Unsaturated polyester
View Patent ↗The present invention relates to a resin composition comprising (a) an unsaturated polyester resin having a molecular weight M n of at least 750 Dalton and at most 5000 Dalton and (b) a reactive diluent, wherein the unsaturated polyester resin comprises C5-C10 unsaturated diacid building blocks and isosorbide building blocks. Preferably, at least part of the isosorbide is derived from a non-fossil source. Preferably, itaconic acid or anhydride is used as the C5 unsaturated dicarboxylic acid.
1. A resin composition comprising:
(a) an unsaturated polyester resin having a molecular weight M n of at least 750 Dalton and at most 5000 Dalton, and
(b) a reactive diluent, wherein
the unsaturated polyester resin comprises C5-C10 unsaturated diacid building blocks and isosorbide building blocks, and wherein
at least 25 wt. % of the unsaturated dicarboxylic acid building blocks of the unsaturated polyester resin are itaconic acid building blocks.
2. The resin composition according to claim 1 , wherein at least part of the isosorbide is derived from a non-fossil source.
3. The resin composition according to claim 1 , wherein the C5-C10 unsaturated dicarboxylic acid building blocks are itaconic acid or anhydride building blocks.
4. The resin composition according to claim 3 , wherein at least a part of the itaconic acid or anhydride building blocks is derived from a non-fossil source.
5. The resin composition according to claim 1 , wherein the isosorbide building blocks are present in a molar amount of at least 2.5% and at most 50%, relative to the total amount of diols.
6. The resin composition according according to claim 1 , wherein the unsaturated polyester resin has a Tg which is at least −70° C. and at most 100° C.
7. The resin composition according to claim 1 , wherein hydroxyl end groups and carboxylic acid end groups in the unsaturated polyester resin are present in a molar ratio of the hydroxyl end groups to the carboxylic acid end groups in a range from 0.33 to 3.
8. The resin composition according to claim 7 , wherein the molar ratio of hydroxyl end groups and carboxylic acid end groups in the unsaturated polyester resin is in the range from 1.1 to 3.
9. The resin composition according to claim 1 , wherein the reactive diluent comprises styrene, dimethyl itaconate and/or a methacrylate.
10. The resin composition according to claim 1 , wherein the resin composition further comprises an initiator for curing the resin composition.
11. A multicomponent resin composition comprising a component consisting of the resin composition according to claim 1 , and a component comprising an initiator for curing the resin composition.
12. A cured object or structural part obtained by curing a resin composition according to claim 1 with an initiator.
13. A powder coating composition comprising a resin composition according to claim 1 .