Alignment film, composition for forming alignment film and liquid crystal display device

1. A liquid crystal display device comprising:

a first substrate and a second substrate, at least one of which is transparent;

a liquid crystal layer disposed between the first substrate and the second substrate;

a group of electrodes for applying an electric field to the liquid crystal layer, which is formed on at least one of the first substrate and the second substrate;

a plurality of active elements connected to the group of electrodes; and

an alignment film disposed on at least one of the first substrate and the second substrate, wherein

the alignment film contains a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride,

the diamine contains a first diamine having at least one acidic group and a second diamine having at least one nitrogen atom-containing basic functional group other than two amino groups,

the second diamine is represented by the following chemical formula (2): H 2 N—Y—NH 2 , wherein Y is an at least divalent organic group which contains one to three nitrogen atoms, and contains a functional group selected from an amino group having a secondary amine structure (—NH—), a primary amide group (—CO—NH 2 ), and a secondary amide group (—CO—NH—) as the nitrogen atom-containing basic functional group, and

in a case where the second diamine has an annulation in the molecule, the annulation is a benzene ring structure, and

wherein the second diamine comprises at least one of the compounds represented by the following chemical formulae (B-7), (B-30) and (B-31):

in which each n independently represents an integer of 0 to 8, and each R independently represents an alkyl group having 1 to 3 carbon atoms.

2. The liquid crystal display device according to claim 1 , wherein the first diamine contains at least one functional group selected from a carboxylic acid group, a sulfonic acid group, a phosphoric acid group, and a phosphonic acid group as the acidic group.

3. The liquid crystal display device according to claim 1 , wherein the first diamine is represented by the following chemical formula (1): H 2 N—X—NH 2 (wherein X is an at least divalent organic group, and contains one to three functional groups of at least one kind selected from a carboxylic acid group, a sulfonic acid group, a phosphoric acid group, and a phosphonic acid group as the acidic group in the chemical structure thereof).

4. The liquid crystal display device according to claim 3 , wherein the ratio of the number of nitrogen atoms derived from the nitrogen atom-containing functional group to the number of the acidic groups derived from the first diamine contained in the polyimide and the precursor of the polyimide constituting the alignment film is from 0.25 to 4.0.

5. The liquid crystal display device according to claim 3 , wherein the sum of the content rate of the first diamine and the content rate of the second diamine in the diamine to be used for forming the polyimide and the precursor of the polyimide is 30 mol % or more.

6. The liquid crystal display device according to claim 1 , wherein the acid anhydride to be used for forming the polyimide and the precursor of the polyimide contains an aliphatic acid dianhydride in an amount of 50 mol % or more.

7. The liquid crystal display device according to claim 1 , wherein the transmittance (Y) of the alignment film is 98.0% or more.

8. The liquid crystal display device according to claim 1 , wherein the alignment film is imparted a liquid crystal alignment ability by irradiation with polarized ultraviolet light.

9. The liquid crystal display device according to claim 1 , wherein the precursor of the polyimide contains a polyamide acid ester and a polyamide acid.

10. The liquid crystal display device according to claim 9 , wherein the polyamide acid ester is formed from a cyclobutane tetracarboxylic dianhydride derivative and an aromatic diamine.

11. The liquid crystal display device according to claim 1 , wherein the precursor of the polyimide is a polyamide acid ester which is formed from a cyclobutane tetracarboxylic dianhydride derivative.

12. An alignment film comprising a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride, and

liquid crystal molecules on a surface of the alignment film, uniformly aligned by the alignment film,

wherein

the diamine contains a first diamine having at least one acidic group and a second diamine having at least one nitrogen atom-containing basic functional group other than two amino groups,

the second diamine is represented by the following chemical formula (2): H 2 N—Y—NH 2 , wherein Y is an at least divalent organic group which contains one to three nitrogen atoms, and contains a functional group selected from an amino group having a secondary amine structure (—NH—), a primary amide group (—CO—NH 2 ), and a secondary amide group (—CO—NH—) as the nitrogen atom-containing basic functional group, and

in a case where the second diamine has an annulation in the molecule, the annulation is a benzene ring structure, and

wherein the second diamine comprises at least one of the compounds represented by the following chemical formulae (B-7), (B-30) and (B-31):

in which each n independently represents an integer of 0 to 8, and each R independently represents an alkyl group having 1 to 3 carbon atoms.

13. A liquid crystal display device comprising:

a first substrate and a second substrate, at least one of which is transparent;

a liquid crystal layer disposed between the first substrate and the second substrate;

a group of electrodes for applying an electric field to the liquid crystal layer, which is formed on at least one of the first substrate and the second substrate;

a plurality of active elements connected to the group of electrodes; and

an alignment film disposed on at least one of the first substrate and the second substrate, wherein

the alignment film contains a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride,

the diamine contains a first diamine having at least one acidic group and a second diamine having at least one nitrogen atom-containing basic functional group other than two amino groups,

the first diamine contains at least one functional group selected form a sulfonic acid group, a phosphoric acid group, and a phosphonic acid group as the acidic group,

the second diamine is represented by the following chemical formula (2): H 2 N—Y—NH 2 , wherein Y is an at least divalent organic group which contains one to three nitrogen atoms, and contains a functional group selected from an amino group having a secondary amine structure (—NH—), a primary amide group (—CO—NH 2 ), and a secondary amide group (—CO—NH—) as the nitrogen atom-containing basic functional group, and

in a case where the second diamine has an annulation in the molecule, the annulation is a benzene ring structure, and

wherein the second diamine comprises at least one of the compounds represented by the following chemical formulae (B-7), (B-30) and (B-31):

in which each n independently represents an integer of 0 to 8, and each R independently represents an alkyl group having 1 to 3 carbon atoms.

14. An alignment film comprising a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride, and

liquid crystal molecules on a surface of the alignment film, uniformly aligned by the alignment film, wherein

the diamine contains a first diamine having at least one acidic group and a second diamine having at least one nitrogen atom-containing basic functional group other than two amino groups,

the first diamine contains at least one functional group selected form a sulfonic acid group, a phosphoric acid group, and a phosphonic acid group as the acidic group,

the second diamine is represented by the following chemical formula (2): N 2 N—Y—NH 2 , wherein Y is an at least divalent organic group which contains one to three nitrogen atoms; and contains a functional group selected from an amino group having a secondary amine structure (—NH—), primary amide group (—CO—NH 2 ), and a secondary amide group (—CO—NH—) as the nitrogen atom-containing basic functional group, and

in a case where the second diamine has an annulation in the molecule, the annulation is a benzene ring structure, and

wherein the second diamine comprises at least one of the compounds represented by the following chemical formulae (B-7), (B-30) and (B-31):

in which each n independently represents an integer of 0 to 8, and each R independently represents an alkyl group having 1 to 3 carbon atoms.