Acrylic photovoltaic module backsheet
View Patent ↗The invention relates to an acrylic layer (in the form of a coating, film or sheet) useful as part of a photovoltaic module backsheet. The acrylic layer contains at least 40 percent of one or more acrylic polymers, including an acrylic polymer matrix and optionally acrylic impact modifiers. The acrylic polymer is preferably a polymer, copolymer, or terpolymer containing at least 50 weight percent of methylmethacrylate monomer units. The acrylic layer is flexible and optionally contains high levels of white pigment. It may also contain fluoropolymers such as polyvinylidene fluoride to improve weathering, processibility and film formation. The acrylic layer adheres to a polymer support layer such as polyethylene terephthalate (PET). A preferred substrate is PET that is pre-treated to improve adhesion, but unprimed PET can also be used. The backsheet provides excellent weatherability, environmental stability and reflectivity as part of a photovoltaic module.
1. A photovoltaic module comprising, in order from front to back:
a) a solar radiation transparent glazing material;
b) one or more solar cells; and
c) a multi-layer backsheet consisting of from front to back:
1) a polymer support layer having a thickness of from 50 to 500 microns, wherein said polymer support layer is selected from polyethylene terephthalate (PET), and polyethylene naphthalate (PEN);
2) as the outermost backside layer exposed to the environment, an acrylic homopolymer or copolymer layer (the acrylic layer) adhered directly to said support layer on the outer back side of said support layer, wherein said acrylic layer has a Tg of greater than 110° C., and where said acrylic layer comprises:
a) 51 percent or greater by weight, based on the total polymer(s) in the acrylic layer of an acrylic polymer consisting of one or more acrylic polymers comprising at least 70 weight percent of methyl methacrylate monomer units;
b) from 10 to 49 weight percent of one or more pigments, based on the weight of the acrylic polymer;
c) optionally up to 40 weight percent of fluoropolymers, based on the total weight of the acrylic polymer and said optional fluoropolymer;
d) optionally from 0 to 50 weight percent of impact modifiers, based on the weight of the acrylic polymer;
and wherein said acrylic layer is in the form of one or more coatings, films, or sheets having a total thickness of from 5 to 200 microns.
2. The photovoltaic module of claim 1 , wherein said pigment(s) are white pigments.
3. The photovoltaic module of claim 2 , wherein said white pigment comprises TiO 2 , ZnO, and BaSO 4 particles.
4. The photovoltaic module of claim 1 , wherein said acrylic polymer comprises an acrylic matrix and from 0 to 50 weight percent of one or more impact modifiers, based on the total weight of acrylic polymers.
5. The photovoltaic module of claim 4 , wherein said acrylic polymer comprises an acrylic matrix and from 10 to 30 weight percent of one or more acrylic impact modifiers, based on the total weight of acrylic polymers.
6. The photovoltaic module of claim 1 , wherein said acrylic polymer comprises from 0.01 to 20 weight percent of functionalized monomer units.
7. The photovoltaic module of claim 6 , wherein said functionalized monomer units comprise acrylic acid, methacrylic acid, or a mixture thereof.
8. The photovoltaic module of claim 1 , wherein said fluoropolymer comprises a homopolymer or copolymer of polyvinylidene fluoride, comprising at least 75 weight percent of vinylidene fluoride monomer units.
9. The photovoltaic module of claim 1 , further comprising one or more additional layers selected from the group consisting of an additional acrylic layer of the same or different composition, a fluoropolymer layer, an ethylene vinyl acetate (EVA) layer, and a thermoplastic layer.
10. The photovoltaic module of claim 1 , wherein said acrylic polymer layer further is crosslinkable, and reactive with multi-functional groups.
11. The photovoltaic module of claim 1 , wherein said acrylic layer further comprises reactive additives.