Graphite coated metal nanoparticles for polycrystalline diamond compact synthesis
View Patent ↗A method of forming polycrystalline diamond includes forming metal nanoparticles having a carbon coating from an organometallic material; combining a diamond material with the metal nanoparticles having the carbon coating; and processing the diamond material and the metal nanoparticles having the carbon coating to form the polycrystalline diamond. Processing includes catalyzing formation of the polycrystalline diamond by the metal nanoparticles; and forming interparticle bonds that bridge the diamond material by carbon from the carbon coating.
1. A method of forming polycrystalline diamond, comprising:
forming metal nanoparticles having a carbon coating from an organometallic material;
combining a diamond material with the metal nanoparticles having the carbon coating; and
processing the diamond material and the metal nanoparticles having the carbon coating to form the polycrystalline diamond, including:
catalyzing formation of the polycrystalline diamond by the metal nanoparticles; and
forming interparticle bonds that bridge the diamond material by carbon from the carbon coating,
wherein the organometallic material is a metallocene comprising:
a metal selected from magnesium, aluminum, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, zirconium, ruthenium, hafnium, tantalum, tungsten, rhenium, osmium, or a combination comprising at least one of the foregoing; and
a ligand selected from an alkyl, aryl, hydride, halide, amide, η 2 -alkene, CO, CS, amine, nitrile, isocyanide, phosphane, alkylidene, alkyldiide, nitrene, imide, oxide, alkylidyne, alkytriide, η 3 -allyl, η 3 -enyl, η 3 -cyclopropenyl, NO, η 4 -diene, η 4 -cyclobutadiene, η 5 -cyclopentadienyl, η 6 -arene, η 6 -triene, η 7 -tropylium, η 7 -cycloheptatrienyl, η 8 -cyclooctatetraene, or a combination comprising at least one of the foregoing.
2. The method of claim 1 , wherein forming the metal nanoparticles having the carbon coating comprises pyrolizing the organometallic material.
3. The method of claim 1 , wherein processing the diamond material and the metal nanoparticles having the carbon coating comprises sintering at a temperature of greater than or equal to about 1000° C. at a pressure greater than or equal to about 5 gigapascals for about 1 second to about 1 hour.
4. The method of claim 3 , wherein sintering is at a pressure greater than or equal to 6.5 gigapascals.
5. The method of claim 4 , wherein sintering is at a pressure greater than or equal to 7.5 gigapascals.
6. The method of claim 3 , further comprising removing a portion of the metal from the polycrystalline diamond by leaching.
7. The method of claim 1 , further comprising functionalizing the carbon coating to include a functional group before processing the diamond material and the metal nanoparticles having the carbon coating,
wherein the functional group comprises carboxyl, epoxy, ether, keto, amino, amido, hydroxyl, alkoxy, alkyl, alkenyl, alkynyl, aryl, aralkyl, alkaryl, lactone, functionalized polymeric or oligomeric groups, or a combination comprising at least one of the forgoing functional groups.
8. The method of claim 7 , wherein the functional group is present in an amount effective to allow substantially homogeneous dispersion of the metal nanoparticles having the carbon coating among the diamond material.
9. The method of claim 1 , further comprising functionalizing the diamond material to include a functional group before processing the diamond material and the metal nanoparticles having the carbon coating,
wherein the functional group comprises alkyl, alkenyl, alkynyl, carboxyl, hydroxyl, amino, amido, epoxy, keto, alkoxy, ether, ester, lactones, metallic groups, organometallic groups, polymeric groups, ionic groups, or a combination comprising at least one of the foregoing.
10. The method of claim 9 , wherein the functional group is present in an amount effective to allow substantially homogeneous dispersion of the diamond material among the metal nanoparticles having the carbon coating.
11. The method of claim 1 , further comprising using a hydrocarbon, in addition to the organometallic material to form a portion of the carbon coating on the metal nanoparticles.
12. The method of claim 11 , wherein the hydrocarbon comprises an alkane, alkene, alkyne, arene, or a combination comprising at least one of the foregoing.
13. The method of claim 1 , wherein the carbon coating comprises a carbon onion, single walled nanotube, multiwalled nanotube, graphite, graphene, fullerene, nanographite, C1-C40 alkane, C1-C40 alkene, C1-C40 alkyne, C3-C60 arene, or a combination comprising at least one of the following.
14. The method of claim 1 , wherein the metal nanoparticles having the carbon coating are present in an amount of about 0.1 wt. % to about 20 wt. %, based on the weight of the diamond material and the metal nanoparticles having the carbon coating.
15. The method of claim 1 , wherein the metallocene is ferrocene, cobaltocene, nickelocene, ruthenocene, or a combination of at least one of the foregoing.
16. The method of claim 1 , wherein the metal nanoparticles are an alloy of at least two of the metals.
17. The method of claim 1 , wherein combining the diamond material with the metal nanoparticles having the carbon coating comprises forming a multilayer comprising:
a first layer of the metal nanoparticles having the carbon coating; and
a second layer of the diamond material disposed on the first layer.
18. The method of claim 1 , wherein combining the diamond material with the metal nanoparticles having the carbon coating comprises forming a dispersion of the metal nanoparticles having the carbon coating in the diamond material.
19. The method of claim 18 , wherein the dispersion has a concentration gradient of the metal nanoparticles having the carbon coating.
20. A method of forming a polycrystalline diamond compact, comprising
forming metal nanoparticles at least partially having a carbon coating from an organometallic material;
disposing a diamond material and the metal nanoparticles having the carbon coating on a ceramic substrate; and
processing the diamond material and the metal nanoparticles having the carbon coating to form the polycrystalline diamond compact, including
catalyzing formation of the polycrystalline diamond by the metal nanoparticles; and
forming bonds that bridge the diamond material by the carbon from the carbon coating,
wherein the organometallic material is a metallocene comprising:
a metal selected from magnesium, aluminum, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, zirconium, ruthenium, hafnium, tantalum, tungsten, rhenium, osmium, or a combination comprising at least one of the foregoing; and
a ligand selected from an alkyl, aryl, hydride, halide, amide, η 2 -alkene, CO, CS, amine, nitrile, isocyanide, phosphane, alkylidene, alkyldiide, nitrene, imide, oxide, alkylidyne, alkytriide, η 3 -allyl, η 3 -enyl, η 3 -cyclopropenyl, NO, η 4 -diene, η 4 -cyclobutadiene, η 5 -cyclopentadienyl, η 6 -arene, η 6 -triene, η 7 -tropylium, η 7 -cycloheptatrienyl, η 8 -cyclooctatetraene, or a combination comprising at least one of the foregoing.
21. The method of claim 20 , further comprising removing a portion of the metal from the polycrystalline diamond compact by leaching.
22. The method of claim 21 , wherein leaching comprises immersing the polycrystalline diamond compact in hydrochloric acid, hydrofluoric acid, nitric acid, or a combination comprising at least one of the foregoing, at a temperature of greater than about 100° C.
23. The method of claim 20 , wherein the ceramic substrate comprises tungsten carbide.