c+e) is 20, present in the amount of about 1.0%, based on the total weight of the yellow inkjet ink composition;
(3) 1-(2-hydroxyethyl)-2-pyrrolidone present in the amount of about 6.0%, based on the total weight of the yellow inkjet ink composition; and
(4) trimethylolpropane present in the amount of about 1.0%, based on the total weight of the yellow inkjet ink composition.